Evidence of NAO control on subsurface ice accumulation in a 1200 yr old cave-ice sequence, St. Livres ice cave, Switzerland

Mid-latitude ice caves are assumed to be highly sensitive to climatic changes and thus represent a potentially interesting environmental archive. Establishing a precise chronology is, however, a prerequisite for the understanding of processes driving the cave-ice mass balance and thus allows a paleoenvironmental interpretation. At St. Livres ice cave (Jura Mountains, Switzerland), subfossil trees and organic material are abundant in the cave-ice deposit, therefore allowing the dating of individual ice layers. The dendrochronological analysis of 45 subfossil samples of Norway spruce (Picea abies (L.) Karst.) from the overhanging front of the ice outcrop as well as the dating of seven wood samples with ¹⁴C dating allowed for a reconstruction of the St. Livres cave-ice sequence and for the determination of periods of ice accumulation and ablation. Results suggest a maximal age of 1200 ± 50 ¹⁴C yr BP for the observed ice sequence and indicate the presence of four major deposition gaps dated to the 14th, 15th, mid-19th and late 19th century, which can be related with periods of positive North Atlantic Oscillation anomalies (NAO+) over the winter half-year and/or anthropogenic cave-ice abstraction. Similarly, there is evidence that periods of cave-ice accumulation as observed between AD 1877-1900 and AD 1393-1415 would correspond with phases of negative NAO indices. Cave ice represents therefore an original climate archive for the winter half-year and is complementary to other continental proxies recording preferentially summer conditions (e.g., tree rings, varves).     

激光剥蚀-等离子体质谱技术及其在地球化学宇宙化学和环境研究中的应用

激光剥蚀-等离子体质谱(LA-ICPMS)已成为地球化学、宇宙化学和环境研究领域元素和同位素原位分析最重要的技术之一。文章介绍了多种类型的质谱仪及其使用的激光器。用途最广的LA-ICPMS仪器之一是单接收器扇形磁场质谱仪,配有Nd:YAG激光剥蚀系统(激光波长分为193 nm和213 nm两种),MPI Mainz实验室使用的就是这套系统,文章对此作一详细介绍。文中阐述了数据优化技术及其多种校正过程;介绍LA-ICPMS在痕量元素和同位素分析领域的一些应用,包括参考物质的研制,Hawaiian玄武岩、Martian陨石、生物骨针和珊瑚虫中痕量元素分析及熔融包裹体和富钙-铝碳质球粒陨石中的铅和锶同位素测量。     

Palaeoglaciation of Bayan Har Shan,northeastern Tibetan Plateau: glacial geology indicates maximum extents limited to ice cap and ice field scales

Key locations within an extensive area of the northeastern Tibetan Plateau, centred on Bayan Har Shan, have been mapped to distinguish glacial from non‐glacial deposits. Prior work suggests palaeo‐glaciers ranging from valley glaciers and local ice caps in the highest mountains to a regional or even plateau‐scale ice sheet. New field data show that glacial deposits are abundant in high mountain areas in association with large‐scale glacial landforms. In addition, glacial deposits are present in several locations outside areas with distinct glacial erosional landforms, indicating that the most extensive palaeo‐glaciers had little geomorphological impact on the landscape towards their margins. The glacial geological record does indicate extensive maximum glaciation, with local ice caps covering entire elevated mountain areas. However, absence of glacial traces in intervening lower‐lying plateau areas suggests that local ice caps did not merge to form a regional ice sheet on the northeastern Tibetan Plateau around Bayan Har Shan. No evidence exists for past ice sheet glaciation. Copyright © 2009 John Wiley & Sons, Ltd.     

Oxygen isotopic compositions of chondrules: Implications for evolution of oxygen isotopic reservoirs in the inner solar nebula

We review the oxygen isotopic compositions of minerals in chondrules and compound objects composed of a chondrule and a refractory inclusion, and bulk oxygen isotopic compositions of chondrules in unequilibrated ordinary, carbonaceous, enstatite, and Kakangari-like chondrites, focusing on data acquired using secondary ion mass-spectrometry and laser fluorination coupled with mass-spectrometry over the last decade. Most ferromagnesian chondrules from primitive (unmetamorphosed) chondrites are isotopically uniform (within 3–4‰ in Δ¹⁷O) and depleted in ¹⁶O (Δ¹⁷O>−7‰) relative to amoeboid olivine aggregates (AOAs) and most calcium–aluminum-rich inclusions (CAIs) (Δ¹⁷O<−20‰), suggesting that these classes of objects formed in isotopically distinct gaseous reservoirs, ¹⁶O-poor and ¹⁶O-rich, respectively. Chondrules uniformly enriched in ¹⁶O (Δ¹⁷O<−15‰) are exceptionally rare and have been reported only in CH chondrites. Oxygen isotopic heterogeneity in chondrules is mainly due to the presence of relict grains. These appear to consist of chondrules of earlier generations and rare refractory inclusions; with rare exceptions, the relict grains are ¹⁶O-enriched relative to chondrule phenocrysts and mesostasis. Within a chondrite group, the magnesium-rich (Type I) chondrules tend to be ¹⁶O-enriched relative to the ferrous (Type II) chondrules. Aluminum-rich chondrules in ordinary, enstatite, CR, and CV chondrites are generally ¹⁶O-enriched relative to ferromagnesian chondrules. No systematic differences in oxygen isotopic compositions have been found among these chondrule types in CB chondrites. Aluminum-rich chondrules in carbonaceous chondrites often contain relict refractory inclusions. Aluminum-rich chondrules with relict CAIs have heterogeneous oxygen isotopic compositions (Δ¹⁷O ranges from −20‰ to 0‰). Aluminum-rich chondrules without relict CAIs are isotopically uniform and have oxygen isotopic compositions similar to, or approaching, those of ferromagnesian chondrules. Phenocrysts and mesostases of the CAI-bearing chondrules show no clear evidence for ¹⁶O-enrichment compared to the CAI-free chondrules. Spinel, hibonite, and forsterite of the relict refractory inclusions largely retained their original oxygen isotopic compositions. In contrast, plagioclase and melilite of the relict CAIs experienced melting and ¹⁶O-depletion to various degrees, probably due to isotopic exchange with an ¹⁶O-poor nebular gas. Several igneous CAIs experienced isotopic exchange with an ¹⁶O-poor nebular gas during late-stage remelting in the chondrule-forming region. On a three-isotope diagram, bulk oxygen isotopic compositions of most chondrules in ordinary, enstatite, and carbonaceous chondrites plot above, along, and below the terrestrial fractionation line, respectively. Bulk oxygen isotopic compositions of chondrules in altered and/or metamorphosed chondrites show evidence for mass-dependent fractionation, reflecting either interaction with a gaseous/fluid reservoir on parent asteroids or open-system thermal metamorphism. Bulk oxygen isotopic compositions of chondrules and oxygen isotopic compositions of individual minerals in chondrules and refractory inclusions from primitive chondrites plot along a common line of slope of 1, suggesting that only two major reservoirs (gas and solids) are needed to explain the observed variations. However, there is no requirement that each had a permanently fixed isotopic composition. The absolute (²⁰⁷Pb–²⁰⁶Pb) and relative (²⁷Al–²⁶Mg) chronologies of CAIs and chondrules and the differences in oxygen isotopic compositions of most chondrules (¹⁶O-poor) and most refractory inclusions (¹⁶O-rich) can be interpreted in terms of isotopic self-shielding during UV photolysis of CO in the initially ¹⁶O-rich (Δ¹⁷O−25‰) parent molecular cloud or protoplanetary disk. According to these models, the UV photolysis preferentially dissociates C¹⁷O and C¹⁸O in the parent molecular cloud and in the peripheral zones of the protoplanetary disk. If this process occurs in the stability field of water ice, the released atomic ¹⁷O and ¹⁸O are incorporated into water ice, while the residual CO gas becomes enriched in ¹⁶O. During the earliest stages of evolution of the protoplanetary disk, the inner solar nebula had a solar H₂O/CO ratio and was ¹⁶O-rich. During this time, AOAs and the ¹⁶O-rich CAIs and chondrules formed. Subsequently, the inner solar nebula became H₂O- and ¹⁶O-depleted, because ice-rich dust particles, which were depleted in ¹⁶O, agglomerated outside the snowline (5 AU), drifted rapidly towards the Sun and evaporated. During this time, which may have lasted for 3 Myr, most chondrules and the ¹⁶O-depleted igneous CAIs formed. We infer that most chondrules formed from isotopically heterogeneous, but ¹⁶O-depleted precursors, and experienced isotopic exchange with an ¹⁶O-poor nebular gas during melting. Although the relative roles of the chondrule precursor materials and gas–melt isotopic exchange in establishing oxygen isotopic compositions of chondrules have not been quantified yet, mineralogical, chemical, and isotopic evidence indicate that Type I chondrules may have formed in chemical and isotopic equilibrium with nebular gas of variable isotopic composition. Whether these variations were spatial or temporal are not known yet.     

Flow velocity profiles in the Lower Scheldt estuary

Recent acoustic Doppler current profiler (ADCP)-measurements in the Scheldt estuary near Antwerp, Belgium, revealed anomalous, i.e. anti-clockwise circulations in a left bend during the major part of the flood period; these circulations were established shortly after the turn of the tide. During ebb, anti-clockwise circulations persisted, as predicted by classical theory. These data were analysed with a 3D and a 1DV-model. The 3D simulations reveal that the anomalous circulations are found when salinity is included in the computations—without salinity “normal” circulations were found. From analytical and 1DV simulations, it is concluded that a longitudinal salinity gradient ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ may induce a near-bed maximum in flow velocity reversing the direction of the secondary currents. The 1DV-model was then used to assess the contribution of various processes one by one. It was found that because of a reduction in vertical mixing, the vertical velocity profile is not at equilibrium during the first phase of accelerating tide, further enhancing the effects of ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ . A small vertical salinity gradient ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial z}}} \right. \kern-0em} {\partial z}$ appeared to have a very large effect as the crosscurrents of the secondary circulations induced by ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ became an order of larger magnitude. However, at the site under consideration, the effects of transverse salinity gradients, generated by differential advection in the river bend, were dominant: adverse directions of the secondary circulations were found even when the vertical velocity profile became more regular with a more or less logarithmic shape, i.e. when the effects of ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ and ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial z}}} \right. \kern-0em} {\partial z}$ did not play a dominant role anymore. It is argued that data on the secondary velocity structure, which can be measured easily owing to today’s developments in ADCP equipment, may serve as an indicator for the accuracy at which the salinity field is computed with 3D numerical models. Moreover, the large effect of the salinity structure on the velocity field must have a large impact on the morphological development of estuaries, which should therefore be accounted for in morphological modelling studies.     

Response of the meridional overturning circulation to variable buoyancy forcing in a double hemisphere basin

We consider how a highly idealized double-hemisphere basin responds to a zonally constant restoring surface temperature profile that oscillates in time, with periods ranging from 0.5 to 32,000 years. In both hemispheres, the forcing is similar but can be either in phase or out of phase. The set-up is such that the Northern Hemisphere always produces the densest waters. The model’s meridional overturning circulation (MOC) exhibits a strong response in both hemispheres on decadal to multi-millennial timescales. The amplitude of the oscillations reaches up to 140% of the steady-state maximum MOC and exhibits resonance-like behaviour, with a maximum at centennial to millennial forcing periods. When the forcing is in phase between the Northern and Southern Hemispheres, there is a marked decrease in the amplitude of the MOC response as the forcing period is increased beyond the resonance period. In this case the resonance-like behaviour is identical to the one we found earlier in a single-hemisphere model and occurs for the same reasons. When the forcing is out of phase between the Northern and Southern Hemispheres, the amplitude of the MOC response is substantially greater for long forcing periods (millennial and longer), particularly in the Southern Hemisphere. This increased MOC amplitude occurs because for an out of phase forcing, either the northern or the southern deep water source is always active, leading to generally colder bottom waters and thus greater stratification in the opposite hemisphere. This increased stratification in turn stabilises the water column and thus reduces the strength of the weaker overturning cell. The interaction of the two hemispheres leads to response timescales of the deep ocean at half the forcing period. Our results suggest a possible explanation for the half-precessional time scale observed in the deep Atlantic Ocean palaeo-temperature record.     

The Effects of Building Representation and Clustering in Large-Eddy Simulations of Flows in Urban Canopies

We perform large-eddy simulations of neutral atmospheric boundary-layer flow over a cluster of buildings surrounded by relatively flat terrain. The first investigated question is the effect of the level of building detail that can be included in the numerical model, a topic not yet addressed by any previous study. The simplest representation is found to give similar results to more refined representations for the mean flow, but not for turbulence. The wind direction on the other hand is found to be important for both mean and turbulent parameters. As many suburban areas are characterised by the clustering of buildings and homes into small areas separated by surfaces of lower roughness, we look at the adjustment of the atmospheric surface layer as it flows from the smoother terrain to the built-up area. This transition has unexpected impacts on the flow; mainly, a zone of global backscatter (energy transfer from the turbulent eddies to the mean flow) is found at the upstream edge of the built-up area.     

Obduction triggered by regional heating during plate reorganization

The reason for obduction, or tectonic transport of oceanic lithosphere onto continents, is investigated by two‐dimensional thermo‐mechanical numerical modelling based on the geology of the Anatolia–Lesser Caucasus ophiolites. Heating of the oceanic domain and extension induced by far‐field plate kinematics appear to be essential for the obduction of ~80‐Ma‐old oceanic crust over distances exceeding 200 km. Heating of the oceanic lithosphere by mantle upwelling is evidenced by a thick alkaline volcanic series emplaced on top of the oceanic crust 10–20 Ma before obduction, at the onset of Africa–Eurasia convergence. Regional heating reduced the negative buoyancy and strength of the magmatically old lithosphere. Extension facilitated the propagation of obduction by reducing the mantle lithosphere thickness, which led to the exhumation of eclogite‐free continental crust previously underthrusted beneath the ophiolites. This extensional event is ascribed to far‐field plate kinematics resulting from renewed Neotethys oceanic subduction beneath Eurasia.