Mineralogical constraints on the high-silica martian surface component observed by TES

The Thermal Emission Spectrometer (TES) has observed a high-silica material in the dark regions of Mars that is spectrally similar to obsidian glass and may have a volcanic origin. An alternate interpretation is that the spectrally amorphous material consists of clay minerals or some other secondary material, formed by chemical alteration of surface rocks. The regions where this material is observed (e.g., Acidalia Planitia) have relatively high spectral contrast, suggesting that the high-silica material exists as coarse particulates, indurated soils or cements, within rocks, or as indurated coatings on rock surfaces. The geologic interpretation of this spectral result has major implications for understanding magmatic evolution and weathering processes on Mars. One of the complications in interpreting spectral observations of glasses and clay minerals is that both are structurally and compositionally complex. In this study, we perform a detailed spectroscopic analysis of indurated smectite clay minerals and relate their thermal emission spectral features to structural and crystal chemical properties. We examine the spectral similarities and differences between smectite clay minerals and obsidian glass from a structural-chemical perspective, and make further mineralogical interpretations from previous TES results. The results suggest that neither smectite clays nor any clay mineral with similar structural and chemical properties can adequately explain TES observations of high-silica materials in some martian dark regions. If the spectrally amorphous materials observed by TES do represent an alteration product, then these materials are likely to be poorly crystalline aluminosilicates. While all clay minerals have Si/O ratios ?0.4, the position of the emissivity minimum at Mars suggests a Si/O ratio of 0.4-0.5. The spectral observation could be explained by the existence of a silica-rich alteration product, such as Al- or Fe-bearing opal, an intimate physical mixture of relatively pure silica and other aluminosilicates (such as clay minerals or clay precursors), or certain zeolites. The chemical alteration of basaltic rocks on Mars to phyllosilicate-poor, silica-rich alteration products provides a geologically reasonable and consistent explanation for the global TES surface mineralogical results.     

Age and Origin of Upland block Fields on Melville Peninsula, Eastern Canadian Arctic

Block fields have developed on gently graded uplands of granite and gneiss on central and southern Melville Peninsula. The location of block fields is not controlled by elevation, but rather by areas covered by cold–based ice during the last glaciation. Block fields consist either of angular boulders, sorted circles 3–4 m across having blocky rims and central areas of weathered grus, concentrations of openwork boulders, or in the southeast, of immature bouldery till. The block fields are primarily relict features predating the last glaciation, produced by weakening of bedrock by weathering along joints, followed by frost heave, although some block fields have been modified by meltwater from regional glacier down–wasting. Frost processes are active in the modern environment but the extent of riven bedrock and the size of recent patterned ground forms on postglacial surfaces are insufficient to account for the forms in the block fields.     

Acute toxicity of inorganic mercury to Capitella

The polychaete worm Capitella capitata is shown to be fairly resistant to high concentrations of inorganic mercury. Survival of adults compared with those of the polychaete Ophryotrocha labronica shows that C. capitata can withstand 1 ppm Hg²⁺ for several days whilst O. labronica succombs to 0.5 ppm Hg²⁺ in 2 h.     

Comparing nitrogen isotopic signals between bulk sediments and invertebrate remains in High Arctic seabird-influenced ponds

The mass transport of nutrients by migratory animals can markedly alter the biogeochemistry and ecology of recipient ecosystems, particularly in nutrient-poor regions such as the Arctic. However, the role of biovectors in the global cycling of nutrients is often overlooked. Here we investigate nitrogen dynamics in two seabird-affected ponds in the Canadian High Arctic. The ponds lie at the base of a large seabird colony and have been greatly enriched in nutrients due to the input of guano and other wastes. Using sediment cores that span the last ~200 years, we measured stable isotopes of nitrogen (δ¹⁵N) in bulk sediments as well from the subfossil remains of chironomid (Diptera) head capsules and Daphnia ephippia. The bulk-sediment samples from our seabird-affected ponds had elevated δ¹⁵N values relative to seabird-free sites elsewhere in the Arctic. In general, the chironomid δ¹⁵N profiles roughly paralleled those of bulk sediments in both study ponds, while the Daphnia profile remained relatively stable in contrast to the considerable variation recorded in the bulk sediments and chironomids. Interestingly, no apparent pattern emerged among δ¹⁵N values recorded in the bulk sediments, chironomids, and Daphnia between the two study ponds. The stability recorded in the δ¹⁵N profiles from bulk sediments relative to the more variable invertebrate profiles point towards the complexity of nitrogen uptake by chironomids and Daphnia at these sites. These data suggest that the bulk sediments are integrating the different fractions of the overall δ¹⁵N pool and thus may be most appropriate for reconstructing overall trends in lake trophic status.     

Using 'the body' as an 'instrument of research': kimch'i and pavlova

Often researchers position themselves in relation to race, age and gender, but the body is less often discussed as an actual 'instrument of research'. We aim to extend thinking on this point by reflecting on a project we conducted on migrant women and food in New Zealand. We present a vignette as an example of how we used our bodies as 'instruments of research' at a 'shared lunch' attended by new migrants from a range of different countries. At the lunch some combined on their plates spicy dishes such as kimch'i (fermented vegetables) and sweet dishes such as pavlova (a meringue dessert). For others this combination prompted feelings of disgust. We conclude that the body is a primary tool through which all interactions and emotions filter in accessing research subjects and their geographies.     

Lithium and boron isotopes in illite-smectite: The importance of crystal size

Clay minerals record chemical data about the past, acting like natural computer memory chips. To retrieve the data we must understand how they are stored. To achieve this we have examined the isotopic information revealed by two trace elements, lithium and boron, that are incorporated into the common clay minerals illite-smectite (I-S) during diagenesis. We used hydrothermal experiments at 300°C, 100 MPa, to speed up the reaction of smectite to illite that normally occurs during slow (10-100 Ma) sediment burial. During illitization, Li substitutes into the octahedral sites and B enters the tetrahedral sites of the silicate framework. Both Li and B are also adsorbed in the interlayer of smectite, but Li is preferred over B in the exchange sites. To determine the equilibrium isotope fractionation of the two trace elements it is important to remove these adsorbed interlayer species. By measuring the isotopic composition of Li and B in the silicate framework during reaction, we can address the relative timing of element exchange in the different crystallographic sites. Furthermore, because illitization of smectite is a crystal growth process (not an isomorphous replacement) we have examined the effect of crystal size on the isotope fractionation.The results show that Li and B approach an isotopic steady state when R1 ordering occurs, long before oxygen isotopes equilibrate with the fluid. The isotopic fractionation (α_{mineral-water}) for Li (0.989) is similar to that for B (0.984) at 300°C. However, when separated into <0.2, 0.2-2.0, and >2.0 μm fractions, there are significant differences in measured isotope ratios by as much as 9‰. Crystal growth mechanisms and surface energy effects of nanoscale crystals may explain the observed isotopic differences. The fact that different crystals equilibrate at different rates (based on size) may be applied to natural samples to reveal the changing paleofluid history, provided we understand the conditions of equilibrium. This has very important implications for the interpretation of diagenetic environments, fluid flow, and surficial geochemical cycling.