The Vicência meteorite fall: A new unshocked (S1) weakly metamorphosed (3.2) LL chondrite

The Vicência meteorite, a stone of 1.547 kg, fell on September 21, 2013, at the village Borracha, near the city of Vicência, Pernambuco, Brazil. It was recovered immediately after the fall, and our consortium study showed it to be an unshocked (S1) LL3.2 ordinary chondrite. The LL group classification is based on the bulk density (3.13 g cm^?3); the chondrule mean apparent diameter (0.9 mm); the bulk oxygen isotopic composition (δ¹⁷O = 3.768 ± 0.042‰, δ¹⁸O = 5.359 ± 0.042‰, Δ¹⁷O = 0.981 ± 0.020‰); the content of metallic Fe,Ni (1.8 vol%); the Co content of kamacite (1.73 wt%); the bulk contents of the siderophile elements Ir and Co versus Au; and the ratios of metallic Fe⁰/total iron (0.105) versus total Fe/Mg (1.164), and of Ni/Mg (0.057) versus total Fe/Mg. The petrologic type 3.2 classification is indicated by the beautifully developed chondritic texture, the standard deviation (~0.09) versus mean Cr₂O₃ content (~0.14 wt%) of ferroan olivine, the TL sensitivity and the peak temperature and peak width at half maximum, the cathodoluminescence properties of chondrules, the content of trapped ¹³²Xe_tr (0.317 × 10^?8cm³STP g^?1), and the Raman spectra for organic material in the matrix. The cosmic ray exposure age is ~72 Ma, which is at the upper end of the age distribution of LL group chondrites. The meteorite is unusual in that it contains relatively large, up to nearly 100 μm in size, secondary fayalite grains, defined as olivine with Fa_>75, large enough to allow in situ measurement of oxygen and Mn‐Cr isotope systematics with SIMS. Its oxygen isotopes plot along a mass‐dependent fractionation line with a slope of ~0.5 and Δ¹⁷O of 4.0 ± 0.3‰, and are similar to those of secondary fayalite and magnetite in the unequilibrated chondrites EET 90161, MET 96503, and Ngawi. These data suggest that secondary fayalite in Vicência was in equilibrium with a fluid with a Δ¹⁷O of ~4‰, consistent with the composition of the fluid in equilibrium with secondary magnetite and fayalite in other unequilibrated ordinary chondrites. Secondary fayalite and the chondrule olivine phenocrysts in Vicência are not in isotopic equilibrium, consistent with low‐temperature formation of fayalite during aqueous alteration on the LL parent body. That alteration, as dated by the ⁵³Mn‐⁵³Cr chronology age of secondary fayalite, took place $4.0{}_{?1.1}^{+1.4}$ Ma after formation of CV CAIs when anchored to the quenched angrite D'Orbigny.     

Pillars of Heaven

Sometimes the most beautiful things are the hardest to understand. Pillars like those of the Eagle Nebula form at the boundary between some of the hottest (10000~K) and coldest (10~K) gas in the Galaxy. Many physical processes come into play in the birth and growth of such gaseous pillars: hydrodynamic instability, photoionization, ablation, recombination, molecular heating and cooling, and probably magnetic fields. High-quality astronomical observations, quantitative numerical simulations, and scaled laser experiments provide a powerful combination for understanding their formation and evolution. We put our most recent hydrodynamic model to the test, by creating simulated observations from it and comparing them directly to the actual radioastronomical observations. Successfully reproducing major characteristics of the observations in this manner is an important step in designing appropriate laser experiments.     

Occurrence of phthalate diesters in rivers of the Paris district (France)

The occurrence and fate of six phthalate esters were investigated in the River Seine and two tributaries in the Paris area, at six sites from upstream to downstream, throughout different seasons, with special attention given to a flood episode. At all sites, except the River Marne, whatever the period, diethylhexyl phthalate (DEHP) displayed the highest concentration (0·323–0·779 µg l^?1 as mean values), followed by di‐n‐butyl phthalate (DnBP; 0·211–0·526 µg l^?1 as mean values), which is consistent with the production pattern. High phthalate concentrations appeared to be related to population density and industrial distribution. The strongest values were located downstream from wastewater treatment plant effluent inputs. Seasonal variations were closely related to river flow and air and water temperature. The annual evolution of phthalates was linked to the hydrological conditions. During the flood episode at Paris, the DEHP concentration displayed a sharp increase (260 to 1123 ng l^?1) occurring 9 days before the flood peak. The simultaneous fluctuations of NH₄, typical of domestic origin, and of DEHP suggests a similar origin from combined sewer overflows for both compounds. Other elevated values corresponded to the highest precipitation amounts, and demonstrated the contribution of non‐point‐source runoff and wastewater overflow to DEHP inputs. The DEHP concentration relationship with river flow displayed a clockwise hysteresis loop, corresponding to a ‘first‐flush’ effect in which the finite supplies are swept along in the early stage of the flood. Annual fluxes for 2004 at Paris were 2257 kg of DEHP and 1613 kg of DnBP. The flood period seemed to have a minor impact on annual phthalate transport (29·5% and 41% of the total for DEHP and for DnBP, respectively), which is contrary to annual suspended solids transport (69%). Copyright © 2007 John Wiley & Sons, Ltd.     

Nonlinear Force-Free Modeling of Coronal Magnetic Fields Part I: A Quantitative Comparison of Methods

We compare six algorithms for the computation of nonlinear force-free (NLFF) magnetic fields (including optimization, magnetofrictional, Grad–Rubin based, and Green's function-based methods) by evaluating their performance in blind tests on analytical force-free-field models for which boundary conditions are specified either for the entire surface area of a cubic volume or for an extended lower boundary only. Figures of merit are used to compare the input vector field to the resulting model fields. Based on these merit functions, we argue that all algorithms yield NLFF fields that agree best with the input field in the lower central region of the volume, where the field and electrical currents are strongest and the effects of boundary conditions weakest. The NLFF vector fields in the outer domains of the volume depend sensitively on the details of the specified boundary conditions; best agreement is found if the field outside of the model volume is incorporated as part of the model boundary, either as potential field boundaries on the side and top surfaces, or as a potential field in a skirt around the main volume of interest. For input field (B) and modeled field (b), the best method included in our study yields an average relative vector error E_n = 〈 |B−b|〉/〈 |B|〉 of only 0.02 when all sides are specified and 0.14 for the case where only the lower boundary is specified, while the total energy in the magnetic field is approximated to within 2%. The models converge towards the central, strong input field at speeds that differ by a factor of one million per iteration step. The fastest-converging, best-performing model for these analytical test cases is the Wheatland, Sturrock, and Roumeliotis (2000) optimization algorithm as implemented by Wiegelmann (2004).