Reionization: characteristic scales, topology and observability

Recently the numerical simulations of the process of reionization of the universe at z>6 have made a qualitative leap forward, reaching sufficient sizes and dynamic range to determine the characteristic scales of this process. This allowed making the first realistic predictions for a variety of observational signatures. We discuss recent results from large-scale radiative transfer and structure formation simulations on the observability of high-redshift Ly-α sources. We also briefly discuss the dependence of the characteristic scales and topology of the ionized and neutral patches on the reionization parameters.     

A proposal for an approach to mapping susceptibility to landslides using natural language processing and machine learning

Landslides - Compiling an inventory is a fundamental step for carrying out assessments of landslide hazards. However, data in sufficient quantity and quality are not always available. Thus, this...     

Aridity indices to assess desertification susceptibility: a methodological approach using gridded climate data and cartographic modeling

Natural Hazards - Desertification is a land degradation phenomenon with dire and irreversible consequences, affecting different regions of the world. Assessment of spatial climate susceptibility to...     

Leaf breakdown in two tropical streams: Differences between single and mixed species packs

We assessed leaf breakdown of five native riparian species from Brazilian Cerrado (Myrcia guyanensis, Ocotea sp., Miconia chartacea, Protium brasiliense, and Protium heptaphyllum), incubated in single and mixed species packs in two headwater streams with different physico-chemical properties in the Espinhaço Mountain range (Southeastern Brazil). Leaves were placed in plastic litter bags (15 cm×20 cm, 10 mm mesh size) and the experiments were carried out during the dry seasons of 2003 and 2004. Leaf nitrogen and phosphorus contents were similar in all species, but polyphenolic contents were different (P<0.001). M. guyanensis showed higher polyphenolics content (8.48% g⁻¹ dry mass) and leaf toughness. Individually, higher breakdown rates were found in M. guyanensis at Indaiá stream (k=0.0063±0.0005 d⁻¹) and in Ocotea sp. at Garcia stream (k=0.0088±0.0006 d⁻¹). However, P. brasiliense and P. heptaphyllum showed lower breakdown rates at Indaiá and Garcia streams (Indaiá: k=0.0020±0.0002 and 0.0019±0.0001 d⁻¹; Garcia: k=0.0042±0.0001 and 0.0040±0.0002 d⁻¹). Single and mixed breakdown processes of each species were not statistically different on both streams. However, all species showed higher breakdown rates at Garcia stream (P<0.01). These results suggest that leaf breakdown is not altered when litter benthic patches are composed by a mixture of species in the same proportions that they occur on riparian leaf falls.     

Concentration of anionic detergents in Rio Grande water (South Brazil)

The concentration of anionic detergents, polyphosphates, ammonia, seston and dissolved oxygen have been determined in a small bay near the principal sewage discharge of the city of Rio Grande. The results show great variations in the concentrations, as a function of the time of the day. The highest concentrations in anionic detergents were observed between 09.00 and 10.00 in the morning, and from 18.00 to 21.00. The other parameters present an erratic distribution, except the dissolved oxygen, showing a net increase in the second half of the sampling period.     

2D stream hydrodynamic,sediment transport and bed morphology model for engineering applications

A 2D depth‐averaged hydrodynamic, sediment transport and bed morphology model named STREMR HySeD is presented. The depth‐averaged sediment transport equations are derived from the 3D dilute, multiphase, flow equations and are incorporated into the hydrodynamic model STREMR. The hydrodynamic model includes a two‐equation turbulence model and a correction for the mean flow due to secondary flows. The suspended sediment load can be subdivided into different size classes using the continuum (two‐fluid) approach; however, only one bed sediment size is used herein. The validation of the model is presented by comparing the suspended sediment transport module against experimental measurements and analytical solutions for the case of equilibrium sediment‐laden in a transition from a rigid bed to a porous bed where re‐suspension of sediment is prevented. On the other hand, the bed‐load sediment transport and bed evolution numerical results are compared against bed equilibrium experimental results for the case of a meander bend. A sensitivity analysis based on the correction for secondary flow on the mean flow including the effect of secondary flow on bed shear stresses direction as well as the downward acceleration effect due to gravity on transverse bed slopes is performed and discussed. In general, acceptable agreement is found when comparing the numerical results obtained with STREMR HySeD against experimental measurements and analytical solutions. Copyright © 2007 John Wiley & Sons, Ltd.     

Mesoarchean sanukitoid rocks of the Rio Maria Granite-Greenstone Terrane,Amazonian craton,Brazil

The Archean sanukitoid Rio Maria Granodiorite yielded zircon ages of ～2.87 Ga and is exposed in large domains of the Rio Maria Granite-Greenstone Terrane, southeastern Amazonian craton. It is intrusive in the greenstone belts of the Andorinhas Supergroup, in the Arco Verde Tonalite and Caracol Tonalitic Complex (older TTGs). Archean potassic leucogranites, younger TTGs and the Paleoproterozoic granites of Jamon Suite are intrusive in the Rio Maria Granodiorite.The more abundant rocks of the Rio Maria Granodiorite have granodioritic composition and display medium to coarse even-grained textures. These rocks show generally a gray color with greenish shades due to strongly saussuritized plagioclase, and weak WNW-ESE striking foliation. The significant geochemical contrasts between the occurrences of Rio Maria Granodiorite in different areas suggest that this unit corresponds in fact to a granodioritic suite of rocks derived from similar but distinct magmas. Mingling processes involving the Rio Maria Granodiorite and similar mafic to intermediate magmas are able to explain the constant occurrence of mafic enclaves in the granodiorite.The associated intermediate rocks occur mainly near Bannach, where mostly quartz diorite and quartz monzodiorite are exposed. The dominant rocks are mesocratic, dark-green rocks, with fine to coarse even-grained texture. The Rio Maria Granodiorite and associated intermediate rocks show similar textural and mineralogical aspects. They follow the calc-alkaline series trend in some diagrams. However, they have high-Mg#, Cr, and Ni conjugate with high contents of large ion lithophile elements (LILEs), typical of sanukitoids series. The patterns of rare earth elements of different rocks are similar, with pronounced enrichment in light rare earth elements (LREEs) and strong to moderate fractionation of heavy rare earth elements (HREEs).Field aspects and petrographic and geochemical characteristics denote that the granodiorites and intermediate rocks have sanukitoid affinity. However, geochemical data suggest that the intermediate rocks and the granodiorites are not related by a fractional crystallization process. It is concluded that the intermediate rocks derived from similar sources to the granodiorites, but probably result from a higher degree of melting, being both cogenetic, but not comagmatic rocks.Mineralogical aspects associated with experimental evidence suggest that the Rio Maria Granodiorite magma was relatively water-enriched (>4 wt.%), explaining the presence of hornblende at the liquidus and the absence of clinopyroxene and orthopyroxene in the studied rocks. The occurrence of well-preserved magmatic epidote crystals, admitting that the Rio Maria Granodiorite was emplaced at shallow crustal levels, points to a rapid ascent of the Rio Maria Granodiorite magma.     

A unified model for bedform development and equilibrium under unidirectional,oscillatory and combined‐flows

The development of bedforms under unidirectional, oscillatory and combined‐flows results from temporal changes in sediment transport, flow and morphological response. In such flows, the bedform characteristics (for example, height, wavelength and shape) change over time, from their initiation to equilibrium with the imposed conditions, even if the flow conditions remain unchanged. These variations in bedform morphology during development are reflected in the sedimentary structures preserved in the rock record. Hence, understanding the time and morphological development in which bedforms evolve to an equilibrium stage is critical for informed reconstruction of the ancient sedimentary record. This article presents results from a laboratory flume study on bedform development and equilibrium development time conducted under purely unidirectional, purely oscillatory and combined‐flow conditions, which aimed to test and extend an empirical model developed in past work solely for unidirectional ripples. The present results yield a unified model for bedform development and equilibrium under unidirectional, oscillatory and combined‐flows. The experimental results show that the processes of bedform genesis and growth are common to all types of flows, and can be characterized into four stages: (i) incipient bedforms; (ii) growing bedforms; (iii) stabilizing bedforms; and (iv) fully developed bedforms. Furthermore, the development path of bedform; growth exhibits the same general trend for different flow types (for example, unidirectional, oscillatory and combined‐flows), bedform size (for example, small versus large ripples), bedform shape (for example, symmetrical or rounded), bedform planform geometry (for example, two‐dimensional versus three‐dimensional), flow velocities and sediment grain sizes. The equilibrium time for a wide range of bed configurations was determined and found to be inversely proportional to the sediment transport flux occurring for that flow condition.     

Treatment of a Trifluraline Effluent by Means of Oxidation‐Coagulation with Fe(VI) and Combined Fenton Processes

The amination water (AW) effluent stream from the industrial production of the trifluraline herbicide was submitted to an oxidation‐coagulation treatment with potassium ferrate, combined with advanced oxidation processes. The experimental results obtained by analysis of variance (ANOVA) for the oxidation‐coagulation‐Fenton process, evaluating the variables pH (A), Fe(VI) concentration (B), and H₂O₂ concentration (C), demonstrated that the regression equation resulting from the Response Surface Methodology (RSM) experimental design, for the quadratic model, was η_Abs (%) = 36.9– 21.58A + 8.37A² + 1.36B + 0.92B² + 1.08C + 1.52C² + 1.27AB – 1.34AC + 1.33BC. The maximum absorptiometric color reduction occurred at pH 3, with corresponding maximum amounts of iron and hydrogen peroxide. The absorptiometric color and COD reduction were 96% and 57%, respectively. For the oxidation‐coagulation‐photo‐Fenton process, the analyzed variables were pH (A), Fe(VI) concentration (B), H₂O₂ concentration (C), and temperature (D). The regression equation resulting from the quadratic model was η_Abs (%) = 38.3 – 20.2A + 8.12A² – 0.27B + 3.73B² + 0.3C + 3.6C² + 1.67D + 3.1D² + 1.72AB + 0.51AC – 1.82AD + 0.74BC – 1.11BD + 0.03CD. The ANOVA response showed that the highest absorptiometric color reduction occurred at pH 3, with respective maximum amounts of iron and hydrogen peroxide at 60°C. The maximum efficiencies achieved by the proposed treatment process for the trifluraline effluent stream were 95% and 85%, for absorptiometric color and COD reduction, respectively.     

Temporal and spatial variations in the geochemistry of major and minor particulate and selected dissolved elements of Thermaikos Gulf, Northwestern Aegean Sea

The objectives of this study were to examine both spatial and temporal changes of particulate major elements and minor metals, as well as dissolved Mn and Cd, in the waters of Thermaikos Gulf. Collections of water and suspended particulate matter (SPM), as depth profiles (5–8 depths), were undertaken at 10 principal stations, essentially on a N–S traverse of the western side of the Gulf.One of the principal aims of the study was to observe if there was any change in the patterning of the elements between the three occupations of the stations: (a) in September 2001, immediately before the commencement of trawling; (b) in October 2001, whilst fishing was active; and (c) in winter/early spring conditions (February 2002), when fishing was still active, but after a change of river/atmospheric conditions.Bottom (20 m) waters were dominated by sediment resuspension; this was identified by concentration changes in the aluminosilicate elements (e.g. Al, Ti, K, Fe) of the SPM. A two- to three-fold increase occurred between September and October, caused probably by trawling; this was sustained at the offshore stations, in February. During February, the western inshore stations showed little sediment resuspension, caused by extreme winter cooling and the sinking of water. Consequently, a N–S density discontinuity existed at all water depths, which prevented the thermohaline cyclonic circulation from penetrating into the western seaboard of the Gulf. The distribution of dissolved and particulate Mn in the lower waters was due to redox cycling of the element at the benthic boundary; this was more intense in the north, where the organic supply was higher.Biogenic element concentrations and Ca/Al, Si/Al ratios showed no evidence that trawling activity promoted higher biological production. Strong correlations of Co, Cr, Ni and V, with Al and K, showed that these elements were associated strongly with detrital aluminosilicates. However, the variable association of Cd, Pb and Zn, with K (and Al), especially in the upper waters, implied an anthropogenic source derived from the rivers and the city of Thessaloniki. Examination of the Kd's of Cd showed a two-order of magnitude decrease with depth, caused by resuspension and possible advection of relatively unpolluted sediments, into the western Gulf.