Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.     

Sr/Sr and Sr/Ca in speleothems for paleoclimate reconstruction in Central China between 70 and 280 kyr ago

Limestone cave deposits (speleothems) provide archives for past changes in regional climates over a range of timescales. While δ¹⁸O and δ¹³C in speleothem calcite have been commonly used for reconstruction of paleoclimates, we report here further efforts in the use of ⁸⁷Sr/⁸⁶Sr and Sr/Ca signals in speleothem calcite to deduce paleomonsoon variability near the Loess Plateau of central China. A two end-member mass-balance model of concentration and isotopic composition of strontium in a cave system is used to estimate variation of the ⁸⁷Sr/⁸⁶Sr ratio in sediments overlying a limestone cave. We show that this ratio reflects climate-driven variations in the provenance and the extent of chemical weathering of the epikarstic sediments. The measurements of ⁸⁷Sr/⁸⁶Sr made on a well-dated stalagmite, SFL, from Buddha Cave (33^o40N′ 109^o05′E) show ratios of 0.71092 to 0.71133 (±0.00001 as 2σ) during relatively cold periods (e.g., Marine Isotope Stage (MIS) 5b, 5d, and 8), lower than ratios of 0.71133 to 0.71194 during relatively warm periods (e.g., MIS 5a, 5c, 5e, and 7). As changes in the Sr/Ca ratio may affect speleothem ⁸⁷Sr/⁸⁶Sr, we show that the direct use of speleothem ⁸⁷Sr/⁸⁶Sr is less ideal than our modeled ⁸⁷Sr/⁸⁶Sr for the exogenic Sr source above the cave as a paleomonsoon proxy. Using the δ¹⁸O, δ¹³C, Sr/Ca, and ⁸⁷Sr/⁸⁶Sr records of the stalagmite, we reconstruct the variability of the East Asian monsoon for the time period between 70 and 280 kyr ago. The results show that summer monsoons were more intense during interglacial periods than during glacial periods.     

富营养化湖泊蓝藻—芦苇碎屑堆积分解过程及其潜在的共代谢效应

为探究富营养化浅水湖泊所富集的有机物对湖泊碳循环和水质的影响,本研究构建微宇宙系统,模拟蓝藻和芦苇碎屑单独分解及混合分解过程.通过测定各组上覆水营养盐浓度、有机质含量及结构的变化,揭示富营养化湖泊藻草残体混合分解过程中养分和有机碳的释放特征.结果 表明,在实验0～88 h内,在添加相同的碳源条件下,蓝藻和芦苇混合处理组...     

基于网络游记的城市旅游流网络结构演化研究——以北京市为例

采用网络游记文本数据,结合爬虫技术和社会网络分析方法,分析北京市"十二五"和"十三五"时期城市旅游客流网络结构的演变特征。结果表明:①城市旅游流网络结构存在不均衡性,城市历史文化遗产节点的的影响控制能力强,新兴旅游吸引物的集聚能力相对较弱,受不同类型节点的路径依赖效应的影响,这种差异存在动态扩大特征。②城市旅游流网络结构呈现显著的等级分层结构和节点分散分布特征,传统游憩场所是城市旅游流的核心节点,外围发育的旅游节点较分散且规模能级提升空间较大。③城市旅游流拥有显著的赋能效应、倒逼效应和联通效应。     

东北三省全面振兴的社会经济支撑能力评估

在解析支撑能力和东北问题特点的基础上,从"创新、协调、绿色、开放、共享"五大理念出发建立全面振兴社会经济支撑能力评价指标体系和综合评价方法,以地级市为单元对东北三省进行评估。研究发现:各地市社会经济支撑能力差异显著,哈大沿线核心城市的支撑能力较强,西翼城市以及朝阳、七台河、绥化、葫芦岛、铁岭、双鸭山和鹤岗等资源型城市支撑能力较弱。因此未来东北地区在振兴政策的区域分布上应有所侧重,对不同地区施以不同的振兴或扶持政策。在创新、绿色、开放方面需要集中力量重点突破,而在体制机制改革和共享服务建设方面需要全面覆盖,并重点加强黑龙江北部和辽宁、吉林西翼城市的共享能力建设。     

一种非平稳噪声背景下的线谱相干检测方法

舰艇目标航行时往往向水中辐射大量线状谱结构的声波信号,线谱信号检测对舰艇目标的被动探测至关重要.实际水下环境噪声常表现为时域非平稳噪声,常规离散傅里叶变换类线谱检测方法时域积分时,不可避免会引入非平稳噪声背景中出现的短时强干扰噪声,使积分结果中线谱信噪比大幅降低,线谱检测性能急剧恶化.为解决上述问题,对分段离散傅里叶变...     

钾长石粉酸浸除铁的实验研究

在利用钾长石粉合成沸石分子筛和制取碳酸钾技术中，铁的存在会降低沸石的白度。对北京平谷、天津蓟县、内蒙白云鄂博三地钾长石粉进行硫酸酸浸除铁实验，获得最大铁浸出率分别为88．6％、93．2％和64．6％，且前两地钾长石粉中铁的浸出行为相似，酸浸除铁效果均优于白云鄂博钾长石粉。采用正交实验法研究硫酸浓度、酸浸温度和时间对除铁效果的影响，表明三者对不同地区钾长石粉酸浸除铁效果的影响程度各不相同。钾长石酸浸除铁反应开始时，铁的溶解极快，反应速率主要由化学反应控制；其后溶解相对缓慢，反应速率则由扩散作用控制。     

地幔柱大辩论及如何验证地幔柱假说

目前关于地幔柱存在与否的争论主要集中在地幔柱学说的三个假设上:(1)起源于地球核幔边界缓慢上升的细长柱状热物质流;(2)热点下具有异常高温地幔;(3)地幔柱是相对静止的。这三个方面的验证需要今后深部地球物理探测、岩石学和古地磁等学科的综合运用和进一步的工作。文中认为,地幔柱学说依然能合理地解释地球上一级地质现象,反对地幔柱的学者过分强调了一些小尺度的与地幔柱理论不符的细节,而小尺度地壳特征显然还受到其他许多因素的影响。可以从以下5个方面来鉴别老地幔柱:(1)大规模火山作用前的地壳抬升;(2)放射状岩墙群;(3)火山作用的物理特征;(4)火山链的年代学变化;(5)地幔柱产出岩浆的化学组成。研究表明,峨眉山大火成岩省满足其中的3到4个指标,因此地幔柱是形成峨眉山玄武岩的主要动力学机制。     

赣南地区寒武纪高滩组碎屑锆石U-Pb年龄和Hf同位素特征及地质意义

寒武纪高滩组广泛分布于赣南武功山-雩山地区,主体为一套浅变质砂岩夹板岩的复理石建造。为分析其物源,并对源区地壳生长和构造演化提供约束,本文对采自高滩组的变长石石英杂砂岩进行了LA-ICP-MS碎屑锆石U-Pb年代学和Hf同位素研究。锆石U-Pb年龄数据显示2 500 Ma、1 100~900 Ma和900~700 Ma 3个主要年龄峰值。2 500 Ma的年龄峰值代表了新太古代末期—古元古代的古陆核生长事件。1 100~900 Ma和900~700 Ma两个峰最显著,表明Rodinia超大陆聚合裂解在华南地区的响应,为该区寒武纪地层提供了主要物源。此外,3 003 Ma锆石年龄的捕获说明,华夏地块可能存在太古宙地壳基底。Hf同位素数据表明,源区锆石结晶多为古老地壳组分部分熔融产生的岩浆。结合锆石年龄数据分析认为,华南地区存在强烈的新元古代岩浆活动,该时期岩浆活动主要是古老地壳物质的再循环。     

星叶石族矿物红外光谱研究

在新测定的星叶石晶体结构资料的基础上,对星叶石矿物进行了详细和红外光谱研究,对比了单斜及三斜星叶石的红光谱特征,并对星叶石中工外吸收振动的归属问题进行了讨论。