Soil moisture dynamics under different land uses on karst hillslope in northwest Guangxi,China

Temporal and spatial dynamics of soil moisture are little known on karst hillslope with shallow soil in subtropical region. The objectives of this paper were (1) to investigate the temporal dynamics of soil moisture at depth of 0–10 cm under different land uses; and (2) to understand the relationship between mean and coefficient of variation (CV) of moisture contents on karst hillslope in northwest Guangxi, China. Soil moisture contents had a moderate variation (CV 17.5–30.3%) over an 8-month period and they had a significant difference among different land uses at the 0.01 level with a decreasing order: native scrubland > abandoned cropland and sloping cropland > economic forestland. There were higher mean and lower CV of moisture contents in rainy season than those in drought season. Mean and CV of moisture contents had a significant negative linear relationship except in abandoned cropland with higher soil and vegetation heterogeneity. This suggested that spatial variability of soil moisture within sampling sites would decrease when soils were wet and increase when soils were arid. Compared with rainy season, more soil samples may be needed and the interval for sampling should be shortened in drought season. Such information provided some insights to better understand the dynamics and variability of soil moisture at a larger scale in karst region of southwest China.     

Experimental modeling of the interaction of subducted carbonates and sulfur with mantle silicates

Experimental studies in the system Fe,Ni–olivine–carbonate–S (P = 6.3 GPa, T = 1050–1550°C, t = 40–60 h) aimed at modeling of the interaction of subducted carbonates and sulfur with rocks of the silicate mantle and at investigation of the likely mechanism of the formation of mantle sulfides were performed. It is shown that an association of olivine + orthopyroxene + magnesite + pyrite coexisting with a sulfur melt/fluid with dissolved Fe, Ni, and O is formed at T ≤ 1250°C. An association of low-Fe olivine, orthopyroxene, and magnesite and two immiscible melts of the carbonate and S–Fe–Ni–O compositions are formed at T ≥ 1350°C. It is shown that the reduced S-bearing fluids may transform silicates and carbonates, extract metals from the solid-phase matrix, and provide conditions for generation of sulfide melts.     

An approximate analytical solution for measuring air permeability of asphalt samples partially saturated with water

In coastal areas, abnormally high pressure may be caused by the tide-induced water table variation under extensive pavements, particularly during rainfall. To simulate the rainfall infiltration effects on the air permeability of asphalt pavements in coastal area, column-shaped asphalt sample was fixed in the upper part of a steel cylinder with its upper surface saturated with ponding water (depth < 5 mm) and open to the atmosphere. The cylinder’s lower part formed an air chamber. The chamber was pressurized and then the air therein was released naturally through the sample. The pressure variation with time in the chamber was recorded for analysis. Based on the Green–Ampt piston model for the surface water infiltration, an approximate analytical solution was derived to describe the pressure–time relationship in the chamber. A new parameter called the escape pressure was introduced to describe the air pressure needed for the chamber air to break through the capillary pressure induced by the ponding water. The analytical solution gave good estimations of both the escape pressures and the harmonic averages of the permeabilities of the wet and dry parts of 14 samples in the sense that excellent fittings were obtained between the observed and predicted air pressures in the air chamber. The estimated escape pressure ranges from 0.0 to 1.74 kPa. The harmonic average of the permeabilities of the wet and dry parts is 5–94% of the dry sample’s permeability.     

Seasonal and spatial variability of particulate matter of a muddy intertidal flood front

The concentration and composition of suspended particulate matter (SPM) were measured weekly for a period of one year in the flood front waters traversing a muddy tidal flat. SPM concentrations were lowest in the winter when portions of the tidal flat were covered with ice, and biological activity was minimal. In contrast, the summer months had the highest SPM concentrations which reflected increased bottom resuspension. The two main sources of SPM were suspended matter carried in from offshore on the flooding tide and resuspended in situ bottom sediments. The offshore source was characterized by low SPM concentrations, coarse textures, and a high content of protein and chlorophyll ‘a’. Samples taken during resuspension events (storms/showers) had high SPM concentrations, finer textures, and were enriched in dead detrital organic material (phaeophytin). At any one time the SPM was primarily an admixture of these two sources. The highest SPM measurements were taken during storm events, with rainfall seeming to play a dominant physical role in aiding resuspension. SPM concentrations, textures, and compositions collected during the storms closely approximated SPM measurements made over newly dug ‘clam flats’.     

Refined relationship between the position of the fundamental OH stretching and the first overtones for clays

The aim of this paper is to determine a relationship between the wavenumbers of the first OH-stretching overtones (W_2OH) and the wavenumbers of the OH-stretching fundamentals (W_OH) to help to interpret the near-infrared (NIR) spectra. The first overtone (2OH) bands appear at wavenumbers less than twice those of the fundamental bands (OH), due to the anharmonic character of vibrations, X = W_2OH/2 - W_OH, with X being the anharmonicity constant. Talc samples with various crystal chemistries are used to solve the equation and the experimental data are well fitted with X = –85.6 cm^–1. As far as the authors are aware, it is the first time that the anharmonicity constant for the OH-stretching vibrations is determined for phyllosilicates. The anharmonicity constant remains almost unchanged for several types of clay samples. Therefore the relation, established from talc samples because their absorption bands are narrow and their wavenumber range of OH vibrations is wide, can be used for any other clay minerals.     

Detection of blends in the vicinity of Zeeman lines

High resolution spectrograms taken in polarized light have revealed the presence of significant blending within the profiles of some important Zeeman multiplets of a large umbra. Wavelength and equivalent width of each depictable blend have been derived from the corrected spectrograms and some preliminary identifications have been made.