Composition and flux of suspended organic matter in the middle and lower reaches of the Changjiang (Yangtze River) — impact of the Three Gorges Dam and the role of tributaries and channel erosion

To investigate the sources of particulate organic matter (POM) and the impact of Three Gorges Dam (TGD), two large lakes and erosion processes on determining the composition and flux of POM in low water discharge periods along the middle and lower Changjiang, suspended particulate samples were collected along the middle and lower reaches of the Changjiang (Yangtze River) in January 2008. Organic geochemistry of bulk sediment (particulate organic carbon, organic carbon to nitrogen molar ratio (C/N), stable carbon isotope (δ¹³C) and grain size) and biomarker of bulk sediment (lignin phenols) were measured to trace the sources of POM. The range of C/N ratios (6.4–8.9), δ¹³C (?24.3‰ – ?26.2‰) and lignin phenols concentration Λ8 (0.45 mg/100 mg OC‐2.00 mg/100 mg OC) of POM suggested that POM originated from the mixture of soil, plant tissue and autochthonous organic matter (OM) during the dry season. POM from lakes contained a higher portion of terrestrial OM than the mainstream, which was related to sand mining and hydropower erosion processes. A three end‐member model based on δ¹³C and Λ8 was performed. The results indicated that soil contributed approximately 50% of OM to the POM, which is the dominant OM source in most stations. POM composition was affected by total suspended matter (TSM) and grain size composition, and the direct OM input from two lakes and channel erosion induced OM. The lower TSM concentration in January 2008 was mainly caused by seasonal variations; the impact from the TGD in the dry season was relatively small. A box model indicated that more than 90% of the terrestrial OM transported by the Changjiang in January 2008 was from the middle and lower drainage basins. Channel erosion induced OM, and contributions from Poyang Lake were the major terrestrial OM sources in the dry season. Copyright © 2012 John Wiley & Sons, Ltd.     

基于广域电磁法的页岩气有利区预测——以渝东北巫山地区为例

渝东北巫山地区是重要的页岩气勘探远景区,勘探程度较低.本次研究以岩石物理和测井数据为基础,以广域电磁法为手段,开展该区的页岩气有利区评价.通过对地表样品及井孔电阻率测井资料的分析,揭示研究区目的层富有机质页岩层电阻率表现为明显低阻特征,与上覆下伏地层电性差异明显,表明本区分布的上奥陶统五峰—下志留统龙马溪组富有机质页岩具备开展电法勘探工作的物性条件.在对电磁资料处理解释的基础上,查明了重庆巫山地区“隆凹相间”的构造格局,断裂性质主要为逆断层;目的层上奥陶统五峰组—下志留统龙马溪组富有机质泥页岩连续稳定分布,低阻特征明显,埋深范围在800~4 800m之间.综合考虑目的层页岩电阻率、极化率、埋深等因素,预测出页岩气有利区3个,区内富有机质页岩发育,页岩气勘探前景较好.     

西藏多龙矿集区拿若铜（金）矿床成矿元素空间分布规律及地球化学勘查模型

拿若铜(金)矿床是多龙矿集区内继多不杂斑岩铜(金)矿、波龙斑岩铜(金)矿之后又一取得重大找矿突破的大型斑岩型矿床。作者以矿区探矿工程分析数据为基础,研究各成矿元素空间分布规律。成矿元素在垂向上的分带特征不明显,在平面上分带特征较显著,表现为自矿区中心ZK0001,向南西方向具有Cu+Au-Cu(Au、Ag)→Cu(Ag、Au)-Cu(Ag)的分带特征。同时,矿区土壤地球化学测量显示,从0线开始至31线(北东→南西)具有Mo、Cu→Mo(Cu、Au)→Cu、Au(Ag、Mo、Pb)→Pb→Pb、Zn分带特征,显示物质来源和热源位于0线附近,成矿流体是以0线、7线一带向四周运移,并具有从北东向南西方向运移的特点。通过矿床地质特征、元素分带特征研究,建立了矿区地球化学勘查模型。     

松辽盆地泰康地区青山口组沉积相及与油气分布关系研究

系统地研究了松辽盆地泰康地区青山口组沉积相类型及沉积特征,其中对青一段与青二、三段的沉积相平面分布与垂向演化规律做了较深入地探讨。研究表明,青山口组主要发育湖泊相与三角洲相2种沉积相类型,其中湖泊相包括2种亚相与4种微相,三角洲相包括2种亚相和2种微相。沉积演化分析表明,青一段以深湖、半深湖相泥岩沉积为特征,青二、三段以浅湖相与三角洲相砂泥岩互层为特征。区内青山口组主要存在三种类型的储层砂体,分别为三角洲前缘河口坝砂体、三角洲前缘远砂坝砂体和浅湖砂体,其中浅湖砂体是最好的含油砂体,浅湖砂体发育的优势区也即浅湖沉积亚相发育区是区内最重要的油气富集区,是今后油气勘探的有利地区。     

基于遥感技术的海岸带土地利用、覆被信息提取方法研究

本文以地处莱州湾东海岸的莱州市为研究区域,以TM影像为主要信息源,在分析各类地物分类效果的基础上,结合区域特点和地物光谱特征,综合利用两期典型季相的遥感图像,并针对每一种土地利用类型确定最佳信息提取影像,提出了基于光谱、地形等多种知识的分层信息提取方法.结果表明该方法分层目标明确,分类精度和计算效率都有明显提高,且在数...     

Chromium isotopic systematics of the Sutter's Mill carbonaceous chondrite: Implications for isotopic heterogeneities of the early solar system

Recent studies have shown that major meteorite groups possess their own characteristic ⁵⁴Cr values, demonstrating the utility of Cr isotopes for identifying genetic relationships between the planetary materials in conjunction with other classical tools, such as oxygen isotopes. In this study, we performed Cr isotope analyses for whole rocks and chemically separated phases of the new CM2 chondrite, Sutter's Mill (SM 43 and 51). The two whole rocks of Sutter's Mill show essentially identical ε⁵⁴Cr excesses (SM 43 = +0.95 ± 0.09ε, SM 51 = +0.88 ± 0.07ε), relative to the Earth. These values are the same within error with that of the CM2‐type Murchison (+0.89 ± 0.08ε), suggesting that parent bodies of Sutter's Mill and Murchison were formed from the same precursor materials in the solar nebula. Large ε⁵⁴Cr excess of up to 29.40ε is observed in the silicate phase of Sutter's Mill, while that of Murchison shows 15.74ε. Importantly, the leachate fractions of both Sutter's Mill and Murchison form a steep linear anticorrelation between ε⁵⁴Cr and ε⁵³Cr, cross‐cutting the positive correlation previously observed in carbonaceous chondrites. The fact that L4 acid leachate fraction contains higher ⁵⁴Cr excesses than that of L5 step designed to dissolve refractory minerals suggests that spinel is not a major ⁵⁴Cr carrier. We also note that L5 contains ⁵³Cr anomalies lower than the solar initial value, suggesting it carries a component of nucleosynthetic anomaly unrelated to the ⁵³Mn decay. We have identified five endmember components of nucleosynthetic origin among the early solar system materials.     

冷水坑斑岩型银铅锌矿床成矿流体特征研究

斑岩型银铅锌矿床世界上并不多见,目前我国典型斑岩型银铅锌矿床仅冷水坑一处.笔者通过对冷水坑斑岩型银铅锌矿床的流体包裹体地球化学、稳定同位素地球化学研究,结合岩相学研究、激光拉曼探针(LRM)和扫描电镜/能谱(SEM/EDS)测试,揭示了冷水坑斑岩型银铅锌矿床成矿流体特征及演化过程,并进一步探讨了成矿物质来源和矿床成矿机制.研究表明,冷水坑矿床成矿流体及主要成矿元素(硫)来自于斑岩系统,大气水在整个成矿过程中均有不同程度的参与.     

阿尔金北缘岩石变形机制——来自X光组构分析的证据

对阿尔金北缘地区变形蚀变花岗岩、花岗质糜棱岩、变形酸性火山岩和变形英安质凝灰岩中石英和绢云母2种矿物进行X光岩石组构分析,认为本区岩石变形比较明显,宏观面理近于东西向展布,绢云母变形较强,平行于面理定向排列;而石英以底面或近底面滑移为主,部分样品兼有柱面Ⅰ型滑移和柱面Ⅱ型滑移,反映本区岩石变形机制为中浅层次的脆-韧性变形(10~15km、250~350℃、0.25~0.40GPa)。通过岩石组构特征与宏观面理产状,推断本区韧性变形以右行运动为主,与板块碰撞在阿尔金北缘大平沟地区产生的韧性变形带特征一致。     

辽东南长海地区花岗质片麻岩类的地球化学特征:对其原岩性质及形成环境的制约

本文对辽东南长海地区花岗质片麻岩进行了系统的岩石学和地球化学研究,以便对其原岩性质及形成的构造环境给予制约。研究结果表明,研究区内花岗质片麻岩类可划分为富钠和富钾两类花岗质岩石,前者包括黑云二长花岗质片麻岩和花岗闪长质片麻岩,矿物组成主要包括斜长石、石英、黑云母及少量的钾长石等,后者则主要包括花岗质、二长花岗质和糜棱岩化花岗质片麻岩,其矿物组成以钾长石、斜长石、石英和次要的白云母和黑云母为主。地球化学分析结果显示,富钠花岗质片麻岩具有富硅、富钠、高铝、富集LREEs和LILEs、强烈亏损HREEs和HFSEs(Nb、Ta、P、Ti)、轻重稀土强烈分馏、并显示弱负Eu异常和Ba的相对亏损等特征;而富钾花岗质片麻岩则显示高硅、富钾、过铝质的地球化学属性、富集LREEs和LILEs、亏损HREEs和HFSEs,与富钠花岗质岩石相比,轻重稀土分馏程度相对较弱、HFSEs以及Ba相对于Rb和Th的亏损程度更强,并显示中等负Eu异常和强烈的Sr负异常等特征。上述特征表明,辽东南长海地区富钠花岗质片麻岩应起源于中酸性陆壳物质的部分熔融,并可能有玄武质物质的加入,原岩应为具有活动大陆边缘属性的花岗闪长岩,其形成应与狼林地块(或胶辽地块)东南及南部先存洋盆向陆块之下的俯冲作用相联系;而富钾花岗质片麻岩应形成于中酸性陆壳物质的部分熔融,原岩为具有碰撞型花岗岩属性的碱性花岗岩,其形成应与洋壳消减闭合、陆陆碰撞拼贴相联系。     

鄂尔多斯盆地三叠系延长组长7油页岩特征与页岩气资源潜力研究

鄂尔多斯盆地三叠系延长组长7油页岩,主要分布在盆地南部,单层厚度10 ～30 m(最厚处超过50m),试气证实具有一定产气能力.延长组沉积时是鄂尔多斯盆地发育的鼎盛时期,长7期湖盆范围达到最大.通过对长7油页岩分布与沉积相展布关系的研究,认为鄂尔多斯盆地油页岩的分布受沉积环境的控制作用显著,深湖—半深湖相形成的油页岩具有厚度大、分布范围广的特点,且盆地构造相对简单,开发条件优越.采用资源丰度类比法估算出长7页岩气资源量为(4.47 ～～8.83)×1012 m3.因此,鄂尔多斯盆地长7油页岩具有广阔的勘探开发前景.