Sources of polyfluoroalkyl compounds in the North Sea, Baltic Sea and Norwegian Sea: Evidence from their spatial distribution in surface water

The spatial distribution of 15 polyfluoroalkyl compounds (PFCs) in surface water was investigated in the North Sea, Baltic Sea and Norwegian Sea. In addition, an interlaboratory comparison of the sampling techniques and analysis was conducted. Highest concentration in the North Sea was found near the coast, whereas the ∑PFC concentration decreased rapidly from 18.4 to 0.07 ng l⁻¹ towards the open North Sea. The river Elbe could identify as a local input source for PFCs into the North Sea, whereas perfluorobutanoic acid (PFBA) was transported into the sampling area with the easterly current. In contrast to the North Sea, the distribution of PFCs in the Baltic Sea was relatively homogenous, where diffuse sources dominated. In general, the composition profile was influenced from local sources caused by human activities, whereas atmospheric depositions of here analysed PFCs were negligible, but it could have possibly an influence on low contaminated sites like the open North Sea or Norwegian Sea.     

A comparison of peak and plate electrodes in electrical resistivity tomography: application to the chalky groundwater of the Beauvais aquifer (northern part of the Paris basin,France)

Electrical resistivity tomography was used in order to explore an experimental site of the LaSalle Beauvais Polytechnic Institute (France). The test was conducted along a profile line of 315 m length, using 64 electrodes deployed at an inter‐electrode spacing of 5 m, and the data were recorded using gradient, Wenner and pole–dipole arrays. The performance of plate electrodes (non‐conventional flat‐based) is compared with the performance of peak electrodes (conventional spike). The hydrogeophysical investigation of the chalk aquifer system of Beauvais shows that the performance of plate electrodes is satisfactory, leading to inversions of small root‐mean‐square errors. Peak and the plate electrodes were tested before and after injection of a salt tracer in the piezometer of the experimental site. The study demonstrates the usefulness of plate electrodes (efficient, less time consuming) and the possibility of aquifer characterization by a salt tracer. Copyright © 2010 John Wiley & Sons, Ltd.     

Lead in the North Sea and the north east Atlantic Ocean

Lead has been determined in 105 water samples from the north east Atlantic and from the North Sea. Rigorous precautions were applied to avoid contamination during sampling and analysis.Two different analytical methods were used: ASV and AAS. Determinations with ASV were carried out on board, directly after sampling. After two months storage, acidified samples were analysed by AAS after freon dithiocarbamate extraction and nitric acid back extraction. Particulate lead was determined by AAS after an acid digestion.The profiles of lead concentration versus depth show around 160 pM at the surface and around 20 pM at the bottom, both in the Atlantic and in the Norwegian Sea. The shapes of the profiles are different, however, depending on the hydrography of the area sampled. The profiles from the north east Atlantic coincide with a recently published profile from the north west Atlantic. Moreover, these profiles have lead concentrations about a factor of three higher than those in the Pacific.Considering the high lead input to the North Sea, the lead concentrations found there are remarkably low, probably because of scavenging effects in estuaries leading to a short residence time in the water column. The dominant lead input in offshore regions is from the atmosphere. The highest lead levels are found in the northern North Sea, around 300 pM in surface water.In the Atlantic, particulate lead is a minor part of the total lead whereas in the North Sea the particulate fraction is larger, up to 40%.     

Holocene relative sea-level change, isostatic subsidence and the radial viscosity structure of the mantle of northwest Europe (Belgium, the Netherlands, Germany, southern North Sea)

A comprehensive observational database of Holocene relative sea-level (RSL) index points from northwest Europe (Belgium, the Netherlands, northwest Germany, southern North Sea) has been compiled in order to compare and reassess the data collected from the different countries/regions and by different workers on a common time–depth scale. RSL rise varies in magnitude and form between these regions, revealing a complex pattern of differential crustal movement which cannot be solely attributed to tectonic activity. It clearly contains a non-linear, glacio- and/or hydro-isostatic subsidence component, which is only small on the Belgian coastal plain but increases significantly to a value of ca 7.5 m relative to Belgium since 8 cal. ka BP along the northwest German coast. The subsidence is at least in part related to the Post-Glacial collapse of the so-called peripheral forebulge which developed around the Fennoscandian centre of ice loading during the Last Glacial Maximum. The RSL data have been compared to geodynamic Earth models in order to infer the radial viscosity structure of the Earth's mantle underneath NW Europe (lithosphere thickness, upper- and lower-mantle viscosity), and conversely to predict RSL in regions where we have only few observational data (e.g. in the southern North Sea). A very broad range of Earth parameters fit the Belgian RSL data, suggesting that glacial isostatic adjustment (GIA) only had a minor effect on Belgian crustal dynamics during and after the Last Ice Age. In contrast, a narrow range of Earth parameters define the southern North Sea region, reflecting the greater influence of GIA on these deeper/older samples. Modelled RSL data suggest that the zone of maximum forebulge subsidence runs in a relatively narrow, WNW–ESE trending band connecting the German federal state of Lower Saxony with the Dogger Bank area in the southern North Sea. Identification of the effects of local-scale factors such as past changes in tidal range or tectonic activity on the spatial and temporal variations of sea-level index points based on model-data comparisons is possible but is still complicated by the relatively large range of Earth model parameters fitting each RSL curve, emphasising the need for more high-quality observational data.     

Designing Service Architectures for Distributed Geoprocessing: Challenges and Future Directions

In this paper we study the feasibility of using services offered by a Spatial Data Infrastructure as a basis for distributed service oriented geoprocessing. By developing a prototype we demonstrate that a Spatial Data Infrastructure facilitates rapid development of applications that solve typical problems for an existing risk management application. The prototype provides users with a distributed application that enables the assessment of fire damage areas based on land cover data in a given area. The services involved in the application include: Web Feature Services, Web Map Services, a Gazetteer Service, a Catalogue Service, and Geoprocessing Services. We present the architecture of the application and describe details about implementation‐specific issues. We conclude that current OGC specifications provide a sound basis for developing service oriented architectures for geographic applications; however, in particular for geoprocessing applications, we question the feasibility of the use of Web Feature Services as data sources for larger amounts of data and call for further research in this direction.     

Changing patterns of the population distribution in Spain

The 1981 census has motivated this study, outlining changes in Spanish population patterns during the decade 1970–1981. For migration patterns the year 1975 may have been a significant turning point. As a consequence of the economic recession in the western world emigration is coming to an end; the interprovincial migration, too, is declining rapidly. In some provinces a remarkable change can be observed in the direction of migration flows. After more than 25 years the industrial regions of Spain are now losing population by migration, whereas rural provinces of the central highlands and of Andalusia exhibit some growth by migration for the first time. This is a result of return migration from abroad as well as from the industrial regions of Spain. For natural change three important dynamics overlap. First, a marked increase in natural growth from North to South is found. This pattern of natural change is strengthened or weakened regionally by age-specific selective migration. Lastly, both dynamics have recently been dominated by an overall decline of the crude birth rate in all of Spain since 1970.     

The cooling history of Silurian to Cretaceous alkaline ring complexes, south Eastern Desert, Egypt, as revealed by fission-track analysis

Forty fission-track ages of apatite, zircon and sphene, and nine horizontal “confined” track-length distribution patterns in apatite have been used to establish the cooling history of nine Silurian to Late Cretaceous alkaline ring complexes which intrude Precambrian basement in the southern Eastern Desert of Egypt. Zircon or sphene fission-track ages were determined from three complexes for whichK/Ar andRb/Sr ages on the same samples were also available, these ages are concordant and are interpreted as emplacement ages resulting from rapid cooling following high level crustal intrusion into relatively thick volcanic piles.Average apatite ages for each of the eight ring complexes range from 33 to 167 m.y. Track-length distribution patterns for apatites taken together with their ages invite subdivision into two groupings. Those complexes yielding Early Oligocene apparent apatite ages suggest cooling from the total track annealing zone followed by a relatively lengthy residence near the base of the partial annealing zone whereas those with Late Cretaceous ages indicate cooling from a shallower level in the partial annealing zone. Variations in cooling history resulted from differential uplift between fault-bound blocks. One block, that containing the Late Cretaceous Abu Khruq complex, was relatively stable and the different degrees of partial resetting recorded in apatites of this complex are attributed to the thermal effect of localised Tertiary dyke intrusion.Fission-track analysis in combination with geologic data indicates that in the south Eastern Desert of Egypt a phase of uplift commenced in Late Oligocene time and was accompanied by paleogeothermal gradients of ca. 40–50°C/km. Uplift was more pronounced (at least 2–2.5 km) in areas within about 100 km from the present Red Sea coast. This uplift, which is viewed as part of a broader regional tectonism related to the opening of the Red Sea, occurred along a northwest fracture pattern and was controlled by pre-existing lines of weakness in the basement complex.