Garnet re‐equilibration by coupled dissolution–reprecipitation: evidence from textural,major element and oxygen isotope zoning of ‘cloudy’ garnet

The analysis of texture, major element and oxygen isotope compositions of cloudy garnet crystals from a metapelite sampled on Ikaria Island (Greece) is used to assess the model of growth and re‐equilibration of these garnet crystals and to reconstruct the pressure–temperature–fluid history of the sample. Garnet crystals show complex textural and chemical zoning. Garnet cores (100–200 μm) are devoid of fluid inclusions. They are characterized by growth zoning demonstrated by a bell‐shaped profile of spessartine component (7–3 mol.%), an increase in grossular from 14 to 22 mol.% and δ¹⁸O values between 9.5 ± 0.3‰ and 10.4 ± 0.2‰. Garnet inner rims (90–130 μm) are fluid inclusion‐rich and show a decreasing grossular component from 22 to 5 mol.%. The trend of the spessartine component observed in the inner rim allows two domains to be distinguished. In contrast to domain I, where the spessartine content shows the same trend as in the core, the spessartine content of domain II increases outwards from 2 to 14 mol.%. The δ¹⁸O values decrease towards the margins of the crystals to a lowest value of 7.4 ± 0.2‰. The outer rims (<10 μm) are devoid of fluid inclusions and have the same chemical composition as the outermost part of domain II of the inner rim. Garnet crystals underwent a four‐stage history. Stage 1: garnet growth during the prograde path in a closed system for oxygen. Garnet cores are remnants of this growth stage. Stage 2: garnet re‐equilibration by coupled dissolution–reprecipitation at the temperature peak (630 < T < 650 °C). This causes the creation of porosity as the coupled dissolution–reprecipitation process allows chemical (Ca) and isotopic (O) exchange between garnet inner rims and the matrix. The formation of the outer rim is related to the closure of porosity. Stage 3: garnet mode decreases during the early retrograde path, but garnet is still a stable phase. The resulting garnet composition is characterized by an increasing Mn content in the inner rim’s domain II caused by intracrystalline diffusion. Stage 4: dissolution of garnet during the late retrograde path as garnet is not a stable phase anymore. This last stage forms corroded garnet. This study shows that coupled dissolution–reprecipitation is a possible re‐equilibration process for garnet in metamorphic rocks and that intra‐mineral porosity is an efficient pathway for chemical and isotopic exchange between garnet and the matrix, even for otherwise slow diffusing elements.     

Modification of sediment characteristics during glacial transport in high-alpine catchments: Mount Cook area, New Zealand

The Mount Cook area in the Southern Alps of New Zealand is heavily glacierized with numerous peaks over 3000 m a.s.l. feeding several large valley glaciers. The region is subject to rapid tectonic uplift and heavy precipitation (up to 15 m per year). This paper describes the clast roundness, clast shape and textural characteristics associated with five glaciers (Fox, Franz Josef, Hooker, Mueller and Tasman) in terms of inputs to the glacier system, transport by the glaciers and reworking following glacial deposition. Inputs include rockfall, alluvial fan and avalanche material delivered to the surface of valley glaciers. Basal debris, where observed at the terminus of two glaciers, consists mainly of incorporated fluvial material. Following deposition, reworking is mainly by subglacial and proglacial streams. The dominant facies are (i) boulder gravel with mainly angular clasts on the steep slopes above the glaciers, (ii) sandy boulder gravel, with mainly angular and subangular clasts, forming lateral and end moraines, and (iii) sandy boulder/cobble gravel with mainly subrounded clasts, and sand, which represent glacially transported sediment reworked by braided rivers. Diamicton is rare in the contemporary glacial environment. Since most sediment associated with glaciers in the Southern Alps lacks unambiguous indications of glacial transport, interpretation of similar sediments in the geological record should not necessarily exclude the involvement of glacial processes.     

Tankering strategies for evading emissions trading in aviation

Which actors in the aviation sector ought to be obliged to participate in emissions trading? The European Commission opted for the aircraft operator in their proposal for a Directive. A major drawback is that non-EU aircraft operators might legally challenge their inclusion in this scheme and, if the challenge was successful, discrimination between EU and non- EU operators would undermine the scheme. An alternative would be to place an obligation on fuel suppliers to prove possession of allowances, thus avoiding discrimination. However, emissions trading can be evaded to some extent by increased refuelling beyond EU boundaries (tankering). Typical city pairs were used to analyse the conditions under which such tankering strategies are economically attractive. The analysis shows that the attractiveness of tankering depends substantially on the relationship between fuel prices and allowance prices. If the price relation as of March 2006 is taken as a basis, tankering would be attractive within a radius of up to 4,000 km especially on southbound and eastward routes. Emissions trading could, under unfavourable conditions, be evaded for up to 20% of the total fuel consumption in aviation with the help of tankering. Although this value is only a theoretical upper limit, more than 10% of fuel consumption could be affected by tankering.     

Late Weichselian ice-sheet sensitivity over Franz Josef Land, Russian High Arctic, from numerical modelling experiments

A numerical ice-sheet model was run in order to produce reconstructions of the Late Weichselian ice coverage of Franz Josef Land, Russian High Arctic. The model grid covers the archipelago and surrounding shelf, but does not include the whole Barents-Kara region or the extensive ice cover that may have built up there. One experiment, where rates of iceberg calving at the grounded margin were curtailed because of the assumed presence of permanent thick sea ice, yielded a single I.8 km-thick ice dome which covered the entire archipelago and surrounding sea. If, however, iceberg calving were included in the model's environmental input, the extent of the ice sheet would be limited to the periphery of the archipelago. If a large ice sheet existed over Franz Josef Land, the deglaciation of the islands may have been linked to the decay of the adjacent Barents-Kara Sea Ice Sheet, permitting iceberg calving (enhanced by relative sea-level rise) to occur. The introduction of a water-depth-related iceberg calving function at 15 000 yr ago forced an initial rapid rate of ice-sheet decay of 30 000 km³ 1000 yr'. However, as the ice sheet thinned, and isostatic rebound began, the calculated rate of iceberg calving was reduced such that ice remained over the archipelago at 8000 yr ago. The model's failure to simulate complete ice-sheet decay by 8000 yr ago is at variance with radiocarbon-dated raised terraces on Franz Josef Land, which indicates the complete deglaciation of the islands at this time.     

FINDING CAUSES OF OUTLIERS IN MULTIVARIATE ENVIRONMENTAL DATA

Multivariate outliers in environmental data sets are often caused by atypical measurement error in a singlevariable.From a quality assurance perspective it is important to identify these variables efficiently so thatcorrective actions may be performed.We demonstrate a procedure for using two multivariate tests toidentify which variable‘caused’each outlier.The procedure is tested with simulated data sets that havethe same correlation structure as selected water chemistry variables from a survey of lakes in the WesternUnited States.The success rates are evaluated for three of the variables for sample sizes of 50 and 100,significance levels of 0.01 and 0.05 and various amounts of mean shift.The procedure works best forhighly correlated variables.     

Problems of moraine morphology: Rogen moraine and Blattnick moraine

In Västerbotten County, Sweden, both Rogen moraine and Blattnick moraine are common in the inner part of the county. Rogen moraines are found primarily in basins and upslope positions, whereas the Blattnick type (first found in the Blattnicksele area in the county) mostly occurs in broader, more plain-like areas. Moreover, both types show a great variety of individual forms, due to topography, basal conditions and ice tectonics. Most Rogen moraine ridges are characterized by features due to active ice. The Blattnick moraine type is characterized by broader and more drumlinized ridges. They are often proximally higher and laterally-distally extended, thus merging into streamlined mounds or hills. The material composition of Rogen and Blattnick moraines is similar. The authors have found the following sequence of transitional forms from the Scandinavian mountains in the west towards the east: (1) Rogen moraines, (2) crescent ridges, (3) Blattnick moraines, (4) drumlins.     

Beryllium and Other Trace Elements in Paragneisses and Anatectic Veins of the Ultrahigh-Temperature Napier Complex, Enderby Land, East Antarctica: the Role of Sapphirine

Anatectic veins containing the Be minerals khmaralite and berylliansapphirine as primary phases (or surinamite derived therefrom)are associated with Mg–Al-rich paragneisses at three localitiesin the ultrahigh-temperature Napier complex, Antarctica, a uniqueBe mineralization in the granulite facies. Likely precursorsof the paragneisses are volcaniclastic deposits that were hydrothermallyaltered by heated seawater prior to metamorphism. Regular distributionof Be among minerals in the paragneisses suggests an approachto equilibrium with Be greatly concentrated in sapphirine (25–3430ppm Be) or cordierite (560–930 ppm Be) relative to plagioclaseAn53–66 (14–43 ppm Be) > cores of coarse-grainedorthopyroxene (0·7–29 ppm Be) > coronitic orthopyroxene(0·4–14 ppm Be) sillimanite (0·1–26ppm Be) plagioclase An18–33 (0·6–15 ppmBe) > biotite (0·06–8 ppm Be) > K-feldspar,quartz, garnet (0·05–0·7 ppm Be). Sapphirine-bearingparagneisses have average Be concentrations, 4·9 ±2·4 ppm (13 samples), about twice that of typical pelites,whereas paragneisses lacking sapphirine and primary cordieritehave only 2·9 ± 2·1 ppm Be (12 samples),implying some loss of Be during metamorphism. The likely sourcerocks for the Be-rich melts were biotitic rocks lacking theBe sinks sapphirine and cordierite. These gneisses were probablyless competent than the sapphirine-bearing gneisses, so themelts were drawn to the latter and collected in spaces openedduring deformation and boudinage of the more competent paragneisses.Fractionation of the melts concentrated Be to the extent thatBe minerals could crystallize. The final result was Be-mineralizedanatectic veins hosted by relatively Be-rich sapphirine-bearingparagneisses. KEY WORDS: Antarctica; beryllium; granulite facies; microprobe; sapphirine     

Combined Trace Element and Pb-Nd-Sr-O Isotope Evidence for Recycled Oceanic Crust (Upper and Lower) in the Iceland Mantle Plume

We present the results of a comprehensive major element, traceelement and Sr–Nd–Pb–O isotopic study of post-glacialvolcanic rocks from the Neovolcanic zones on Iceland. The rocksstudied range in composition from picrites and tholeiites, whichdominate in the main rift systems, to transitional and alkalicbasalts confined to the off-rift and propagating rift systems.There are good correlations of rock types with geochemical enrichmentparameters, such as La/Sm and La/Yb ratios, and with long-termradiogenic tracers, such as Sr–Nd–Pb isotope ratios,indicating a long-lived enrichment/depletion history of thesource region. ⁸⁷Sr/⁸⁶Sr vs ¹⁴³Nd/¹⁴⁴Nd defines a negative array.Pb isotopes define well-correlated positive arrays on both ²⁰⁶Pb/²⁰⁴Pbvs ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb diagrams, indicating mixing ofat least two major components: an enriched component representedby the alkali basalts and a depleted component represented bythe picrites. In combined Sr–Nd–Pb isotopic spacethe individual rift systems define coherent mixing arrays withslightly different compositions. The enriched component hasradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb > 19·3) and very similargeochemistry to HIMU-type ocean island basalts (OIB). We ascribethis endmember to recycling of hydrothermally altered upperbasaltic oceanic crust. The depleted component that is sampledby the picrites has unradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb < 17·8),but geochemical signatures distinct from that of normal mid-oceanridge basalt (N-MORB). Highly depleted tholeiites and picriteshave positive anomalies in mantle-normalized trace element diagramsfor Ba, Sr, and Eu (and in some cases also for K, Ti and P),negative anomalies for Hf and Zr, and low ¹⁸O_olivine values(4·6–5·0) below the normal mantle range.All of these features are internally correlated, and we, therefore,interpret them to reflect source characteristics and attributethem to recycled lower gabbroic oceanic crust. Regional compositionaldifferences exist for the depleted component. In SW Icelandit has distinctly higher Nb/U (68) and more radiogenic ²⁰⁶Pb/²⁰⁴Pbratios (18·28–18·88) compared with the NErift (Nb/U 47; ²⁰⁶Pb/²⁰⁴Pb = 18·07–18·47).These geochemical differences suggest that different packagesof recycled oceanic lithosphere exist beneath each rift. A thirdand minor component with relatively high ⁸⁷Sr/⁸⁶Sr and ²⁰⁷Pb/²⁰⁴Pbis found in a single volcano in SE Iceland (Öræfajökullvolcano), indicating the involvement of recycled sediments inthe source locally. The three plume components form an integralpart of ancient recycled oceanic lithosphere. The slope in theuranogenic Pb diagram indicates a recycling age of about 1·5Ga with time-integrated Th/U ratios of 3·01. Surprisingly,there is little evidence for the involvement of North AtlanticN-MORB source mantle, as would be expected from the interactionof the Iceland plume and the surrounding asthenosphere in formof plume–ridge interaction. The preferential samplingof the enriched and depleted components in the off-rift andmain rift systems, respectively, can be explained by differencesin the geometry of the melting regions. In the off-rift areas,melting columns are truncated deeper and thus are shorter, whichleads to preferential melting of the enriched component, asthis starts melting deeper than the depleted component. In contrast,melting proceeds to shallower depths beneath the main rifts.The longer melting columns also produce significant amountsof melt from the more refractory (lower crustal/lithospheric)component. KEY WORDS: basalts; trace element and Sr, Nd, Pb, O isotope geochemistry; Iceland plume; isotope ratios; oceanic crustal recycling; partial melting; plume–ridge interaction     

1991年皮纳图博火山灰沉降物对南海海洋环境及硅藻生长的影响

通过对菲律宾皮纳图博(Pinatubo)火山1991年6月爆发前后南海表层沉积物及沉降颗粒物中的硅藻丰度及群落组成进行分析,试图揭示皮纳图博火山爆发对南海硅藻生长的影响.研究发现,火山爆发后南海沉积物中硅藻相对丰度显著减少,原因主要在于皮纳图博火山喷发物大量沉积于南海深海,显著提高了南海沉积速率,同时稀释了沉积物中生源...