A new computational strategy for solving two‐phase flow in strongly heterogeneous poroelastic media of evolving scales

We develop a new computational methodology for solving two‐phase flow in highly heterogeneous porous media incorporating geomechanical coupling subject to uncertainty in the poromechanical parameters. Within the framework of a staggered‐in‐time coupling algorithm, the numerical method proposed herein relies on a Petrov–Galerkin postprocessing approach projected on the Raviart–Thomas space to compute the Darcy velocity of the mixture in conjunction with a locally conservative higher order finite volume discretization of the nonlinear transport equation for the saturation and an operator splitting procedure based on the difference in the time‐scales of transport and geomechanics to compute the effects of transient porosity upon saturation. Notable features of the numerical modeling proposed herein are the local conservation properties inherited by the discrete fluxes that are crucial to correctly capture the fingering patterns arising from the interaction between heterogeneity and nonlinear viscous coupling. Water flooding in a poroelastic formation subject to an overburden is simulated with the geology characterized by multiscale self‐similar permeability and Young modulus random fields with power‐law covariance structure. Statistical moments of the poromechanical unknowns are computed within the framework of a high‐resolution Monte Carlo method. Numerical results illustrate the necessity of adopting locally conservative schemes to obtain reliable predictions of secondary recovery and finger growth in strongly heterogeneous deformable reservoirs. Copyright © 2011 John Wiley & Sons, Ltd.     

New controversies on Columbus' “cosmographic” ideas

This paper examines the spatial distribution of the functional systems in the different belts of settlements around Budapest. The surburban belts have an important role in the capital's labour market, places of employment and recreation with 45 settlements. The paper reviews the structure of the Budapest agglomeration from the core to the three inner, middle and outer belts comprising the suburbs, the semi-urban settlements, the suburban villages, the satellite towns, and the satellite villages. Then the system of the functional urban centres are reviewed, The author establishes the concept of the main, the division, the district and the settlement group centres in the Budapest agglomeration. The different levels of attached functions, such as international, national, regional and local are also described with each centre type. The areal distribution of the centre system of Budapest is shown in maps too.     

Geochemistry and origin of volcanic rocks of the Andes (26°–28°S)

Mesozoic to Recent volcanic rocks from a transect of the Central Andes between latitudes 26 ° and 28 ° South in northern Chile and Argentina show chemical and temporal zonation with respect to the Peru-Chile trench. Jurassic to Eocene lavas occur closer to the trench and are comparable to calc-alkaline rocks of island arcs. Eastwards they are followed by Miocene to Quaternary sequences of typical continental margin calc-alkaline rocks which have higher contents of K, Rb, Sr, Ba, Zr, and REE and also higher K/Na and La/Yb ratios. The rocks occurring farthest from the trench have shoshonitic affinities. The distribution of major and trace elements is consistent with a model in which magmas were derived by anatexis of an upper mantle source already enriched in LILE and located above the descending oceanic slab. It is suggested that the chemical variations across the volcanic belt reflect systematic changes in the composition of the magmas due to a decreasing degree of partial melting with increasing depth, and probably also due to the heterogeneity of the source materials.     

Oxygen isotopic compositions of Central Andean plutonic and volcanic rocks,latitudes 26°–29° south

Oxygen isotope data are reported for 27 igneous rocks of Mesozoic to Quaternary age from the Central Andes. 26–29°S. The plutonic rocks, and most of the volcanics, have δ¹⁸O values between 6.2 and 8.3‰.The whole-rock δ¹⁸O values show a weak correlation with initial⁸⁷Sr/⁸⁶Sr data. This O-Sr array differs from documented trends for calc-alkaline plutonic suites from California, Scotland and northern Italy, but overlaps with data for volcanic and plutonic rocks from Ecuador, northern Chile and southern Perú.The oxygen isotope results indicate that the magmas evolved without significant contamination from supracrustal rocks (e.g., rocks that experienced¹⁸O enrichment during surficial weathering). The available O, Sr and Pb isotopic data for these rocks are best explained by magma generation in the upper mantle or lower crust. From the Late Mesozoic on, the⁸⁷Sr/⁸⁶Sr values were modified at depth by isotopic exchange between the magma and a continually thickening crust of plutonic rocks of Late Precambrian to early Mesozoic age.     

Evidence of progressive deformation in minor structures in Western Asturias (N. W. Spain)

Examples of progressive deformation provided by minor structures are not frequent in the geological literature. In NW Spain some minor structures in Lower Paleozoic inhomogeneous layered material may be interpreted as the result of progressive deformation during the Hercynian Orogeny. The examples described include structures generated by progressive contraction (folded wedges), contraction followed by elongation (folds disrupted by boudinage) and elongation followed by contraction (folded boudins).     

Electron microprobe dating of monazite substantiates ages of major geological events in the southern Brazilian shield

To obtain the chemical Th^*–Pb isochron ages and surface maps of monazite crystals in igneous and metamorphic rocks from the southern Brazilian Shield, we employ Th–U-total Pb dating by an electron probe microanalyzer. The ages of two Trans-Amazonian metamorphic events are given by a felsic, garnet-bearing granulite from the Santa Maria Chico granulitic complex. The age of the first event, at approximately 2.35 Ga, was obtained by surface mapping in a grain included in garnet. The dating of the second event, 1899±43 Ma, is in agreement with previous data obtained in zircon crystals with sensitive high-resolution ion microprobe. Other determinations belong to the Brasiliano cycle. In the São Gabriel block, an age of 643±129 Ma was obtained on monazite from a staurolite-garnet schist of the Cambaizinho Formation, whereas a staurolite-bearing schist from the Passo Feio complex yielded a 510±68 Ma age. Several units in the Dom Feliciano belt were dated, including the biotite-sillimanite gneisses of the Várzea do Capivarita complex (552±90 Ma), the sillimanite-garnet gneisses of Camboriú complex (565±77 Ma), the Três Figueiras granite (558±57 Ma), and the Plaza Itapema granite (545±55 Ma). The ages presented in this study, obtained through monazite chemical dating, are confirmed through comparison with previous data regarding zircon crystals from the same geological units.     

Generation of overtides and compound tides in Amazon estuary

Tidal propagation in estuaries is affected by friction and fresh water discharge, besides changes in the depth and morphology of the channel. Main distortions imply variations in the mean water level and asymmetry. Tidal asymmetry can be important as a mechanism for sediment accumulation and turbidity maximum formation in estuaries, while mean water level changes can affect navigation depths. Data from several gauges stations from the Amazon estuary and the adjacent coast were analyzed and a 2DH hydrodynamic model was configured in a domain covering the continental shelf up to the last section of the river where the tidal signature is observed. Based on data, theoretical and numerical results, the various influences in the generation of estuarine harmonics are presented, including that of fresh water discharge. It is shown that the main overtide, M₄, derived from the most important astronomic component in the Amazon estuary, M₂, is responsible for the tidal wave asymmetry. This harmonic has its maximum amplitude at the mouth, where minimum depths are found, and then decreases while tide propagates inside the estuary. Also, the numerical results show that the discharge does not affect water level asymmetry; however, the Amazon river discharge plays an important role in the behavior of the horizontal tide. The main compound tide in Amazon estuary, Msf, generated from the combination of the M₂ and S₂, can be strong enough to provoke neap low waters lower than spring ones. The results show this component increasing while going upstream in the estuary, reaching a maximum and then slightly decaying.     

Stability and P–V–T equation of state of KAlSi3O8-hollandite determined by in situ X-ray observations and implications for dynamics of subducted continental crust material

In situ X-ray diffraction measurements of KAlSi₃O₈-hollandite (K-hollandite) were performed at pressures of 15–27 GPa and temperatures of 300–1,800 K using a Kawai-type apparatus. Unit-cell volumes obtained at various pressure and temperature conditions in a series of measurements were fitted to the high-temperature Birch-Murnaghan equation of state and a complete set of thermoelastic parameters was obtained with an assumed K′_300,0=4. The determined parameters are V _300,0=237.6(2) Å³, K _300,0=183(3) GPa, (?K _T,0/?T) _P =?0.033(2) GPa K^?1, a ₀=3.32(5)×10^?5 K^?1, and b ₀=1.09(1)×10^?8 K^?2, where a ₀ and b ₀ are coefficients describing the zero-pressure thermal expansion: α _T,0 = a ₀ + b ₀ T. We observed broadening and splitting of diffraction peaks of K-hollandite at pressures of 20–23 GPa and temperatures of 300–1,000 K. We attribute this to the phase transitions from hollandite to hollandite II that is an unquenchable high-pressure phase recently found. We determined the phase boundary to be P (GPa)=16.6 + 0.007 T (K). Using the equation of state parameters of K-hollandite determined in the present study, we calculated a density profile of a hypothetical continental crust (HCC), which consists only of K-hollandite, majorite garnet, and stishovite with 1:1:1 ratio in volume. Density of HCC is higher than the surrounding mantle by about 0.2 g cm^?3 in the mantle transition zone while this relation is reversed below 660-km depth and HCC becomes less dense than the surrounding mantle by about 0.15 g cm^?3 in the uppermost lower mantle. Thus the 660-km seismic discontinuity can be a barrier to prevent the transportation of subducted continental crust materials to the lower mantle and the subducted continental crust may reside at the bottom of the mantle transition zone.     

Preliminary magnetic studies of lagoon and stream sediments from Chascomús Area (Argentina)—magnetic parameters as indicators of heavy metal pollution and some results of using an experimental method to separate magnetic phases

Magnetic properties of lagoon and stream sediments from Chascomús area (Buenos Aires Province) and the relevance of various magnetic parameters as giving pollution status are studied in the present work. This work is focussed on magnetic parameters, such as concentration-dependent (magnetic susceptibility, saturation anhysteric and isothermal remanent magnetisation) and feature-dependent parameters (S-ratio, coercivity of remanence, anhysteric susceptibility/magnetic susceptibility-ratio), as pollution indicators. Firstly and most importantly, different magnetic parameters and chemical measurements were correlated in order to investigate their goodness, obtaining the best results for feature-dependent magnetic parameters. Coercivity of remanence correlate very well with chemical variables, showing correlations at high level of significance up to 0.9094, and the anhysteric susceptibility/magnetic susceptibility-ratio also shows very good correlations (up to 0.8376). Some results and advantages of using a new experimental method in order to discriminate hard and soft magnetic phases are also shown. This method uses alternately backfield isothermal remanent magnetisation and alternating field demagnetisation. From the experimental separation, the presence of hard magnetic phases in some samples was confirmed.