First-principles study of OH defects in zircon

The infrared spectroscopic properties of selected OH defects in zircon are investigated by first-principles calculations. The explicit treatment of the coupled nature of OH motions in the stretching modes, together with the calculation of the intensity and polarization of absorption bands, makes it possible to directly compare theoretical and experimental data. The bands observed at 3,420 cm^?1 (polarization parallel to c axis) and 3,385 cm^?1 (polarization perpendicular to c axis) in natural and synthetic samples correspond to the IR-active vibrational modes of the hydrozircon defect, that is, fully protonated Si vacancy. The broad band observed at 3,515 cm^?1 in the spectrum of zircon crystals grown in F-rich environments is consistent with the occurrence of composite (OH,F) tetrahedral defects. Calculations also show that the band observed at 3,200 cm^?1 in the spectrum of synthetic undoped samples can be ascribed to fully protonated Zr vacancies. The theoretical values of integrated absorption coefficients indicate that general correlations can be reasonably used to determine the concentration of OH groups in zircon.     

Assessing adaptive capacity within regional climate change vulnerability studies—an Alpine example

Adaptive capacity represents a crucial component in the assessment of a region’s vulnerability to climate change. The term adaptive capacity is only fuzzily defined, and determining it is difficult and often neglected in previous studies. In this paper, a newly developed adaptive capacity concept is introduced, with a respective indicator/criteria system and simple aggregation methods. The approach allows for adaptive capacity assessments at 3 levels of specificity (impact specific, sector specific and regional generic). The selection of indicators is tailor-made for Alpine regions, where the approach has been widely tested. The presented approach requires extended stakeholder involvement, namely for the evaluation of the indicators. The overall effort needed for its implementation remains reasonable. The outcome of the assessment exercise does not provide precise objective measurements, but remains an indicative estimation due to the fuzziness and complexity of the underlying concept. The conceptual approach is transferable to other mountain areas and beyond, the selection of indicators however is only valid for the Alpine region. The showcase presents results from the adaptive capacity assessment in the region of South Tyrol, where the method was carried out as part of a climate change vulnerability study. The outcomes indicate a number of issues that future actions could address in order to improve adaptive capacity in the region, namely in the field of prevention measures against meteorological extremes and natural hazards.     

Co-seismic ruptures and deformations recorded by speleothems in the epicentral zone of the Basel earthquake

Abstract

The study of growth anomalies of speleothems in a karstic environment can provide potential evidence or palaeoearthquakes. These data are used to study the recurrence times of major earthquakes in areas where evidence for historic seismicity is lacking. A study has been carried out in the epicentral area of the 1356 Basel earthquake (epicentral intensity = VII-VIII, macroseismic magnitude = 6.2). The Bättlerloch and Dieboldslöchli caves, situated in the area of greatest damage, show growth anomalies of speleothems possibly related to a seismic event (several breaks of speleothems an offsets of the axis of the regrowths). The first U/Th disequilibrum measurements by alpha spectrometry show recent ages (less than several tens of thousands of years and pro a y historic). ¹⁴C dating by AMS of carbonate laminations taken on both sides of the anomalies confirm the evidence of a seismic event around 1300 AD. More accurate datings by U/Th TIMS are carried out in order to compare the information provided by the two different dating methods. © Elsevier, Paris     

Linking the NE Anatolian and Lesser Caucasus ophiolites: evidence for large-scale obduction of oceanic crust and implications for the formation of the Lesser Caucasus-Pontides Arc

In the Lesser Caucasus and NE Anatolia, three domains are distinguished from south to north: (1) Gondwanian-derived continental terranes represented by the South Armenian Block (SAB) and the Tauride–Anatolide Platform (TAP), (2) scattered outcrops of Mesozoic ophiolites, obducted during the Upper Cretaceous times, marking the northern Neotethys suture, and (3) the Eurasian plate, represented by the Eastern Pontides and the Somkheto-Karabagh Arc. At several locations along the northern Neotethyan suture, slivers of preserved unmetamorphozed relics of now-disappeared Northern Neotethys oceanic domain (ophiolite bodies) are obducted over the northern edge of the passive SAB and TAP margins to the south. There is evidence for thrusting of the suture zone ophiolites towards the north; however, we ascribe this to retro-thrusting and accretion onto the active Eurasian margin during the latter stages of obduction. Geodynamic reconstructions of the Lesser Caucasus feature two north dipping subduction zones: (1) one under the Eurasian margin and (2) farther south, an intra-oceanic subduction leading to ophiolite emplacement above the northern margin of SAB. We extend our model for the Lesser Caucasus to NE Anatolia by proposing that the ophiolites of these zones originate from the same oceanic domain, emplaced during a common obduction event. This would correspond to the obduction of non-metamorphic oceanic domain along a lateral distance of more than 500?km and overthrust up to 80?km of passive continental margin. We infer that the missing volcanic arc, formed above the intra-oceanic subduction, was dragged under the obducting ophiolite through scaling by faulting and tectonic erosion. In this scenario part of the blueschists of Stepanavan, the garnet amphibolites of Amasia and the metamorphic arc complex of Erzincan correspond to this missing volcanic arc. Distal outcrops of this exceptional object were preserved from latter collision, concentrated along the suture zones.     

Effects of multi-annual climate variability on the hydrodynamic evolution (1833 to present) in a shallow aquifer system in northern Belgium

Abstract

Using a groundwater flow model and long historical meteorological time series data, the evolution of the groundwater flow regime in a multi-layered groundwater flow basin in northern Belgium during the last one and a half centuries (since 1833) is reconstructed. Model output parameters such as piezometric levels, depth to water table, seepage fluxes in the valleys and calculated baseflow to the river system are presented and inter-annual and decadal variations are evaluated against seasonal fluctuations. The main time-varying boundary condition in the model is the aquifer recharge which was estimated using the method of Thornthwaite and Mather based on precipitation and temperature data. The model does not take into account changes in boundary conditions due to changes in land use (deforestation, drainage of cultivated land) or groundwater exploitation. Variations in model output parameters are therefore only due to climatological forcing. Only the natural non-exploited state of the aquifer is considered. Although few historical piezometric measurements are available to verify model output, the results give an indication of the natural hydrodynamic variations on a time scale of decades.

Citation Van Camp, M., Coetsiers, M., Martens, K. & Walraevens, K. (2010) Effects of multi-annual climate variability on the hydrodynamic evolution (1833 to present) in a shallow aquifer system in northern Belgium. Hydrol. Sci. J. 55(5), 763–779.     

Evaluating model performance: towards a non-parametric variant of the Kling-Gupta efficiency

ABSTRACT

Goodness-of-fit measures are important for an objective evaluation of runoff model performance. The Kling-Gupta efficiency (R_KG), which has been introduced as an improvement of the widely used Nash-Sutcliffe efficiency, considers different types of model errors, namely the error in the mean, the variability, and the dynamics. The calculation of R_KG is implicitly based on the assumptions of data linearity, data normality, and the absence of outliers. In this study, we propose a modification of R_KG as an efficiency measure comprising non-parametric components, i.e. the Spearman rank correlation and the normalized flow–duration curve. The performances of model simulations for 100 catchments using the new measure were compared to those obtained using R_KG based on a number of statistical metrics and hydrological signatures. The new measure resulted overall in better or comparable model performances, and thus it was concluded that efficiency measures with non-parametric components provide a suitable alternative to commonly used measures.     

Doppler weather radar as a meteorite recovery tool

Abstract– We report the use of Doppler weather radar as a tool for locating meteorites, both at the time of a fall and from archived radar data. This asset is especially useful for meteorite recovery as it can provide information on the whereabouts of falling meteorites in “dark flight” portion of their descent where information on their flight paths cannot be discerned from more traditional meteorite location techniques such as eyewitness accounts. Weather radar data can provide information from detection in three distinct regimes: (A) direct detection of the rapidly moving, optically bright fireball by distant radars, (B) detection of falling debris to include hand‐sample sized rocks, and (C) detection of dust produced by detonation events that can occur tens of minutes and many kilometers laterally removed from the actual fireball locality. We present examples of each, as well as comparisons against man‐made debris from a re‐entering Soyuz rocket and the Stardust Sample Return Capsule. The use of Doppler weather radar as a supplement to traditional meteorite recovery methods holds the promise of improving both the speed and total number of meteorite recoveries, thereby increasing the number of freshly fallen meteorites for scientific study.     

Continuous monitoring of stream δ18O and δ2H and stormflow hydrograph separation using laser spectrometry in an agricultural catchment

A portable Wavelength Scanned‐Cavity Ring‐Down Spectrometer (Picarro L2120) fitted with a diffusion sampler (DS‐CRDS) was used for the first time to continuously measure δ¹⁸O and δ²H of stream water. The experiment took place during a storm event in a wet tropical agricultural catchment in north‐eastern Australia. At a temporal resolution of one minute, the DS‐CRDS measured 2160 δ¹⁸O and δ²H values continuously over a period of 36 h with a precision of ±0.08 and 0.5‰ for δ¹⁸O and δ²H, respectively. Four main advantages in using high temporal resolution stream δ¹⁸O and δ²H data during a storm event are highlighted from this study. First, they enabled us to separate components of the hydrograph, which was not possible using high temporal resolution electrical conductivity data that represented changes in solute transfers during the storm event rather than physical hydrological processes. The results from the hydrograph separation confirm fast groundwater contribution to the stream, with the first 5 h of increases in stream discharge comprising over 70% pre‐event water. Second, the high temporal resolution stream δ¹⁸O and δ²H data allowed us to detect a short‐lived reversal in stream isotopic values (δ¹⁸O increase by 0.4‰ over 9 min), which was observed immediately after the heavy rainfall period. Third, δ¹⁸O values were used to calculate a time lag of 20 min between the physical and chemical stream responses during the storm event. Finally, the hydrograph separation highlights the role of event waters in the runoff transfers of herbicides and nutrients from this heavily cultivated catchment to the Great Barrier Reef. Copyright © 2015 John Wiley & Sons, Ltd.     

Detailed seismic stratigraphy of Lago Puyehue: implications for the mode and timing of glacier retreat in the Chilean Lake District

Lago Puyehue is a glacigenic lake in the Chilean Lake District (40°S) with a complex deglaciation history. A detailed seismic–stratigraphic study of its sedimentary infill indicates a much earlier retreat of the glacier from the Lago Puyehue basin than the neighbouring glacier from the Lago Rupanco basin. Because of their close proximity, Rupanco meltwater streams played an important part in the depositional processes of Lago Puyehue. A timing discrepancy between the in‐lake ages of a sediment core and the outer‐lake ages of moraine deposits (re)opens the discussion on the timing of deglaciation in the Southern Hemisphere. Copyright © 2011 John Wiley & Sons, Ltd.