A multiscale electrical survey of a lateritic soil system in the rain forest of Cameroon

Resistivity investigations were carried out on an elementary watershed in SW Cameroon, firstly to assess the applicability of direct-current (DC) resistivity methods to solve various pedological problems in intertropical regions, and subsequently to determine the relationships between electrical resistivities and pedological properties of lateritic soil systems. The survey included measurements in pits with a small Wenner fixed-spacing array (SWA), vertical electrical soundings (VES) and vertical electrical “quick soundings” (VEQS) both using the Schlumberger configuration. The VES data were interpreted using a conventional multilayer inversion program to obtain best-fit models. Constraints to the interpretation of these data were provided by SWA and pedological information from existing observation pits. The results of the interpretation reveal five distinct geoelectrical layers overlying a resistive bedrock. The first is a thin organo-mineral upper layer with low resistivities in the range 250–450 Ωm. The second layer corresponds to micro-aggregated clayey materials and is more resistive (1300–1800 Ωm). The third represents the main part of ferruginous materials and is even more resistive (2000–4500 Ωm). The fourth corresponds to unsaturated saprolite and the last to saturated saprolite (ground water) with resistivities ranging from 800 to 1500 Ωm and from 150 to 250 Ωm, respectively. Estimates of soil volumes for the entire study area were obtained from VEQS interpretations. Most of the soil cover corresponds to saprolite (74%, being saturated by ground water), while topsoil and ferruginous materials represent 14 and 12%, respectively. Finally, geophysical results based upon 1-D inversion provide a satisfactory approximation of the various lateritic components' 3-D geometry over the watershed. The study provides original quantitative results concerning the behaviour of intertropical soil systems as well as some geomorphological keys for soil mapping at a regional scale.     

Quantitative Imaging of Stable Isotopes by Ion Microprobe

A new analytical procedure has been developed to measure oxygen isotopic ratios and, more generally, stable isotopic ratios in microparticles with a few % precision. This procedure uses ion microprobe quantitative imaging with a scanning microbeam. In this mode, ion images are acquired on the electron multiplier. Image processing allows extraction of areas of interest from the whole image and computation of isotopic ratios in the selected areas. The accuracy of this method has been tested for the analysis of the 18O/16O ratio in quartz and magnetite reference samples powdered to a grain size of 2-5 μm. A detailed study of the instrumental mass fractionation allowed an understanding of differences between classical spot analysis and scanning ion imaging, and showed that fractionation effects were related to grain topography for microparticle analysis, and to image processing or to secondary optical settings for ion imaging. The precision obtained for the measurement of ä18O was 3% for grains having a diameter of 2 μm.     

Experimental study of clinopyroxenite partial melting and the origin of ultra-calcic melt inclusions

Ultra-calcic melt inclusions (UCMI: CaO>13.5 wt% and/or CaO/Al₂O₃>0.9) are magnesian and near-primary liquids trapped in volcanic phenocrysts from mid-ocean ridges, arcs, back-arcs, and ocean islands. UCMI can be subdivided into two classes based on tectonic association and degree of silica saturation: those from arcs are nepheline normative and those from all other localities (silicic UCMI) are hypersthene normative. Silicic UCMI share a number of common features, including primitive host minerals, low alkali contents, and variable ratios of K₂O/TiO₂ ranging to high values. Their compositions are not easily derived by partial melting of mantle lherzolite. Accordingly, we have performed a series of partial melting experiments on three clinopyroxenite compositions at 1.0 to 2.0 GPa to investigate the role of partial melting of clinopyroxene-rich lithologies in silicic UCMI genesis. Estimated solidus temperatures for all three compositions are similar to those of normal peridotites, but 1.0 GPa isobaric melt productivities are higher for clinopyroxenite than for peridotite. High degree partial melts of the clinopyroxenites are ultra-calcic and have similarities to silicic UCMI, but the experiments produce ultra-calcic liquids only at melt fractions greater than 30% and temperatures higher than 1,350 °C at 1.0 GPa. Such temperatures are higher than those likely to be prevailing beneath normal mid-ocean ridges, which suggests that some or all silicic UCMI may originate by a process other than simple partial melting of clinopyroxene-rich lithologies. We consider a possible role for partial melting of depleted harzburgite in the genesis of silicic UCMI.     

The groundwater vulnerability map for the Flemish region: its principles and uses

Fobe, B. and Goossens, M., 1990. The groundwater vulnerability map for the Flemish region: its principles and uses. Eng. Geol., 29: 355–363.

The vulnerability map of the groundwater for the Flemish region demonstrates the possible risk for contamination of the groundwater in the upper aquifer of economical value. The map was ordered by the Flemish government and distributed among the people working in the environmental sector. The vulnerability map, in scale 1/100,000, is based on static factors, like the lithology of the aquifer and its possible coverlayers and the depth of the water table. The map will serve as a tool for proper management of the groundwater. Because of its smaller scale, the document will be used to determine areas where particular regulations and actions for the protection of groundwater are necessary.

Some of the data presented by the map suggest a safer situation than actually present. This is because the compilation followed strictly the principles of the legend. In the future, care should be taken to avoid such ambiguous situations on a map that is available for the public.

Plans exist to start with the compilation of dynamic vulnerability maps. One experimental project is already finished. This study and other recent scientific research gave experience about the influence of topography on the recharge of groundwater. It will be necessary to review the risk of groundwater contamination in some of the areas on the vulnerability map, especially in sandy hill ridges.     

A systematic investigation of optimal carrier-phase combinations for modernized triple-frequency GPS

The upcoming modernization of the GPS signals will allow for measurements on an additional third frequency L5 located at 1176.45 MHz. To take advantage of carrier-phase measurements on this new signal, the strategies for integer ambiguity resolution, required for centimeter-level accuracy, may need to be revised. The Least-squares Ambiguity Decorrelation Adjustment method remains perhaps the most powerful tool for finding the best combinations based on a complete decorrelation of the variance–covariance matrix related to the ambiguities. However, the computational load of that method plus the opportunity to comprehensively study the interaction of multiple frequencies suggest a reconsideration of approaches using predefined combinations between frequencies is not out of place. In this paper a systematic investigation is made of all possible triple-frequency geometry-free carrier-phase combinations which retain the integer nature of the ambiguities. The concept of the lane-number is presented to unambiguously describe the wavelength of a particular combination. The propagation of the observation noise and of the ionospheric bias on these combinations is presented. These noise and ionospheric amplification factors are analysed with respect to the resulting wavelength, in an effort to highlight optimal combinations characterized by a long wavelength, low noise and limited ionospheric impact.     

Oxygen isotope heterogeneity and disequilibria of olivine crystals in large volume Holocene basalts from Iceland: Evidence for magmatic digestion and erosion of Pleistocene hyaloclastites

This work considers petrogenesis of the largest Holocene basaltic fissure eruptions of Iceland, which are also the largest in the world: Laki (1783-84 AD, 15 km³), Eldgjá (934 AD, 18 km³), Veidivötn (900, 1480 AD, multiple eruptions, >2 km³), Núpahraun (ca. 4000 BP, >1 km³) and Thjórsárhraun (ca 8000 BP, >20 km³). We present oxygen isotope laser fluorination analyses of 55 individual and bulk olivine crystals, coexisting individual and bulk plagioclase phenocrysts, and their host basaltic glasses with average precision of better than 0.1‰ (1SD). We also report O isotope analyses of cores and rims of 61 olivine crystals by SIMS with average precision on single spots of 0.24‰ (1SD) in 13 samples coupled with electron microprobe data for major and trace elements in these olivines. Within each individual sample, we have found that basaltic glass is relatively homogeneous with respect to oxygen isotopes, plagioclase phenocrysts exhibit crystal to crystal variability, while individual olivines span from the values in equilibrium with the low-δ¹⁸O matrix glass to those being three permil higher in δ¹⁸O than the equilibrium. Olivine cores with maximum value of 5.2‰ are found in many of these basalts and suggest that the initial magma was equilibrated with normal-δ¹⁸O mantle. No olivines or their intracrystalline domains are found with bulk or spot value higher than those found in MORB olivines. The δ¹⁸O variability of 0.3-3‰ exists for olivine grains from different lavas, and variable core-to-rim oxygen isotopic zoning is present in selected olivine grains. Many olivines in the same sample are not zoned, while a few grains are zoned with respect to oxygen isotopes and exhibit small core-to-core variations in Fe-Mg, Ni, Mn, Ca. Grains that are zoned in both Mg# and δ¹⁸O exhibit positive correlation of these two parameters. Electron microprobe analysis shows that most olivines equilibrated with the transporting melt, and thin Fe-richer rim is present around many grains, regardless of the degree of olivine-melt oxygen isotope disequilibrium.The preservation of isotopic and compositional zoning in selected grains, and subtle to severe Δ¹⁸O (melt-olivine) and Δ¹⁸O (plagioclase-olivine) disequilibria suggests rather short crystal residence times of years to centuries. Synglacially-altered upper crustal, tufaceous hyaloclastites of Pleistocene age serve as a viable source for low-δ¹⁸O values in Holocene basalts through assimilation, mechanical and thermal erosion, and devolatilization of stoped blocks. Cumulates formed in response to cooling during assimilation, and xenocrysts derived from hyaloclastites, contribute to the diverse δ¹⁸O crystalline cargo. The magma plumbing systems under each fissure are likely to include a network of interconnected dikes and sills with high magma flow rates that contribute to the efficacy of magmatic erosion of large quantities (10-60% mass) of hyaloclastites required by isotopic mass balance.Olivine diversity and the pervasive lack of phenocryst-melt oxygen isotopic equilibrium suggest that a common approach of analyzing bulk olivine for oxygen isotopes, as a proxy for the basaltic melt or to infer mantle δ¹⁸O value, needs to proceed with caution. The best approach is to analyze olivine crystals individually and demonstrate their equilibrium with matrix.     

Reconstructing Phreatic Palaeogroundwater Levels in a Geoarchaeological Context: A Case Study in Flanders,Belgium

The complex debate on prehistoric settlement decisions is no longer tackled from a purely archaeological perspective but from a more landscape‐oriented manner combined with archaeological evidence. Therefore, reconstruction of several components of the former landscape is needed. Here, we focus on the reconstruction of the groundwater table based on modeling. The depth of the phreatic aquifer influences, for example, soil formation processes and vegetation type. Furthermore, it directly influences settlement by the wetness of a site. Palaeogroundwater modeling of the phreatic aquifer was carried out to produce a series of full‐coverage maps of the mean water table depth between 12.7 ka and the middle of the 20th century (1953) in Flanders, Belgium. The research focuses on the reconstruction of the input data and boundary conditions of the model and the model calibration. The model was calibrated for the 1924–1953 time period using drainage class maps. Archaeological site data and podzol occurrence data act as proxies for local drainage conditions over periods in the past. They also served as a control on the simulated phreatic palaeogroundwater levels. Model quality testing on an independent validation data set showed that the model predicts phreatic water table levels at the time of soil mapping well (mean error of 1.8 cm; root mean square error of 65.6 cm). Simulated hydrological conditions were in agreement with the occurrence of archaeological sites of Mesolithic to Roman age at 96% of the validation locations, and also with the occurrence of well‐drained podzols at 97% of the validation locations.     

Turbidity as a proxy for total suspended solids (TSS) and particle facilitated pollutant transport in catchments

Transport of hydrophobic organic pollutants in rivers is mainly coupled to transport of suspended particles. Turbidity measurements are often used to assess the amount of suspended solids in water. In this study, a monitoring campaign is presented where the total concentration of polycyclic aromatic hydrocarbons (PAHs), the amount of total suspended solids (TSS), and turbidity was measured in water samples from five neighboring catchments in southwest Germany. Linear correlations of turbidity and TSS were obtained which were in close agreement to the literature data. From linear regressions of turbidity versus total PAH concentrations in water, mean concentrations of PAH on suspended particles could be calculated and these varied by catchment. These values furthermore comprise a robust measure of the average sediment quality in a given catchment. Since in the catchments investigated in this study, PAH concentrations on suspended particles were stable over a large turbidity range (1–114 Nephelometric Turbidity Units), turbidity could be used as a proxy for total PAHs and likely other highly hydrophobic organic pollutants in river water if the associated correlations are established. Based on that, online monitoring of turbidity (e.g., by optical backscattering sensors) seems very promising to determine annual pollutant fluxes.