Integrated models,scenarios and dynamics of climate,land use and common birds

Reconciling food, fiber and energy production with biodiversity conservation is among the greatest challenges of the century, especially in the face of climate change. Model-based scenarios linking climate, land use and biodiversity can be exceptionally useful tools for decision support in this context. We present a modeling framework that links climate projections, private land use decisions including farming, forest and urban uses and the abundances of common birds as an indicator of biodiversity. Our major innovation is to simultaneously integrate the direct impacts of climate change and land use on biodiversity as well as indirect impacts mediated by climate change effects on land use, all at very fine spatial resolution. In addition, our framework can be used to evaluate incentive-based conservation policies in terms of land use and biodiversity over several decades. The results for our case study in France indicate that the projected effects of climate change dominate the effects of land use on bird abundances. As a conservation policy, implementing a spatially uniform payment for pastures has a positive effect in relatively few locations and only on the least vulnerable bird species.     

Neoproterozoic to Lower Palaeozoic successions of the Tandilia System in Argentina: implication for the palaeotectonic framework of southwest Gondwana

The Cryogenian to Uppermost Ediacaran successions of the Tandilia System (Sierras Bayas Group and Cerro Negro Formation) in central-eastern Argentina is exceptional because of its unmetamorphosed and nearly undeformed character, its sediment provenance trend and the absence of any identified glacial deposit and the deposition of warm water carbonates. We decipher a dramatic change in the basin evolution from small-scale depositional areas during the Neoproterozoic to a larger basin related to an active continental margin throughout the Uppermost Ediacaran. The base of the succession is represented by immature detritus of alkaline composition (Villa Mónica Formation), but towards the top of this formation, the material is sorted and reworked, nonetheless still reflecting in its detritus the local rocks. The clastic deposition is interrupted by diagenetic overprinted dolomites. The unconformable overlying quartz-arenitic Ediacaran Cerro Largo Formation reworked the Cryogenian Villa Mónica Formation and contains mainly felsic granitic and metamorphic basement material of slightly wider variety, while the dominant alkaline geochemical signature in rocks of the Villa Mónica Formation disappears. Based on diagenetic, petrographic and sedimentological data, we can interpret the unconformity representing a longer time of erosion. The Cerro Largo Formation shows a transition to mudstones and the heterolithic facies of the Olavarría Formation. The top of the Sierras Bayas Group is represented by limestones (Loma Negra Formation), which are discordantly overlain by the Uppermost Ediacaran Cerro Negro Formation. The latter displays detrital material derived from a continental arc, mafic and felsic sources. Several arc-related geochemical proxies (Th/Sc?<?0.8; Zr/Sc?<?10; La/Sc?<?2; Ti/Zr?>?20) are recorded in the sediment detritus, as are syn-depositional pyroclastites. The absence of volcanic material in the underlying rocks allows proposing that the Cerro Negro Formation is related to an active continental margin fringing Gondwana (??Terra Australis Orogen??) as a retro-arc or retro-arc foreland basin.     

Self-diffusion of water and its dependence on temperature and ionic strength in highly compacted montmorillonite, illite and kaolinite

The effect of temperature and ionic strength on the diffusion of HTO parallel to the direction of compaction through 5 highly compacted clay minerals (bulk dry density, ρ_b,d = 1.90 ± 0.05 Mg/m³), namely montmorillonite (Na- and Ca-form), illite (Na- and Ca-form), and kaolinite, was studied. The diffusion experiments were carried out at temperatures between 0 °C and 60 °C and at ionic strengths of 0.01 M and 1 M NaCl for the Na-form clays and kaolinite, and of 0.005 M and 0.5 M CaCl₂ for the Ca-form. The ionic strength had an insignificant influence on the values of the effective diffusion coefficient (variation by less than 10%) for the clays under study at this degree of compaction. The effective diffusion coefficients followed the order Na-montmorillonite < Ca-montmorillonite < Ca-illite < Na-illite  kaolinite. It is thought that the differences between Na- and Ca-montmorillonite originate from the larger size particles, and thus the lower tortuosity of the latter; whereas the differences between Na- and Ca-illite are related to the different degree of solvation of the Na and Ca cations. The activation energies were successfully calculated using the Arrhenius law. Swelling clays (Na- and Ca-montmorillonite) had slightly larger activation energy values (20 kJ/mol) compared to bulk water (17 kJ/mol); Ca-illite (16 kJ/mol), Na-illite (13 kJ/mol) and kaolinite (14.4 kJ/mol) lower values than that of bulk water. The low activation energies of the last three clays may be related to weaker H-bonds between water and the clay surfaces compared to those in bulk water.     

A gamma‐ray spectroscopy survey of Omani meteorites

The gamma‐ray activities of 33 meteorite samples (30 ordinary chondrites, 1 Mars meteorite, 1 iron, 1 howardite) collected during Omani‐Swiss meteorite search campaigns 2001–2008 were nondestructively measured using an ultralow background gamma‐ray detector. The results provide several types of information: Potassium and thorium concentrations were found to range within typical values for the meteorite types. Similar mean ²⁶Al activities in groups of ordinary chondrites with (1) weathering degrees W0‐1 and low ¹⁴C terrestrial age and (2) weathering degree W3‐4 and high ¹⁴C terrestrial age are mostly consistent with activities observed in recent falls. The older group shows no significant depletion in ²⁶Al. Among the least weathered samples, one meteorite (SaU 424) was found to contain detectable ²²Na identifying it as a recent fall close to the year 2000. Based on an estimate of the surface area searched, the corresponding fall rate is ~120 events/10⁶ km²*a, consistent with other estimations. Twelve samples from the large JaH 091 strewn field (total mass ~4.5 t) show significant variations of ²⁶Al activities, including the highest values measured, consistent with a meteoroid radius of ~115 cm. Activities of ²³⁸U daughter elements demonstrate terrestrial contamination with ²²⁶Ra and possible loss of ²²²Rn. Recent contamination with small amounts of ¹³⁷Cs is ubiquitous. We conclude that gamma‐ray spectroscopy of a selection of meteorites with low degrees of weathering is particularly useful to detect recent falls among meteorites collected in hot deserts.     

Institutional ambiguity in implementing the European Union Marine Strategy Framework Directive

This article addresses the institutional ambiguity that exists between the European, Regional and Member State levels in the implementation of the Marine Strategy Framework Directive (MSFD). The two main reasons for the emergence of institutional ambiguity are (1) the MSFD being a framework directive and (2) Member States are required to coordinate the implementation of the MFSD through the Regional Sea Conventions. Institutional ambiguity refers to the interference zone between different institutional settings that come together in new policy practices. New rules of the game are needed to bring these institutional settings together and the room to manoeuvre for the actors who negotiate these rules is a defining feature of institutional ambiguity. This article analyses the institutional ambiguity associated with MSFD implementation on the European and regional level for four European Seas: the North Sea, the Baltic Sea, the Mediterranean Sea and the Black Sea. The results indicate different levels of institutional ambiguity in each of the four regions, with the lowest level of ambiguity in the Baltic Sea and the highest in the Mediterranean Sea. Institutional ambiguity also exists on the European level, as coordination efforts have not resulted in clear directions for the implementation of the MSFD as yet. The level of institutional ambiguity is influenced by the relative number of EU member states bordering the particular sea and whether they consider implementation of the MFSD to be urgent. Member States bordering the Mediterranean and the Black Seas lack the support of Regional Sea Conventions in addition to receiving limited direction from the European level.     

Sedimentary record of redox-sensitive elements (U, Mn, Mo) in a transitory anoxic basin (the Thau lagoon, France)

In order to further document the relation between redox conditions and the sedimentary record of Mn, U and Mo in a transitory anoxic water basin, their distribution has been studied along two profiles in the Thau lagoon (France). Sediments and pore-water have been sampled at two contrasting sites located, respectively, in the shellfish-farming area and in the centre of the lagoon. In the shellfish-farming area, the particulate organic carbon (POC) data indicate a more rapid organic matter mineralisation compared to the centre of the lagoon. This results in a sharper redox gradient characterized by the appearance of H₂S in pore-water a few millimetres below the sediment–water interface. In the centre of the lagoon, H₂S appears at a depth of 35 cm.In both cores, sedimentary Mn is relatively depleted through out the whole sedimentary column and varies with the proportion of clay minerals. After an initial release into solution at the sediment–water interface in relation to Mn-oxide reductive dissolution, authigenic U is immobilized when sulphides appear. Despite the occurrence of anoxic conditions at the sediment–water interface at the site influenced by shellfish farming, the burial of U is reduced by bioturbation, which raises reducing sediments to the surface. In the centre of the lagoon, Mo profiles reflect continuous diffusion into pore water and immobilization at 15 cm probably in anoxic microenvironments. At shellfish farms, dissolved Mo undergoes removal with sulphides but contrary to U, sedimentary Mo does not appear to be strongly affected by bioturbation. The profile indicates an increase in the frequency of anoxia crises during the second half of the 20th century.     

SN 1994W: an interacting supernova or two interacting shells?

We present a multi-epoch quantitative spectroscopic analysis of the Type IIn supernova (Type IIn SN) 1994W, an event interpreted by Chugai et al. as stemming from the interaction between the ejecta of a SN and a  0.4 M_⊙  circumstellar shell ejected 1.5 yr before core collapse. During the brightening phase, our models suggest that the source of optical radiation is not unique, perhaps associated with an inner optically thick cold dense shell and outer optically thin shocked material. During the fading phase, our models support a single source of radiation, an hydrogen-rich optically thick layer with a near-constant temperature of ∼7000 K that recedes from a radius of  4.3 × 10¹⁵  at a peak to  2.3 × 10¹⁵ cm  40 d later. We reproduce the hybrid narrow-core broad-wing line profile shapes of SN 1994W at all times, invoking an optically thick photosphere exclusively (i.e. without any external optically thick shell). In SN 1994W, slow expansion makes scattering with thermal electrons a key escape mechanism for photons trapped in optically thick line cores, and allows the resulting broad incoherent electron-scattering wings to be seen around narrow-line cores. In SNe with larger expansion velocities, the thermal broadening due to incoherent scattering is masked by the broad profile and the dominant frequency redshift occasioned by bulk motions. Given the absence of broad lines at all times and the very low ⁵⁶Ni yields, we speculate whether SN 1994W could have resulted from an interaction between two ejected shells without core collapse. The high conversion efficiency of kinetic to thermal energy may not require a SN-like energy budget for SN1994W.     

Book reviews

Pure and Applied Geophysics -