Paleo-environmental and volcano-tectonic evolution of the southeastern flank of Mt. Etna during the last 225 ka inferred from the volcanic succession of the ‘Timpe’, Acireale, Sicily

The tectonic escarpments locally known as ‘Timpe’ cut a large sector of the eastern flank of Etna, and allow an ancient volcanic succession dating back to 225 ka to be exposed. Geological and volcanological investigations carried out on this succession have allowed us to recognize relevant angular unconformities and volcanic features which are the remnants of eruptive fissures, as well as important changes in the nature, composition and magmatic affinity of the exposed volcanics. In particular, the recognition in the lower part of the succession of important and unequivocal evidence of ancient eruptive fissures led us to propose a local origin for these volcanics and to revise previous interpretations which attributed their westward-dipping to the progressive tectonic tilting of strata. These elements led us to reinterpret the main features of the volcanic activity occurring since 250 ka BP and their relationship with tectonic structures active in the eastern flank of Etna. We propose a complex paleo-environmental and volcano-tectonic evolution of the southeastern flank of Mt. Etna, in which the Timpe fault system played the role of the crustal structure that allowed the rise and eruption of magmas in the above considered time span.     

Thermal expansion and dehydroxylation of phengite micas

Phengite samples (2M ₁ and 3T politypes) and a synthetic end-member muscovite specimen were studied by in situ high-temperature synchrotron radiation X-ray diffraction. The measured volume thermal expansion of 2M ₁ phengite (<α _V> ≈ 36.6 × 10⁻⁶ K⁻¹) was systematically greater than <α _V> of the 3T polytype (≈33.3 × 10⁻⁶ K⁻¹). A positive linear correlation between the average thermal expansion on (001) plane and the mean tetrahedral rotation angle at ambient condition is proposed on the ground of new measurements and literature data. Dehydroxylation processes were observed in 2M ₁, starting at 1,000 K in 3T at 800 and 945 K in synthetic muscovite. Rietveld refinements allowed a determination of structural variations upon heating of phengite samples and their dehydroxylate phases. The phengite structure expands by regularizing the tetrahedral sheet and by reducing the bond length differences between the outer and inner coordination shell of the interlayer site. The dehydroxylate phase derived from 2M ₁ is characterized by fivefold polyhedra in the low temperature form as a consequence of two OH groups reacting to form H₂O + O (residual). The dehydroxylate exhibits an increase of the cation–cation distances along the M–Or–M bonds with respect to low-temperature phengite structures. For the 3T phase, we were unable to achieve completion of dehydroxylation. The refined structural model of the dehydroxylate phase shows two hydroxyl sites, but at a short distance from one another. This result suggests that the dehydroxylation reaction did not proceed to completion. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Investigation on the effect of strong out-of-band signals on global navigation satellite systems receivers

The mitigation of radio frequency interference (RFI) has a fundamental role in global navigation satellite system (GNSS) applications, especially when a high level of availability is required. Several electromagnetic sources, in fact, might degrade the performance of the global positioning system (GPS) and Galileo receivers, and their effects can be either in-band (i.e., secondary harmonics generated by transmitters of other communication systems due to non-linearity distortions) or out-of-band (i.e., strong signals that occupy frequency bandwidths very close to GNSS bands). We investigated the effects of real out-of-band signals on GNSS receivers and analyzed the impact on the overall receiver chain in order to evaluate the impact of the interference source. In particular, the analysis focuses on the spectrum at the front-end output, on the automatic gain control (AGC) behavior, as well as on the digital processing stages (signal acquisition and tracking) at the analog digital converter (ADC) output. This study refers to several experiments and data collections performed in interfered areas of downtown Torino (Italy). The obtained results underline how digital/analog TV transmissions represent a potential interference source for GNSS applications and might be critical for the safety of life services.     

Quantifying the relationship between structural deformation and the morphology of submarine channels on the Niger Delta continental slope

The processes and deposits of deep‐water submarine channels are known to be influenced by a wide variety of controlling factors, both allocyclic and autocyclic. However, unlike their fluvial counterparts whose dynamics are well‐studied, the factors that control the long‐term behaviour of submarine channels, particularly on slopes undergoing active deformation, remain poorly understood. We combine seismic techniques with concepts from landscape dynamics to investigate quantitatively how the growth of gravitational‐collapse structures at or near the seabed in the Niger Delta have influenced the morphology of submarine channels along their length from the shelf edge to their deep‐water counterpart. From a three dimensional (3D), time‐migrated seismic‐reflection volume, which extends over 120 km from the shelf edge to the base of slope, we mapped the present‐day geomorphic expression of two submarine channels and active structures at the seabed, and created a Digital Elevation Model (DEM). A second geomorphic surface and DEM raster—interpreted to closer approximate the most recent active channel geometries—were created through removing the thickness of hemipelagic drape across the study area. The DEM rasters were used to extract the longitudinal profiles of channel systems with seabed expression, and we evaluate the evolution of channel widths, depths and slopes at fixed intervals downslope as the channels interact with growing structures. Results show that the channel long profiles have a relatively linear form with localized steepening associated with seabed structures. We demonstrate that channel morphologies and their constituent architectural elements are sensitive to active seafloor deformation, and we use the geomorphic data to infer a likely distribution of bed shear stresses and flow velocities from the shelf edge to deep water. Our results give new insights into the erosional dynamics of submarine channels, allow us to quantify the extent to which submarine channels can keep pace with growing structures, and help us to constrain the delivery and distribution of sediment to deep‐water settings.     

Complex dynamics of small-moderate volcanic events: the example of the 2011 rhyolitic Cordón Caulle eruption,Chile

After decades of repose, Puyehue-Cordón Caulle Volcano (Chile) erupted in June 2011 following a month of continuously increasing seismic activity. The eruption dispersed a large volume of rhyolitic tephra over a wide area and was characterized by complex dynamics. During the initial climactic phase of the eruption (24–30 h on 4–5 June), 11–14-km-high plumes dispersed most of the erupted tephra eastward towards Argentina, reaching as far as the Atlantic Ocean. This first eruptive phase was followed by activity of lower intensity, leading to the development of a complex stratigraphic sequence, mainly due to rapid shifts in wind direction and eruptive style. The resulting tephra deposits consist of 13 main layers grouped into four units. Each layer was characterized based on its dispersal direction, sedimentological features, and on the main characteristics of the juvenile fraction (texture, density, petrography, chemistry). The lowest part of the eruptive sequence (Unit I), corresponding to the tephra emitted between 4 and 5 June, is composed of alternating lapilli layers with a total estimated volume of ca. 0.75 km³; these layers record the highest intensity phase, during which a bent-over plume dispersed tephra towards the southeast-east, with negligible up-wind sedimentation. Products emitted during 5–6 June (Unit II) signaled an abrupt shift in wind direction towards the north, leading to the deposition of a coarse ash deposit in the northern sector (ca. 0.21 km³ in volume), followed by a resumption of easterly directed winds. A third phase (Unit III) began on 7 June and resulted in tephra deposits in the eastern sector and ballistic bombs around the vent area. A final phase (Unit IV) started after 15 June and was characterized by the emission of fine-grained white tephra from ash-charged plumes during low-level activity and the extrusion of a viscous lava flow. Timing and duration of the first eruptive phases were constrained based on comparison of the dispersal of the main tephra layers with satellite images, showing that most of the tephra was emitted during the first 72 h of the event. The analyzed juvenile material tightly clusters within the rhyolitic field, with negligible chemical variations through the eruptive sequence. Textural observations reveal that changes in eruption intensity (and consequently in magma ascent velocity within the conduit) and complex interactions between gas-rich and gas-depleted magma portions during ascent resulted in vesicular clasts with variable degrees of shear localization, and possibly in the large heterogeneity of the juvenile material.     

Structural damage in the cities of Reggiolo and Carpi after the earthquake on May 2012 in Emilia Romagna

This paper addresses the structural damage to the main buildings of the cities of Reggiolo and Carpi after the primary earthquake shocks on May 20th and 29th, 2012, in Emilia Romagna. The damage survey, performed via form-based methods, highlights the different seismic behaviour of several types of buildings, especially those having historical features, and the consequences of the damage in terms of costs. Moreover, an analysis of some failure mechanisms activated in Reggiolo enables the evaluation of the local peak ground acceleration, due to the soil amplification.     

The use of cholinesterase as potential biomarker: In vitro characterization in the polychaete Capitella teleta

The ecological relevance of polychaetes coupled with their easy culture and maintenance in the laboratory, has led them to become increasingly used in marine ecotoxicological studies, raising the need to validate frequently applied monitoring tools at various biological levels. The present study was aimed to characterize the cholinesterases (ChE) activity in the polychaete Capitella teleta, using three substrates (acetylthiocholine iodide, propionylthiocholine iodide, and S-butyrylthiocholine iodide) and four known inhibitors (eserine hemisulfate, BW284c51, iso-OMPA and chlorpyrifos-oxon). Results showed that most of the measured cholinesterase activity was acetylcholinesterase (AChE). Inhibition of enzyme kinetic experiments denoted that sensitivity of C. teleta’s ChE to the organophosphorous metabolite chlorpyrifos-oxon (IC₅₀ = 60.72 nM) was analogous to some fish species. This study highlights the relevance of ChE characterization before its use as a biomarker in ecotoxicology and biomonitoring studies.     

Visual Event Screening of Continuous Seismic Data by Supersonograms

We present a new visualization method for human inspection of seismic data called supersonograms, which maximizes the amount of time and stations visible on screen while retaining the possibility to detect short and low-signal to noise ratio (SNR) signals. This visualization approach is integrated into a seismological software suite used in the seismic aftershock monitoring system (SAMS) of Comprehensive Nuclear-Test-Ban Treaty Organization (CTBTO) on-site inspections (OSI) to detect suspicious events eventually representing aftershocks from an underground nuclear explosion (UNE). During an OSI, huge amounts of continuous waveform data accumulate from up to 50 six-channel mini-arrays covering an inspection area of 1,000 square kilometers. Sought-after events can have magnitude as low as $\hbox{M}_{\rm L}\,{-2.0}$ and duration of just a few seconds, which makes it particularly hard to discover them in large, noisy datasets. Therefore, the data visualization is based on nonlinearly scaled, noise-adapted spectrograms, i.e., sonograms, which help to distinguish weak signal energy from stationary background noise. Four single-trace sonograms per mini-array can be combined into supersonograms, since the array aperture is small and sonograms suppress differences of local site noise, allowing an analyst to check array-wide signal coherence quickly. In this paper, we present the supersonograms and the software on the basis of a dataset from a creeping, inhabited landslide in Austria where the same station layout is used as in an OSI. Detected signals are fracture processes in the sedimentary landslide, i.e., slidequakes, with $\hbox{M}_{\rm L}\,{-0.5} \,\hbox{\,to}\,{-2.5}$ between July 2009 and July 2011. These signals are comparable in magnitude and duration to expected weak UNE aftershocks.