Intercomparison of210Pb measurements at GEOSECS station 500 in the northeast Pacific

During reoccupation of the GEOSECS-I test station in May, 1979, more than eighty 30-liter Niskin samples were collected in profile, many as replicates, for²¹⁰Pb intercomparison measurements by the WHOI, SIO and Yale groups. In addition to the inter-laboratory comparisons, the SIO group also carried out extensive experiments to test the effect of sample scavenging method. Pb equilibration time (storage effect), and filtration process on the measured²¹⁰Pb results.The intercomparison measurements indicate that there is a general agreement between the various sets of data. The sample set which allows a direct comparison at the same depth was available in most cases only between two of the three groups. The direct paired comparison shows that (1) the WHOI data are systematically 3% lower than the SIO data; (2) there are no systematic differences observed between the SIO and Yale data although the scatter is rather large; (3) the Yale data are systematically higher than the WHOI data by about 8%.The SIO experiments show that (1) the two scavenging methods employed (Fe(OH)₃ and Co-APDC co-precipitation) yield identical²¹⁰Pb results; (2) variation of Pb carrier equilibration time or of storage time has no discernible effect; (3) the filtration apparatus and procedure employed at this station do not result in²¹⁰Pb loss or contamination.The²¹⁰Pb profile structure and absolute concentration measured earlier at the same location (GOGO-II test station and GEOSECS station 347) agree with those of station 500 within 10%. The present profile shows a minimum²¹⁰Pb concentration around 500 m depth, marking the penetration depth of the flux of excess²¹⁰Pb from the atmosphere. There is a mild mid-depth maximum around 2500–3000 m. The²¹⁰Pb/²²⁶Ra activity ratio decreases monotonically from about 1 at the²¹⁰Pb minimum to about 0.5 near the bottom. The particulate²¹⁰Pb profile shows a systematic increase from the subsurface water to the bottom water by a factor of 5. This feature has been observed in many GEOSECS particulate²¹⁰Pb profiles.     

Use of traveltime skips in refraction analysis to delineate velocity inversion1

First arrival refraction data does not normally provide any indication of the velocity inversion problem. However, under certain favourable circumstances, when the low-velocity layer (LVL) is considerably thicker than the overlying higher-velocity layer (HVL), the velocity inversion can be seen in the form of a traveltime skip. Model Studies show that in such cases the length of the HVL traveltime branch can be used to determine the thickness of the HVL and the magnitude of the traveltime skip in order to determine the thickness of the LVL. This is also applicable in the case of field data.     

A comparison of solute-transport solution techniques and their effect on sensitivity analysis and inverse modeling results

Five common numerical techniques for solving the advection-dispersion equation (finite difference, predictor corrector, total variation diminishing, method of characteristics, and modified method of characteristics) were tested using simulations of a controlled conservative tracer-test experiment through a heterogeneous, two-dimensional sand tank. The experimental facility was constructed using discrete, randomly distributed, homogeneous blocks of five sand types. This experimental model provides an opportunity to compare the solution techniques: the heterogeneous hydraulic-conductivity distribution of known structure can be accurately represented by a numerical model, and detailed measurements can be compared with simulated concentrations and total flow through the tank. The present work uses this opportunity to investigate how three common types of results--simulated breakthrough curves, sensitivity analysis, and calibrated parameter values--change in this heterogeneous situation given the different methods of simulating solute transport. The breakthrough curves show that simulated peak concentrations, even at very fine grid spacings, varied between the techniques because of different amounts of numerical dispersion. Sensitivity-analysis results revealed: (1) a high correlation between hydraulic conductivity and porosity given the concentration and flow observations used, so that both could not be estimated; and (2) that the breakthrough curve data did not provide enough information to estimate individual values of dispersivity for the five sands. This study demonstrates that the choice of assigned dispersivity and the amount of numerical dispersion present in the solution technique influence estimated hydraulic conductivity values to a surprising degree.     

Thermische Energieflüsse an der Wasseroberfläche: Beispiel Sempachersee

Data collected every 20 minutes for 18 months by a meteorological buoy moored on Lake Sempach in Switzerland (maximum depth 86 m, surface area 14.1 km²) are used to calculate different processes contributing to the net heat flux between water and atmosphere. The processes considered are shortwave and longwave radiation, evaporation/condensation and sensible heat transfer. The temporal resolution of the measurements allows the evaluation of the processes occurring on three different time scales: diurnal variations, weather events of a few days and yearly cycles. The heat content of the lake is calculated from quasi-continuous measurements of water temperature at different depths. The yearly amplitude of the heat content is 1100·10⁶ J/m². Short-time variations of the heat flux determined from water temperature analysis agree well with the flux variations modeled using meteorological data. However, the latter generally underestimates the measured net heat flux in the long term. Wind measurements, together with the net heat flux, are used to calculate the Flux Richardson Number and the Monin-Obukov Length. Examples are given to show the predominant influence of the wind on the stratification of the upper water column and thus on the surface water temperature.      

Methods for medium-term prediction of the net sediment transport by waves and currents in complex coastal regions

Medium-term prediction of sediment transport and morphological behaviour in the coastal zone is becoming increasingly important as a result of human interference and changing environmental conditions. The interaction of waves and tides is shown to play a pivotal role in the net (annual) sediment transport and morphodynamics of the coastal zone. The Telemac Modelling System has been applied to the Dyfi Estuary and neighbouring coastline, mid Wales, to recreate the annual wave–current conditions and the resulting sediment fluxes. ‘Input reduction’ methods have been required to produce realistic schematisations of events in practical computation times. A field campaign carried out in 2006 provided data for validation of the flow module (Telemac-2D) and also observations to verify the patterns predicted by the wave module (Tomawac). To improve model accuracy refinements were implemented with regard to the sand transport formulation used in the sand transport module (Sisyphe). Here, a parameterisation of the results from the UWB 1DV sand transport ‘research’ model, for the conditions in the Dyfi Estuary, has been introduced, allowing Sisyphe to provide greater realism in the morphological predictions. The model predictions are presented along with a discussion of the success/failure and limitations of the modelling methods applied.     

Ziminaite,Fe3+VO4, a new howardevansite-group mineral from the Bezymyannyi volcano,Kamchatka, Russia

Mineralogy and Petrology - The new mineral ziminaite, ideally Fe3+VO4, was found in fumarole sublimates at the Bezymyannyi volcano, Kamchatka, Russia. Ziminaite occurs as lamellar, tabular or...     

同位素指示的巴丹吉林沙漠南缘地下水补给来源

通过恢复巴丹吉林沙漠及其周边地区大气降水氚值，并结合区域稳定同位素组合特征，揭示了区域地下水氚年龄的多解性与地下水稳定同位素的温度效应。恢复的1963年核试验期氚高峰值达到2 100 TU，进入90年代平均为60 TU。1960年以来降水补给的地下水氚值都应大于15 TU，而1963年的高峰氚衰变至今应在200 TU左右。地下水实测氚值较低，表明由现代少量降水补给的地下水与大量的古水进行了混合。影响降水中δ18O和δ2H分布的主要影响因子是月平均空气温度，对δ18O与δ2H的影响权重分别占到59.9%和57.0%。巴丹吉林沙漠及其周边地区地下水较低的稳定同位素组成表明，其补给主要是晚更新世较冷环境下形成的，来源于东南部的雅布赖山区，部分浅层地下水接受现代降水与河流的补给。      

Stratigraphic evolution of an outcropping continental slope system, Tres Pasos Formation at Cerro Divisadero, Chile

Depositional slope systems along continental margins contain a record of sediment transfer from shallow‐water to deep‐water environments and represent an important area for natural resource exploration. However, well‐preserved outcrops of large‐scale depositional slopes with seismic‐scale exposures and tectonically intact stratigraphy are uncommon. Outcrop characterization of smaller‐scale depositional slope systems (i.e. < 700 m of undecompacted shelf‐to‐basin relief) has led to increased understanding of stratigraphic packaging of prograding slopes. Detailed stacking patterns of facies and sedimentary body architecture for larger‐scale slope systems, however, remain understudied. The Cretaceous Tres Pasos Formation of the Magallanes Basin, southern Chile, presents a unique opportunity to evaluate the stratigraphic evolution of such a slope system from an outcrop perspective. Inherited tectonic relief from a precursor oceanic basin phase created shelf‐to‐basin bathymetry comparable with continental margin systems (～1000 m). Sedimentological and architectural data from the Tres Pasos Formation at Cerro Divisadero reveal a record of continental margin‐scale depositional slope progradation and aggradation. Slope progradation is manifested as a vertical pattern exhibiting increasing amounts of sediment bypass upwards, which is interpreted as reflecting increasing gradient conditions. The well‐exposed, seismic‐scale outcrop is characterized by four 20 to 70 m thick sandstone‐rich successions, separated by mudstone‐rich intervals of comparable thickness (40 to 90 m). Sedimentary body geometry, facies distribution, internal bedding architecture, sandstone richness and degree of amalgamation were analysed in detail across a continuous 2·5 km long transect parallel to depositional dip. Deposition in the lower section (Units 1 and 2) was dominated by poorly channellized to unconfined sand‐laden flows and accumulation of mud‐rich mass transport deposits, which is interpreted as representing a base of slope to lower slope setting. Evidence for channellization and indicators of bypass of coarse‐grained turbidity currents are more common in the upper part of the > 600 m thick succession (Units 3 and 4), which is interpreted as reflecting increased gradient conditions as the system accreted basinward.