Allochthonous and autochthonous organic matter in surface waters in Karelia

A relationship between indirect chemical indices of organic matter content of surface waters and light absorption in the visible and ultraviolet ranges is discussed. The allochthonous and autochthonous types of organic matter are found to essentially differ in the rate of light absorption. Techniques are proposed for the calculation of the concentrations of allochthonous and autochthonous organic matter by the integral rate of light consumption in the visible region and the bichromate oxidability of water, as well as by three indirect indices: chemical oxygen demand, permanganate oxidability, and water color index. The mean concentrations of allochthonous and autochthonous organic matter in large lakes (Ladoga, Onega, and Baikal) and in rivers and smaller water bodies in Karelia (>300 water objects) are analyzed. Allochthonous organic matter was found to predominate in most surface waters of Karelia (>80%), while allochthonous organic matter predominates only in lakes with a small specific catchment area (supposedly, <5) and in highly eutrophic lakes.     

Dust-acoustic soliton in a plasma with multi-species ions and kappa-distributed electrons

In this work, we consider the formation of electrostatic, dust-acoustic solitary structure in a unmagnetized plasma with Lorentzian electrons (kappa-distributed) and more than one species of thermal ions (Maxwellian). The work is inspired by results of different space-based observations of electrostatic solitary waves (ESW) in the near-earth and magnetospheric plasmas and recent experimental realization of existence of superthermal electron component in various space plasmas. We have, in this work, shown that existence of compressive potential structure is possible only with more than one species of thermal ions. Besides, formation of compressive double layers is also possible which depends on the amount of deviation of the electron thermal velocities from a Maxwellian distribution. We show that both dust-temperature and super-thermal electrons lead to a decrease in the soliton amplitude.     

Comparing flow regime,channel hydraulics,and biological communities to infer flow–ecology relationships in the Mara River of Kenya and Tanzania

Abstract

Equatorial rivers of East Africa exhibit unusually complex seasonal and inter-annual flow regimes, and aquatic and adjacent terrestrial organisms have adapted to cope with this flow variability. This study examined the annual flow regime over the past 40 years for three gauging stations on the Mara River in Kenya and Tanzania, which is of international importance because it is the only perennial river traversing the Mara-Serengeti ecoregion. Select environmental flow components were quantified and converted to ecologically relevant hydraulic variables. Vegetation, macroinvertebrates, and fish were collected and identified at target study sites during low and high flows. The results were compared with available knowledge of the life histories and flow sensitivities of the riverine communities to infer flow–ecology relationships. Management implications are discussed, including the need to preserve a dynamic environmental flow regime to protect ecosystems in the region. The results for the Mara may serve as a useful model for river basins of the wider equatorial East Africa region.

Editor Z.W. Kundzewicz; Guest editor M. Acreman     

“Pure” supernovae and accelerated expansion of the Universe

A special class of type Ia supernovae that is not subject to ordinary and additional intragalactic gray absorption and chemical evolution has been identified. Analysis of the Hubble diagrams constructed for these supernovae confirms the accelerated expansion of the Universe irrespective of the chemical evolution and possible gray absorption in galaxies.     

Occurrence and characteristics of sporadic sodium layer observed by lidar at a mid-latitude location

Na lidar observations of SSL during the past 5 years at a mid-latitude location (Wuhan, China, 31°N, 114°E) are reported in this paper. From 26 SSL events detected in about 230 h of observation, an SSL occurrence rate of 1 event/9 h at our location was obtained. This result, combined with that reported by Nagasawa and Abo (Geophys. Res. Lett. 22 (1995) 263) at Tokyo, Japan, reveals that the SSL occurrence can be relatively frequent at some mid-latitude locations. The statistical analyses of main parameters for the 26 SSL events were made, and the results were compared with those previously reported. By examining the corresponding data from a nearby ionosonde, it was found that there was a fairly good correlation between SSL and Es. Of the 18 pairs of SSL and Es events checked, 15 of SSL were accompanied by Es, and 8 pairs of them were correlated within 1 h in time and within 5 km in altitude. From the analyses of observed perturbations during SSL development, the role of dynamic processes of atmosphere in the SSL formations were emphasized.     

Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.     

Rock physics template (RPT) analysis of well logs and seismic data for lithology and fluid classification in Cambay Basin

The Cambay Basin is 450-km-long north–south-trending graben with an average width of 50 km, having maximum depth of about 7 km. The origin of the Cambay and other Basins on the western margin of India are related to the break up of the Gondwana super-continent in the Late-Triassic to Early-Jurassic (215 ma). The structural disposition of the Pre-Cambrian basement—a complex of igneous and metamorphic rocks exposed in the vicinity of the Cambay Basin—controls its architecture. The principal lineaments in the Basin are aligned towards NE-SE, ENE-WSW and NNW-SSE, respectively. Rock physics templates (RPTs) are charts and graphs generated by using rock physics models, constrained by local geology, that serve as tools for lithology and fluid differentiation. RPT can act as a powerful tool in validating hydrocarbon anomalies in undrilled areas and assist in seismic interpretation and prospect evaluation. However, the success of RPT analysis depends on the availability of the local geological information and the use of the proper model. RPT analysis has been performed on well logs and seismic data of a particular study area in mid Cambay Basin. Rock physics diagnostic approach is adopted in the study area placed at mid Cambay Basin to estimate the volume in the reservoir sands from 6 wells (namely; A, B, C, D, E and F) where oil was already encountered in one well, D. In the study area, hydrocarbon prospective zone has been marked through compressional (P wave) and shear wave (S wave) impedance only. In the RPT analysis, we have plotted different kinds of graphical responses of Lame’s parameters, which are the function of P-wave velocity, S-wave velocity and density. The discrete thin sand reservoirs have been delineated through the RPT analysis. The reservoir pay sand thickness map of the study area has also been derived from RPT analysis and fluid characterization. Through this fluid characterization, oil-bearing thin sand layers have been found in well E including well D. The sand distribution results prove that this methodology has able to perform reservoir characterization and seismic data interpretation more quantitatively and efficiently.     

Authors' Reply

Abstract— Jull et al. propose an alternative interpretation of our depth vs. ¹⁴C data measured on a peat core from the central Tunguska impact site (Rasmussen et al., 1999). We find that the proposed alternative is untenable.