Crustal scale balanced cross-sections of the Pyrenees; discussion

From surface and subsurface data, line-length and area balancing were used to construct four balanced and restored sections of the Pyrenees. In the Mesozoic cover, a thin-skinned tectonic model is used. In the basement an anticlinal stack geometry is applied for the foreland part of the thrust nappes. We present and discuss three possible models for the deep structures of the belt: a thin-skinned tectonic model, a thick-skinned tectonic model and an inhomogeneous strain model. The thrusts steepen downwards and the displacements die out in ductile deformation deep in the section. Therefore, we use the inhomogeneous strain model and we equal-area balance the surface of the continental crust.Hanging-wall sequence diagrams are constructed taking into account (1) the strong N-S thickness variations of the Mesozoic cover related to the Cretaceous drift of Spain and (2) the related crustal thinning of the North Pyrenean Zone superimposed upon a previous late Hercynian rise of the lower crust.The Moho step at the vertical of the North Pyrenean Fault results from the thinning of the North Pyrenean Zone. The thickening of both the Axial Zone and the North Pyrenean Zone during the Eocene compressional event preserved the step geometry.Calculated values of the minimum shortening range from 55 km in the western part of the belt to 80 km in the eastern part. Most of the shortening occurs south of the North Pyrenean Fault in the eastern part (Axial Zone) and north of the North Pyrenean Fault in the western part (Labourd thrust).     

18O/16O ratios in lunar fines and rocks

¹⁸O/¹⁶O ratios have been measured for Luna 20 and Apollo 15 fines and Apollo 15 rocks.Isotopic composition and fractionation between minerals are compared with previous results.Partial fluorination experiments on Luna 20 soil and Apollo 15021 extreme fines show large¹⁸O enrichments in grain surfaces. These results are discussed.     

18O16O ratios in Luna 16 fines

Partial fluorination experiments developed on a 26 mg sample of Luna 16 fines show a big ¹⁸O enrichment in the first oxygen evolved similar to those observed by Epstein and Taylor on Apollo samples and probably related to the high solar wind content of this sample.     

Statistics for Modeling Heavy Tailed Distributions in Geology: Part I. Methodology

Many natural phenomena exhibit size distributions that are power laws or power law type distributions. Power laws are specific in the sense that they can exhibit extremely long or heavy tails. The largest event in a sample from such distribution usually dominates the underlying physical or generating process (floods, earthquakes, diamond sizes and values, incomes, insurance). Often, the practitioner is faced with the difficult problem of predicting values far beyond the highest sample value and designing his system either to profit from them, or to protect against extreme quantiles. In this paper, we present a novel approach to estimating such heavy tails. The estimation of tail characteristics such as the extreme value index, extreme quantiles, and percentiles (rare events) is shown to depend primarily on the number of extreme data that are used to model the tail. Because only the most extreme data are useful for studying tails, thresholds must be selected above which the data are modeled as power laws. The mean square error (MSE) is used to select such thresholds. A semiparametric bootstrap method is developed to study estimation bias and variance and to derive confidence limits. A simulation study is performed to assess the accuracy of these confidence limits. The overall methodology is applied to the Harvard Central Moment Tensor catalog of global earthquakes.     

Last glacial maximum climate inferences from cosmogenic dating and glacier modeling of the western Uinta ice field, Uinta Mountains, Utah

During the last glacial maximum (LGM), the western Uinta Mountains of northeastern Utah were occupied by the Western Uinta Ice Field. Cosmogenic ¹⁰Be surface-exposure ages from the terminal moraine in the North Fork Provo Valley and paired ²⁶Al and ¹⁰Be ages from striated bedrock at Bald Mountain Pass set limits on the timing of the local LGM. Moraine boulder ages suggest that ice reached its maximum extent by 17.4 ± 0.5 ka (± 2σ). ¹⁰Be and ²⁶Al measurements on striated bedrock from Bald Mountain Pass, situated near the former center of the ice field, yield a mean ²⁶Al/¹⁰Be ratio of 5.7 ± 0.8 and a mean exposure age of 14.0 ± 0.5 ka, which places a minimum-limiting age on when the ice field melted completely. We also applied a mass/energy-balance and ice-flow model to investigate the LGM climate of the western Uinta Mountains. Results suggest that temperatures were likely 5 to 7°C cooler than present and precipitation was 2 to 3.5 times greater than modern, and the western-most glaciers in the range generally received more precipitation when expanding to their maximum extent than glaciers farther east. This scenario is consistent with the hypothesis that precipitation in the western Uintas was enhanced by pluvial Lake Bonneville during the last glaciation.     

Hydrogen partitioning between melt,clinopyroxene, and garnet at 3 GPa in a hydrous MORB with 6 wt.% H<Subscript>2</Subscript>O

To understand partitioning of hydrogen between hydrous basaltic and andesitic liquids and coexisting clinopyroxene and garnet, experiments using a mid-ocean ridge basalt (MORB) + 6 wt.% H₂O were conducted at 3 GPa and 1,150–1,325°C. These included both isothermal and controlled cooling rate crystallization experiments, as crystals from the former were too small for ion microprobe (SIMS) analyses. Three runs at lower bulk water content are also reported. H₂O was measured in minerals by SIMS and in glasses by SIMS, Fourier Transform infrared spectroscopy (FTIR), and from oxide totals of electron microprobe (EMP) analyses. At 3 GPa, the liquidus for MORB with 6 wt.% H₂O is between 1,300 and 1,325°C. In the temperature interval investigated, the melt proportion varies from 100 to 45% and the modes of garnet and clinopyroxene are nearly equal. Liquid composition varies from basaltic to andesitic. The crystallization experiments starting from above the liquidus failed to nucleate garnets, but those starting from below the liquidus crystallized both garnet and clinopyroxene. SIMS analyses of glasses with >7 wt.% H₂O yield spuriously low concentrations, perhaps owing to hydrogen degassing in the ultra-high vacuum of the ion microprobe sample chamber. FTIR and EMP analyses show that the glasses have 3.4 to 11.9 wt.% water, whilst SIMS analyses indicate that clinopyroxenes have 1,340–2,330 ppm and garnets have 98–209 ppm H₂O. D _H ^cpx−gt is 11 ± 3, D _H ^cpx−melt is 0.023 ± 0.005 and D _H ^gt−melt is 0.0018 ± 0.0006. Most garnet/melt pairs have low values of D _H ^gt−melt, but D _H ^gt−melt increases with TiO₂ in the garnet. As also found by previous studies, values of D _H ^cpx−melt increase with Al₂O₃ of the crystal. For garnet pyroxenite, estimated values of D _H ^{pyroxenite−melt} decrease from 0.015 at 2.5 GPa to 0.0089 at 5 GPa. Hydration will increase the depth interval between pyroxenite and peridotite solidi for mantle upwelling beneath ridges or oceanic islands. This is partly because the greater pyroxene/olivine ratio in pyroxenite will tend to enhance the H₂O concentration of pyroxenite, assuming that neighboring pyroxenite and peridotite bodies have similar H₂O in their pyroxenes. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

A laser-ablation ICP-MS study of Apollo 15 low-titanium olivine-normative and quartz-normative mare basalts

Apollo 15 low-Ti mare basalts have traditionally been subdivided into olivine- and quartz-normative basalt types, based on their different SiO₂, FeO, and TiO₂ whole-rock compositions. Previous studies have reconciled this compositional diversity by considering the olivine- and quartz-normative basalts as originating from different lunar mantle source regions. To provide new information on the compositions of Apollo 15 low-Ti mare basalt parental magmas, we report a study of major and trace-element compositions of whole rocks, pyroxenes, and other phases in the olivine-normative basalts 15016 and 15555 and quartz-normative basalts 15475 and 15499. Results show similar rare-earth-element patterns in pyroxenes from all four basalts. The estimated equilibrium parental-melt compositions from the trace-element compositions of pyroxenes are similar for 15016, 15555 and 15499. Additionally, an independent set of trace-element distribution coefficients has been determined from measured pyroxene and mesostasis compositions in sample 15499. These data suggest that fractional crystallization may be a viable alternative to compositional differences in the mantle source to explain the 25% difference in whole-rock TiO₂, and corresponding differences in SiO₂ and FeO between the Apollo 15 olivine- and quartz-normative basalts. In this model, the older (3.35 Ga) quartz-normative basalts, with lower TiO₂ experienced olivine, chromite, and Cr-ulvöspinel fractionation at ‘crustal levels’ in magma chambers or dikes, followed by limited near-surface mineral fractionation, within the lava flows. In contrast, the younger (3.25 Ga) olivine-normative basalts experienced only limited magmatic differentiation at ‘crustal-levels’, but extensive near-surface mineral fractionation to produce their evolved mineral compositions. A two-stage mineral-fractionation model is consistent with textural and mineralogical observations, as well as the mineral trace-element constraints developed by this study.     

Comparison of GRACE data and groundwater levels for the assessment of groundwater depletion in Jordan

Gravity Recovery and Climate Experiment (GRACE) derived groundwater storage (GWS) data are compared with in-situ groundwater levels from five groundwater basins in Jordan, using newly gridded GRACE GRCTellus land data. It is shown that (1) the time series for GRACE-derived GWS data and in-situ groundwater-level measurements can be correlated, with R ² from 0.55 to 0.74, (2) the correlation can be widely ascribed to the seasonal and trend component, since the detrended and deseasonalized time series show no significant correlation for most cases, implying that anomalous signals that deviate from the trend or seasonal behaviour are overlaid by noise, (3) estimates for water losses in Jordan based on the trend of GRACE data from 2003 to 2013 could be up to four times higher than previously assumed using estimated recharge and abstraction rates, and (4) a significant time-lagged cross correlation of the monthly changes in GRACE-derived groundwater storage and precipitation data was found, suggesting that the conventional method for deriving GWS from GRACE data probably does not account for the typical conditions in the study basins. Furthermore, a new method for deriving plausible specific yields from GRACE data and groundwater levels is demonstrated.