Influence of biogenic Fe(II) on the extent of microbial reduction of Fe(III) in clay minerals nontronite, illite, and chlorite

Microbial reduction of Fe(III) in clay minerals is an important process that affects properties of clay-rich materials and iron biogeochemical cycling in natural environments. Microbial reduction often ceases before all Fe(III) in clay minerals is exhausted. The factors causing the cessation are, however, not well understood. The objective of this study was to assess the role of biogenic Fe(II) in microbial reduction of Fe(III) in clay minerals nontronite, illite, and chlorite. Bioreduction experiments were performed in batch systems, where lactate was used as the sole electron donor, Fe(III) in clay minerals as the sole electron acceptor, and Shewanella putrefaciens CN32 as the mediator with and without an electron shuttle (AQDS). Our results showed that bioreduction activity ceased within two weeks with variable extents of bioreduction of structural Fe(III) in clay minerals. When fresh CN32 cells were added to old cultures (6 months), bioreduction resumed, and extents increased. Thus, cessation of Fe(III) bioreduction was not necessarily due to exhaustion of bioavailable Fe(III) in the mineral structure, but changes in cell physiology or solution chemistry, such as Fe(II) production during microbial reduction, may have inhibited the extent of bioreduction. To investigate the effect of Fe(II) inhibition on CN 32 reduction activity, a typical bioreduction process (consisting of lactate, clay, cells, and AQDS in a single tube) was separated into two steps: (1) AQDS was reduced by cells in the absence of clay; (2) Fe(III) in clays was reduced by biogenic AH₂DS in the absence of cells. With this method, the extent of Fe(III) reduction increased by 45-233%, depending on the clay mineral involved. Transmission electron microscopy observation revealed a thick halo surrounding cell surfaces that most likely resulted from Fe(II) sorption/precipitation. Similarly, the inhibitory effect of Fe(II) sorbed onto clay surfaces was assessed by presorbing a certain amount of Fe(II) onto clay surfaces followed by AH₂DS reduction of Fe(III). The reduction extent consistently decreased with an increasing amount of presorbed Fe(II). The relative reduction extent [i.e., the reduction extent normalized to that when the amount of presorbed Fe(II) was zero] was similar for all clay minerals studied and showed a systematic decrease with an increasing clay-presorbed Fe(II) concentration. These results suggest a similar inhibitory effect of clay-sorbed Fe(II) for different clay minerals. An equilibrium thermodynamic model was constructed with independently estimated parameters to evaluate whether the observed cessation of Fe(III) reduction by AH₂DS was due to exhaustion of reaction free energy. Model-calculated reduction extents were, however, over 50% higher than experimentally measured, indicating that other factors, such as blockage of the electron transfer chain and mineralogy, restricted the reduction extent. Another important result of this study was the relative reducibility of Fe(III) in different clays: nontronite > chlorite > illite. This order was qualitatively consistent with the differences in the crystal structure and layer charge of these minerals.     

Factors influencing willingness to comply with HIV/AIDS prevention measures by female college students in Kolkata,West Bengal,India

With a 2.4 million people living with Human Immunodeficiency Virus (HIV), India is among the countries in the world most vulnerable to the spread of HIV. This study focuses on understanding what makes female college students (ages 18–24) in Kolkata, India willing to comply with HIV/AIDS preventive measures; these students are widely believed to be at low risk of infection with HIV. Through a questionnaire survey, the data used in this study was collected from 232 female students attending five higher education institutes. Multiple regression analysis reveals that religion, household income, perception of whether preventive measures would hamper freedom, and respondents’ perception of the effectiveness of preventive measures all influence the students’ willingness to comply with preventive measures. Based on its findings, the study makes several recommendations to improve HIV/AIDS prevention in Kolkata and West Bengal, India.     

Assessment of Indian summer monsoon simulation by Community Atmosphere Model (CAM3)

Seasonal prediction of Indian Summer Monsoon (ISM) has been attempted for the current year 2011 using Community Atmosphere Model (CAM) developed at the National Centre for Atmospheric Research (NCAR). First, 30?years of model climatology starting from 1981 to 2010 has been generated to capture the variability of ISM over the Indian region using 30 seasonal simulations. The simulated model climatology has been validated with different sets of observed climatology, and it was observed that the simulated climatological rainfall is affected by model bias. Subsequently, a bias correction procedure using the Tropical Rainfall Measuring Mission (TRMM) 3B43 rainfall has been proposed. The bias-corrected rainfall climatology shows both spatial and temporal variability of ISM satisfactorily. Further, four sets of 10-member ensemble simulations of ISM 2009 and 2010 have been performed in hindcast mode using observed sea surface temperature (SST) and persistence of April SST anomaly, and it has been found that the bias-corrected model rainfall captures the seasonal variability of ISM reasonably well with some discrepancies in these two contrasting monsoon years. With this positive background, the seasonal prediction of ISM 2011 has been carried out in forecast mode with the assumption of persistence of May SST anomaly from June through September 2011. The model assessment shows an 11% deficiency in All-India Rainfall (AIR) of ISM 2011. In particular, the monthly accumulated rains are predicted to be 101% (17.6?cm), 86% (24.3?cm), 83% (21.0?cm) and 95% (15.5?cm) of normal AIR for the months of June, July, August and September, respectively.     

Accuracy analysis of the 2014–2015 Global Shuttle Radar Topography Mission (SRTM) 1 arc-sec C-Band height model using International Global Navigation Satellite System Service (IGS) Network

Global Shuttle Radar Topography Mission (SRTM) data products have been widely used in Earth Sciences without an estimation of their accuracy and reliability even though large outliers exist in them. The global 1 arc-sec, 30 m resolution, SRTM C-Band (C-30) data collected in February 2000 has been recently released (2014–2015) outside North America. We present the first global assessment of the vertical accuracy of C-30 data using Ground Control Points (GCPs) from the International GNSS Service (IGS) Network of high-precision static fiducial stations that define the International Terrestrial Reference Frame (ITRF). Large outliers (height error ranging from –1285 to 2306 m) were present in the C-30 dataset and 14% of the data were removed to reduce the root mean square error (RMSE) of the dataset from ～187 to 10.3 m which is close to the SRTM goal of an absolute vertical accuracy of RMSE ～10 m. Globally, for outlier-filtered data from 287 GCPs, the error or difference between IGS and SRTM heights exhibited a non-normal distribution with a mean and standard error of 6.5 ± 0.5 m. Continent-wise, only Australia, North and South America complied with the SRTM goal. At stations where all the X- and C-Band SRTM data were present, the RMSE of the outlier-filtered C-30 data was 11.7 m. However, the RMSE of outlier-included dataset where C- and X-Band data were present was ～233 m. The results suggest that the SRTM data must only be used after regional accuracy analysis and removal of outliers. If used raw, they may produce results that are statistically insignificant with RMSE in 100s of meters.     

Human injuries caused by Bangladesh’s cyclone sidr: an empirical study

The objectives of this paper are to examine the extent of human injuries caused by Cyclone Sidr, which made landfall in Bangladesh coast on November 15, 2007, and report on the circumstances, type and causes of injuries, along with selected risk factors associated with such injuries. Relevant data was collected through a questionnaire survey administered among the cyclone victims. Semi-structured interviews with key personnel were also conducted to obtain information regarding the circumstances causing injuries and public response to care for the injured. The questionnaire survey data reveals that among the respondent families, 132 persons sustained various types of injuries. Since the respondent families comprised of 1,443 members, the injury rate was 9.15%. All injured victims were treated either onsite or in local hospitals. The most common types of injuries were soft-tissue injuries (cuts, bruises, and scrapes) and fracture/dislocations. The most common causes of injuries for survivors were associated with falling trees. Analysis of risk factors reveals that age is significantly correlated with injuries. Both formal and informal interviews suggest that injured persons and their family members were in general pleased with medical response they received from various sources. Several recommendations have been suggested to reduce future cyclone-related injuries in Bangladesh.     

Extended Finite Element Method for the Analysis of Discontinuities in Rock Masses

The strength and deformability of rock mass primarily depend on the condition of joints and their spacing and partially on the engineering properties of rock matrix. Till today, numerical analysis of discontinuities e.g. joint, fault, shear plane and others is conducted placing an interface element in between two adjacent rock matrix elements. However, the applicability of interface elements is limited in rock mechanics problems having multiple discontinuities due to its inherent numerical difficulties often leading to non-convergent solution. Recent developments in extended finite element method (XFEM) having strong discontinuity imbedded within a regular element provide an opportunity to analyze discrete discontinuities in rock masses without any numerical difficulties. This concept is based on partition of unity principle and can be used for cohesive rock joints. This paper summarizes the mathematical frameworks for the implementation of strong discontinuities in 3 and 6 nodded triangular elements and also provides numerical examples of the application of XFEM in one and two dimensional problems with single and multiple discontinuities.     

Safety Measures after the 2011 Joplin,Missouri, Tornado

Immediately following the May 2011 tornado, the city of Joplin, Missouri, initiated recovery efforts to rebuild the part of the community devastated by this event. In doing so, city officials introduced two new safety measures and recommended several others. The main objective of this paper is to explore the tornado survivors' compliance with the safety features recommended by the Joplin city authorities. Face‐to‐face interviews, as well as other methods, were used to survey respondents who were living within the tornado path (damage zones) at the time of the tornado. Results showed that 43 percent of all respondents implemented at least one recommended tornado measure in rebuild or repair their destroyed/damaged homes. Further, it was found that three variables considered here— rebuild or repair, damage zone category, and perceived tornado risk—were all significant contributors to a homeowner's decision to implement recommended tornado safety measures. The paper concludes with a recommendation for expanding tornado safety education among the respondents.     

On a type of solutions for dynamical rupture of the equilibrium of stars

Solutions for dynamical behaviour of unstable stellar models are obtained, in the special case where the velocity of a gaseous element varies asr/t. It is found that the only possible value for the constant of proportionality is 2/3 and that there are only two such stellar configurations.