Coelostat and heliostat: Theory of alignment

For perfectly aligned heliostats and coelostats tracking at the solar rate and half the solar rate, respectively, the solar beam has no translational motion. But, particularly in the field at eclipses, it is not possible to align heliostats and coelostats with infinite precision. We derive the effect of small misalignments on the translational motion of the beam, and give tables to allow the calculation of the accuracy to which the instruments must be mounted and adjusted to attain a desired accuracy over a given duration. Further, we show how to derive the necessary adjustments to improve alignment, given measurements of the tracking error.     

Density functional theory modeling of chromate adsorption onto ferrihydrite nanoparticles

Density functional theory (DFT) calculations were performed on a model of a ferrihydrite nanoparticle interacting with chromate (\( {\text{CrO}}_{4}^{2 - } \)) in water. Two configurations each of monodentate and bidentate adsorbed chromate as well as an outer-sphere and a dissolved bichromate (\( {\text{HCrO}}_{4}^{ - } \)) were simulated. In addition to the 3-D periodic planewave DFT models, molecular clusters were extracted from the energy-minimized structures. Calculated interatomic distances from the periodic and cluster models compare favorably with Extended X-ray Absorption Fine Structure spectroscopy values, with larger discrepancies seen for the clusters due to over-relaxation of the model substrate. Relative potential energies were derived from the periodic models and Gibbs free energies from the cluster models. A key result is that the bidentate binuclear configuration is the lowest in potential energy in the periodic models followed by the outer-sphere complex. This result is consistent with observations of the predominance of bidentate chromate adsorption on ferrihydrite under conditions of high surface coverage (Johnston Environ Sci Technol 46:5851–5858, 2012). Cluster models were also used to perform frequency analyses for comparison with observed ATR FTIR spectra. Calculated frequencies on monodentate, bidentate binuclear, and outer-sphere complexes each have infrared (IR)-active modes consistent with experiment. Inconsistencies between the thermodynamic predictions and the IR-frequency analysis suggest that the 3-D periodic models are not capturing key components of the system that influence the adsorption equilibria under varying conditions of pH, ionic strength and electrolyte composition. Model equilibration via molecular dynamics (MD) simulations is necessary to escape metastable states created during DFT energy minimizations based on the initial classical force field MD-derived starting configurations.     

Crustal and uppermost mantle S-wave velocity below the East European Craton in northern Poland from the inversion of ambient-noise records

International Journal of Earth Sciences - The P-wave velocities (Vp) within the East European Craton in Poland are well known through several seismic experiments which permitted to build a...     

SphinX: The Solar Photometer in X-Rays

Solar Photometer in X-rays (SphinX) was a spectrophotometer developed to observe the Sun in soft X-rays. The instrument observed in the energy range ≈?1?–?15 keV with resolution ≈?0.4 keV. SphinX was flown on the Russian CORONAS–PHOTON satellite placed inside the TESIS EUV and X telescope assembly. The spacecraft launch took place on 30 January 2009 at 13:30 UT at the Plesetsk Cosmodrome in Russia. The SphinX experiment mission began a couple of weeks later on 20 February 2009 when the first telemetry dumps were received. The mission ended nine months later on 29 November 2009 when data transmission was terminated. SphinX provided an excellent set of observations during very low solar activity. This was indeed the period in which solar activity dropped to the lowest level observed in X-rays ever. The SphinX instrument design, construction, and operation principle are described. Information on SphinX data repositories, dissemination methods, format, and calibration is given together with general recommendations for data users. Scientific research areas in which SphinX data find application are reviewed.     

Photometric observations of Earth‐impacting asteroid 2008 TC3

Abstract– A calibrated lightcurve is presented of the near‐Earth asteroid 2008 TC₃, obtained before it impacted Earth on October 7, 2008. The asteroid was observed in unfiltered images from the end of astronomical twilight until the object entered Earth’s shadow about 2 h later. The observations covered a wide range of phase angles from 14.79° to 2.93°, during which the asteroid ranged from 82,000 km to 29,000 km distance from the observer. A method is presented for obtaining photometrically filtered brightness values for the asteroid using unfiltered imaging techniques. Over 1,700 images of the asteroid produce a lightcurve with a peak‐to‐peak variation in V of 0.76 magnitude. Analysis of the lightcurve yields values for H = 30.86 ± 0.01 and G = 0.33 ± 0.03. Combined with other constraints on the kinetic energy and diameter of the asteroid, which suggest a low 1.8 g cm^?3 density and albedo 0.05 ± 0.01, the value of H implies an asteroid of about 4.1 m in diameter, 28 m³ in volume, and 51,000 kg in mass. The determined value of G is out of range for normal, larger asteroids of albedo 0.05–0.15.     

Soil gas composition above gas deposits and perspective structures of the Carpathian Foredeep,SE Poland

In 2001 a surface geochemical survey was carried out in the Carpathian Foredeep, in the area between Jaros?aw and Radymno (SE Poland) where multihorizon gas deposits were discovered. These deposits accumulate microbial CH₄ with small amounts of N₂ and higher molecular weight gaseous hydrocarbons. Soil–gas composition in the hydrocarbon fields in the study area is relatively different from the original composition of natural gas occurring in the subsurface reservoir. In 449 analyzed soil gas samples collected from 1.2 m depth relatively low concentrations were found for CH₄ (median value 2.2 ppm) and its homologues (median value of total alkanes C₂–C₄ – 0.02 ppm). Alkenes were encountered in 36.3% of the analyzed samples (mean value of total alkenes C₂–C₄ – 0.015 ppm) together with distinctly higher concentrations of H₂ (maximum value – 544 ppm, mean value – 42 ppm) and CO₂ (maximum value – 10.26 vol.%, mean value – 2.27 vol.%). Individual, very high concentrations of CH₄ (up to about 35 vol.%) resulted from sub-surface biochemical reactions whereas higher alkanes detected in soil gases (up to about 68 ppm) originated from deep gas accumulations. Both the H₂ and alkenes may be indirect indicators of deep hydrocarbon accumulations. Carbon dioxide may also be useful for hydrocarbon exploration, revealing increased concentrations in those sampling sites where CH₄ concentrations are strongly depleted, presumably due to bacterial oxidation. These relationships are valid only for the study area and should not be extended as an universal principle.     

Full‐scale Applications of Membrane Filtration in Municipal Wastewater Treatment Plants

The performance of one pilot‐scale and two full‐scale membrane bioreactors (MBR) were evaluated based on the control of main operational parameters, composition of microbial community and pathogens concentration in the treated outlet. Plants were designed for 0.75 m³/day (A), 60 m³/day (B) and 30 m³/day (C). Inlet and outlet samples were monitored for chemical oxygen demand (COD), biological oxygen demand, total suspended solids, ammonia nitrogen concentration (NH₄–N), nitrate nitrogen concentration, total Kjeldahl nitrogen, total phosphorus and phosphate phosphorus concentration concentrations. Plants showed good COD removal: 91.9% for Plant A, 97.8% for Plant B and 94.2% for Plant C. The targeted nitrogenous ion was NH₄–N due to the requirements for outlet limits. NH₄–N removal was moderate for Plant A (73.3%) and Plant B (86.1%) and excellent for Plant C (>99%). Excellent phosphorus removal was achieved by Plant A (average outlet concentration was 0.7 mg/L, efficiency 84.7%). Unsatisfactory results for phosphorus removal were achieved at the full‐scale plants due to operational problems. The dependency between the extracellular polymeric substances increase and decreasing mixed liquor volatile suspended solids for both lab and full‐scale plants was confirmed. Soluble microbial product concentrations were reduced by 65–68% after coagulant dosage for Plant A. Outlets from the MBR plants were monitored for the presence of pathogens (thermotolerant coliforms, Escherichia coli, intestinal Enterococci and culturable microorganisms at 22 and 37°C). The treated effluent from Plant A, B and C met Czech national legislation regarding reuse criteria (standards) for environment, irrigation and swimming purposes. Plants B and C were not able to achieve requirements for potable water and personal hygiene quality standards.