Oxygen isotope systematics of gem corundum deposits in Madagascar: relevance for their geological origin

The oxygen isotopic composition of gem corundum was measured from 22 deposits and occurrences in Madagascar to provide a gemstone geological identification and characterization. Primary corundum deposits in Madagascar are hosted in magmatic (syenite and alkali basalt) and metamorphic rocks (gneiss, cordieritite, mafic and ultramafic rocks, marble, and calc-silicate rocks). In both domains the circulation of fluids, especially along shear zones for metamorphic deposits, provoked in situ transformation of the corundum host rocks with the formation of metasomatites such as phlogopite, sakenite, and corundumite. Secondary deposits (placers) are the most important economically and are contained in detrital basins and karsts. The oxygen isotopic ratios (¹⁸O/¹⁶O) of ruby and sapphire from primary deposits are a good indicator of their geological origin and reveal a wide range of δ¹⁸O (Vienna Standard Mean Ocean Water) between 1.3 and 15.6‰. Metamorphic rubies are defined by two groups of δ¹⁸O values in the range of 1.7 to 2.9‰ (cordieritite) and 3.8 to 6.1‰ (amphibolite). “Magmatic” rubies from pyroxenitic xenoliths contained in the alkali basalt of Soamiakatra have δ¹⁸O values ranging between 1.3 and 4.7‰. Sapphires are classified into two main groups with δ¹⁸O in the range of 4.7 to 9.0‰ (pyroxenite and feldspathic gneiss) and 10.7 to 15.6‰ (skarn in marble from Andranondambo). The δ¹⁸O values for gem corundum from secondary deposits have a wide spread between −0.3 and 16.5‰. The ruby and sapphire found in placers linked to alkali basalt environments in the northern and central regions of Madagascar have consistent δ¹⁸O values between 3.5 and 6.9‰. Ruby from the placers of Vatomandry and Andilamena has δ¹⁸O values of 5.9‰, and between 0.5 and 4.0‰, respectively. The placers of the Ilakaka area are characterized by a huge variety of colored sapphires and rubies, with δ¹⁸O values between −0.3 and 16.5‰, and their origin is debated. A comparison with oxygen isotope data obtained on gem corundum from Eastern Africa, India, and Sri Lanka is presented. Giant placer deposits from Sri Lanka, Madagascar, and Tanzania have a large variety of colored sapphires and rubies with a large variation in δ¹⁸O due to mingling of corundum of different origin: mafic and ultramafic rocks for ruby, desilicated pegmatites for blue sapphire, syenite for yellow, green, and blue sapphire, and skarn in marbles for blue sapphire.     

Long-Term Stability Of Geoidal Geopotential FromTopex/Poseidon Satellite Altimetry 1993–1999

The TOPEX/POSEIDON (T/P) satellite altimeter data from January 1, 1993to October 24, 1999 (cycles 11–261) was used for investigating thelong-term variations in the geoidal geopotential W₀ and/orin the geopotential scale factor R₀ = GM/W₀ (GM is theadopted geocentric gravitational constant). The mean valuesdetermined for the whole period covered are: W₀ =(62 636 856.161 ± 0.002) m² s^-2, R₀ =(6 363 672.5448 ± 0.0002) m. The actual accuracy is limited bythe altimeter calibration error (2–3 cm) and it isestimated to be about ± 0.5 m² s^-2 (± 5 cm).The yearly variations of the above mean values are at the formalerror level. No long-term trend in W₀, representing the oceanvolume change, was found for the seven years period 1993–9 on thebasis of T/P altimeter (AVISO) data. No sea surface topography modelwas used in the solution. This revised version was published online in July 2006 with corrections to the Cover Date.     

88 centimetres of coastal erosion per year: The case of Kildare (Alberton), Prince Edward Island,Canada

Conclusion This short article has made it possible to determine the current conditions of erosion in one sector of the coast of Prince Edward Island, as well as to calculate, with as great a degree of accuracy as possible, the speed at which the ocean is destroying the shoreline of this sector. The intensity of shoreline erosion has varied over the years (Dubois and Longhurst 1984). The variation may perhaps be explained in part by the fact that water temperature varies in the same proportion as the temperature of the surrounding air (Trites 1984), and that over a period of several decades, the air temperature, and the climate in general, do vary (Trites 1984). Thus a study of the correlation between coastline erosion and climatological variations over several decades would certainly be a useful aid for predicting the future state of the coastline. There is also a need for a map of the various sectors of the PEI coast, showing their degree of susceptibility to various systems of erosion. Such a map would be extremely useful both for land management purposes (construction, roads, agriculture) and for security reasons (civil protection, ocean recreation.     

Atrazine effects on meiobenthic assemblages of a modular estuarine mesocosm

Atrazine is a widely used herbicide in the US found at levels ranging from <10 ng/L to 62.5 microg/L in estuaries throughout the southeast. Effects of atrazine on estuarine meiobenthic assemblages chronically exposed to environmentally relevant concentrations are unknown. The purpose of our research was to assess effects of atrazine on meiobenthos at concentrations near the proposed USEPA SWQC (26 microg/L) using modular estuarine salt marsh mesocosms as a field surrogate. Indigenous copepod and nematode densities were assessed after 28 days of exposure in transplanted colonization chambers. Cluster analysis showed a group characterized by low copepod densities, mostly atrazine exposed chambers, and a group containing all but one control chamber. The later group included chambers with high densities of the copepods Paronychocamptus wilsoni and Enhydrosoma baruchi. Compared to controls, copepod densities was approximately 70% lower in atrazine chambers, with three of the most common copepod species (E. baruchi, Onychocamptus sp. and P. wilsoni) showing an average of 50-70% reduction in population densities (p<0.05). Although nematode density did not differ between atrazine and control chambers, the nematode-to-copepod ratio was significantly higher in atrazine (9.95+/-7.61; p=0.011) than in control chambers (0.61+/-0.35). Our findings suggest that chronic exposures over multiple generations to atrazine at concentrations near the proposed USEPA SWQC could have significant effects on the abundance and composition of estuarine meiobenthic copepod assemblages.     

Mass Estimation in the Globular Cluster M4

Using the kinematical data we try to solve the Jeans equation to provide mass estimation of the globular cluster M4. The proper motion data provides two independent velocity dispersion profiles which we need in this estimation. Moreover, we have calculated the density distribution function and checked the anisotropy of the velocity dispersion. The comparison of the dynamical mass with the estimation stellar mass for M4 gives the best estimation of the mass inside a spherical shell centered on the cluster, with a radius corresponding to 840 arcsec on the sky, as 4-5× 10⁴ M . This revised version was published online in July 2006 with corrections to the Cover Date.     

Real-Time Tsunami Forecasting: Challenges and Solutions

A new method for real-time tsunami forecasting will provide NOAAs Tsunami Warning Centers with forecast guidance tools during an actual tsunami event. PMEL has developed the methodology of combining real-time data from tsunameters with numerical model estimates to provide site- and event-specific forecasts for tsunamis in real time. An overview of the technique and testing of this methodology is presented.     

Chemical and Mineralogical Signatures of Archaeological Features at the Mailhot‐Curran Iroquoian Site,Eastern Canada

The St. Lawrence Iroquoians built villages in southwestern Quebec (Canada) along the St. Lawrence River. They left behind longhouses, hearths, middens, and storage pits like those discovered at the Mailhot‐Curran archaeological site in Saint‐Anicet. Here, we contrast the properties of Iroquoian features with undisturbed soil to define the chemical and mineralogical signature of hearths, middens, and pits. The native soil has a neutral pH and consists of an Ah horizon overlaying a Bm horizon dominated by quartz and feldspars. In the hearths, ashes are characterized by neoformed calcite and apatite with carbonates, higher total P, and enrichment in amorphous inorganic Al, Fe, and Si. The rubified layer of hearths contain poorly crystallized Fe oxides. The mineralogy of the rubified layer is dominated by authigenetic ankerite, an Fe‐carbonate mineral identified here for the first time in Iroquoian hearths. Middens have the highest organic matter content and contain more organically complexed Al and Fe than the soil. The storage pits have low pH values and carbonate content and contain high levels of amorphous Si and total P. Our work establishes the pedologic signature of three Iroquoian features despite significant alteration of their properties by post‐occupational biogeochemical processes.     

Determination of Gold in e‐Waste Dust Samples and Geological Matrices by ICP‐MS after Extraction by an HClO4‐HBr‐HI‐Aqua Regia Mixture

This study describes two methods (Procedures‐1 and ‐2) for the direct extraction of Au by an inorganic acid mixture (HClO₄‐HBr‐HI‐aqua regia) from complex sample matrices. Standard PTFE jars at 200 °C were used to decompose test portions of 0.5–1 g, with subsequent precise and accurate analysis by ICP‐MS without any other preconcentration or separation. Procedure‐1 decomposed samples effectively without the necessity of leaching with HF and was developed for dust samples from e‐waste (electronic waste) processing; however, testing on geological reference materials showed very good results. The analyses of replicate decompositions (n = 5) from both procedures yielded very good precision (< 5% RSD) for most of the reference materials. The accuracy achieved was better than ± 10%, with the exception of NIST SRM 2782 data from Procedure‐1. Two unknown samples of dust from e‐waste processing (P‐1 and VM‐1) exhibited elevated concentrations of Au (21.31–61.64 μg g^?1) with precision better than 10% (n = 5). The proposed techniques are simple, sensitive and sparing in the use of chemicals, and are designed for a variety of e‐waste dust samples. No significant influences were observed for the predicted spectral interferences on mass ¹⁹⁷Au.