Analyses of insoluble residues of altered organic matter by C CP/MAS nuclear magnetic resonance

Alteration phenomena affecting organic matter during diagenesis frequently lead to the formation of residues almost insoluble. Data from ¹³C CP/MAS nuclear magnetic resonance analyses (NMR) of these residues have been compared to those obtained by other techniques such as elemental analysis, infrared spectroscopy, Rock-Eval pyrolysis or gas chromatography. Three examples of alteration phenomena have been chosen: the artificial and natural oxidation of coals, the biodegradation of oils and solid bitumens, and the radiolytic degradation of organic matter. NMR results and those obtained by other techniques converge on similar general conclusions. Additional information can be extracted from ¹³C NMR data: e.g. definition of the phenol/carbonyl ratio, transformation of the aromatic network and aromatic ring substitution. These comparisons are good evidence for the reliability of non-destructive analysis of the insoluble fraction of altered organic material by ¹³C CP/MAS NMR.     

The relationship betweenin situ strain relaxation and outcrop fractures in the Potsdam Sandstone,Alexandria Bay,New York

Summary In situ strain was measured by overcoring foil-resistance strain gauge rosettes bonded to five outcrops of Potsdam Sandstone near Alexandria Bay, New York. Strain relaxation magnitude and orientation correlated with the area of the intact outcrop outlined by intersecting vertical fractures. The maximum expansion occurred at the outcrop with the largest area between intersecting fractures. Outcrops with more than one set of longer, open fractures or more complicated fracture patterns have lower recoverable strains. Strain relaxation was lowest next to a postglacial pop-up. The orientation of the pop-up indicated relief of an ENE directed compression, the direction also observed as the maximum expansion at the outcrop yielding the largest strain relaxation.Lamont-Doherty Geological Observatory Contribution No. 2456.     

A mechanism for strain relaxation of barre granite: Opening of microfractures

Summary Strain relaxation in the Barre Granite and surrounding metasediments in Vermont, was measured by overcoring strain gauge rosettes bonded to outcrop surfaces. The average maximum expansion upon relieving 15.2 cm diameter cores trends N55°W, while the average maximum expansion of 7.6 cm diameter cores coaxial with 15.2 cm cores trends N70°W. The maximum strain relief of the internal overcores is normal to the microfracture fabric. Therefore, the mechanism of strain relaxation is attributed to the opening of microfractures either parallel to the rift direction of the Barre Granite or parallel to the foliation of the metasediment. The lack of parallelism between the normal to the rift plane and the maximum expansion of the initial overcore suggests an extenrally applied strain superimeposed on the strain caused by opening of microfractures.Lamont-Doherty Geological Observatory Contribution No. 2455.     

Silica standardization: a discriminant technique applied to a volcanic arc system

A classic tholeiitic, calc-alkaline, and shoshonitic island-arc sequence has developed in western Luzon, the Philippines, as a result of subduction defined by an eastward-dipping Benioff zone. A simple technique of standardizing the data allows chemical concentrations to be recast to “andesite equivalent” compositions. Based on the excellent linear correlations that exist between SiO₂ and other elements, individual analyses were standardized to 55% SiO₂ by projecting parallel to least-squares regression lines. Raw and SiO₂-standardized data were then treated by an univariate one-factor analysis of variance and a multivariate discriminant function analysis.Results of the analysis of variance indicate that at the 99% confidence level; 20 of the 27 chemical variates discriminate between at least two of the three geographically distinct magma series; SiO₂-standardized data generally discriminate better than do raw data; and K₂O, Ba, Rb, Sr, and Zr provide the best discrimination. Better classification of samples into the appropriate series is obtained from results of the discriminant function analysis using the SiO₂-standardized data rather than results using the raw data. With this standardizing technique it was possible to detect offsets of SiO₂-standardized K₂O isopleths along the Manila Bay fracture zone that correspond to offsets in contours of depths for earthquake foci.     

Attenuation of Rayleigh waves across the volcanic area of the Massif Central,France

Rayleigh wave attenuation is investigated for periods ranging from 20 to 90 s, along a 450 km-long profile following the Oligocene tensile zone of the French Massif Central. A model is deduced by inversion, assuming that the S-wave intrinsic quality factor Q_β is frequency-independent, and yields a mean value Q_β = 43 ± 10 for the first 100 km in the upper mantle. This value, far lower than the mean value obtained in Eurasia, is close to those obtained in other recent tensile areas, e.g., the western United States or mid-oceanic ridges.A velocity-depth model for S-waves, deduced in a previous study from surface-wave propagation, has been corrected for the attenuation effect. We find a discrepancy between the corrected S-model and P-wave residuals in the same area, implying that Q_β must be frequency-dependent. This can be a clue for partial melting in the upper mantle beneath this region.     

The Sm/Nd secular evolution of the continental crust and the depleted mantle

The published Nd isotopic data on rocks representative of either the continental crust or the depleted mantle are used to determine the Sm/Nd evolution of each system through time making allowance for a contribution from a primitive (chondritic) mantle. Screening using the ¹⁴⁷Sm/¹⁴⁴Nd ratio permits data of doubtful significance to be discarded. Mass balance equations describing mantle-crust exchange processes are numerically integrated. They suggest that crustal growth probably occurs through the addition of strongly LREE-enriched magmas derived from the mantle either directly (andesites) or indirectly (rhyolites). If the modern mean ¹⁴⁷Sm/¹⁴⁴Nd ratio of the crust is close to the sediment average (0.11), then progressive enrichment of LREE in the crust and depletion in the depleted mantle has occurred. If this ratio is of 0.13, then it, and the probable depleted-mantle ¹⁴⁷Sm/¹⁴⁴Nd ratio (0.26) have been constant over the last 3.8 Ga. The fraction of the total Nd (exclusive of the primitive mantle) stored in the continental crust has varied from 40% to 50% over the same period.The volume of the continents can have remained constant only if the rate of sediment reinjection into the mantle is 2.5 km³ a⁻¹ or more. For lower, probably more geologically reasonable, reinjection rates, a nearly uniform continent growth rate over the past 3.8 Ga is inferred. In all cases, the depleted mantle is continuously forming from a primitive reservoir.     

Greenland iceBe concentrations and average precipitation rates north of 40°N to 45°N

A model of¹⁰Be deposition within the subarctic and arctic is developed based on the behavior of⁹⁰Sr in the troposphere. Measured¹⁰Be fluxes, based on analyses of¹⁰Be in one year's snow fall (1979–1980) from the Dye-3 site in southwest Greenland and on published data, and predicted¹⁰Be fluxes, based on the¹⁰Be deposition model, agree. These results indicate that with regard to¹⁰Be, the troposphere north of 40°N to 45°N presently behaves as if it is well-mixed and that the average precipitation rate within that reservoir controls in large part the concentration of¹⁰Be in Greenland ice. Inversion of the Greenland ice core¹⁰Be concentration record with the aid of the model indicates: (1) that the average precipitation rate in the subarctic and arctic was lower than the present rate during the Maunder minimum of solar activity, and higher than the present rate during the Wolf and Sporer solar activity minimums; and (2) that during the Wisconsin-Holocene transition the average precipitation rate in the subarctic and arctic was about one third the present precipitation rate.