Coexisting K-rich alkaline and shoshonitic magmatism of arc affinities in the Proterozoic: a reassessment of syenitic stocks in the southwestern Grenville Province

Biotite-rich syenitic stocks in the Mont-Laurier area of the southwestern Grenville Province are shown to belong to the first recorded Proterozoic example of an ultrapotassic, K-rich alkaline and shoshonitic rock association with clear arc affinities. The plutons investigated were previously considered mostly syenitic, typical of nepheline syenite alkaline suites, slightly metamorphosed and late-tectonic with respect to the Grenville orogeny. We find that they postdate the regional metamorphism and comprise a felsic to ultramafic range of rock types belonging to two series: (1) a potassic-to-ultrapotassic, silica-undersaturated series of biotite-rich nepheline-bearing syenite, syenite, monzonite, diorite and pyroxenite, and (2) a shoshonitic, critically silicasaturated series of quartz syenite and amphibole-bearing syenite, with rare monzonite and diorite. The ubiquitous biotite, previously regarded as metamorphic, is reinterpreted as igneous and diagnostic of the potassic character. The shoshonitic and potassic series display the strong enrichment in Al, Ca, K and large-ion-lithophile elements relative to the high-field-strength elements (e.g. Ba/Nb722, La/YB45) and the low contents in Mg that are characteristic of arc-related magmas. The syenitic rocks consistently share the distinctive arc-related geochemical signature of their mafic counterparts. Syenites may thus represent a potential source of paleotectonic information for high grade terranes. Geochemical discriminants (Nb_N/Ta_N and Hf_N/Ti_N ratios) indicate that the shoshonitic and potassic series are unrelated by closedsystem fractionation processes. Rather, the chemical differences between the two series probably reflect differences in source characteristics and conditions of melting. Similar plutons occur throughout the Central Metasedimentary Belt of the southwestern Grenville Province. They define a 1089 to 1076 Ma, 450-km-long grenvillian potassic alkaline plutonic (PAP) province. The presence of this K-rich alkaline province indicates that the scarcity of K-rich rocks in the Precambrian could be only apparent and a consequence of misidentification of K-rich plutons in metamorphosed Precambrian terranes. These 1.1 Ga ultrapotassic to shoshonitic plutonic rocks are geochemically similar to shoshonites and leucitites of the Sunda arc. This similarity suggests that subduction-type enrichment processes were operating in the Proterozoic in ways similar to those of modern settings.     

Damage formation associated with bending under a constant moment

Deformation within the Earth's lithosphere is largely controlled by the rheology of the rock. Fracture and faulting are characterized by elastic rheologies with brittle mechanisms, while folding and flow are characterized by plastic and/or viscous rheologies due to ductile mechanisms. However, it has been recognized that deformation that resembles ductile behavior can be produced within the confines of the brittle lithosphere. Specific examples are folds that form in the shallow crust, steep hinges at subduction zones that are accompanied by seismicity, and large-scale deformation at plate boundaries. In these cases, the brittle lithosphere behaves elastically with fracture and faulting yet produces ductile behavior. In this paper, we attempt to simulate such ductile behavior in elastic materials using continuum damage mechanics. Engineers utilize damage mechanics to model the continuum deformation of brittle materials. We utilize a modified form of damage mechanics that represents a reduction in frictional strength of preexisting fractures and faults. We use this empirical approach to simulate the bending of the lithosphere under the application of a constant moment.We use numerical simulations to obtain elastostatic solutions for plate bending and where the longitudinal stress at a particular node exceeds a yield stress, we apply damage to reduce Young's modulus at the node. Damage is calculated at each time step by a power-law relationship of the ratio of the yield stress to the longitudinal stress and the yield strain to the longitudinal strain. This results in the relaxation of the material due to increasing damage. To test our method, we apply our damage rheology to an infinite plate deforming under a constant bending moment. We simulate a wide range of behaviors from slow relaxation to instantaneous failure, over timescales that span six orders of magnitude. Using this method, stress relaxation produces elastic-perfectly plastic behavior in cases where failure does not occur. For cases of failure, we observe a rapid increase in damage leading to failure, analogous to the acceleration of microcrack formation and acoustic emissions prior to failure. The changes in the rate of damage accumulation in failure cases are similar to the changes in b-values of acoustic emissions observed in triaxial compression tests of fractured rock and b-value changes prior to some large earthquakes. Thus continuum damage mechanics can simulate the phenomenon of ductile behavior due to brittle mechanisms as well as observations of laboratory experiments and seismicity.     

Comparison of Fiberglass and Other Polymeric Well Casings Part II. Sorption and Leaching of Trace-Level Organics

This paper contains the results of a laboratory study that was designed to compare sorption of low (mg/L) concentrations of 11 organic solutes by six polymeric materials (acrylonitrile butadiene styrene [ABS], fluorinated ethylene propylene [FEP], fiberglass-reinforced epoxy [FRE] and fiberglass-reinforced plastic [FRP], polyvinyl chloride [PVC], and poly-tetrafluoroethylene [PTFE]).
During this six-week study, ABS sorbed analytes much more rapidly and to a greater extent than did the other materials, and PVC and FRE sorbed analytes more slowly and to a lesser extent than the other materials tested.
As the study progressed, an increasing number of spurious peaks were found in the high performance liquid chromatography (HPLC) chromatograms of some of our samples, indicating that leaching of some consituents had occurred. By the end of the study, there were 11 additional peaks in the ABS samples, five in the FRP samples, and one in the FRE samples. Analysis by purge and trap gas chromatography/mass spectrometry (GC/MS) of those samples and of well water samples that were exposed to the casings for 500 hours revealed the identity of some of the leached constituents; acrylonitrile and styrene (components of ABS), chloroform and ethylbenzene (an intermediate in the production of styrene) from the ABS pipe, and toluene, 1,1,1-trichloroethane, and ethylbenzene from the FRP casing.     

Rb-Sr provenance ages from weathered and stream transported quartz grains from the Harney Peak Granite,Black Hills,South Dakota

Weathered quartz grus and stream transported quartz of the Harney Peak Granite, Black Hills, South Dakota, contain low concentrations of Rb (generally 0.3–6.8 ppm) and Sr (0.2–2.0 ppm) and variable Sr isotopic ratios (0.759–1.070).Six of seven single grains of large composite quartz grus which recently entered the weathering environment define an apparent isochron age (about 1800 Myr) and initial ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratio (0.7066) that approximate the whole-rock isochron age (1707 Myr) and initial ratio (0.7143) of the Harney Peak Granite. Apparently the Rb-Sr systematics of these grains were not significantly altered during initial weathering. Leached fluid inclusion material from a ca. 2 g aggregate of composite quartz grains contains very little Rb or Sr (0.019 and 0.17 μg, respectively) and has a very low ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratio (0.739). The Rb and Sr content of the quartz grains appears to be concentrated in minute, heterogeneously-distributed mineral inclusions.Five aggregates of more completely weathered, small non-composite quartz grains produce a widely scattered pattern on an isochron diagram with all samples plotting below the 1707 Myr isochron. Examination by SEM of these grains shows solution and precipitation features on their relatively large effective surface areas. The differential precipitation of Rb is believed to have been the major perturbating chemical process during weathering.Three aggregates of stream quartz grains define an apparent isochron age of 1777 Myr and an initial ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratio of 0.720 that suggest the initial ‘igneous’ Rb-Sr characteristics of the stream quartz were re-attained during their transportation, probably as a result of removal of the outer weathered surface by abrasion. The apparent resistance to chemical weathering of stream quartz and quartz which has just entered the weathering environment suggests that this mineral may be extremely useful in studies of provenance and the geochronology of strongly weathered terranes.     

A spectral optimally interpolated mean sea surface from satellite radar altimetry

 A technique is presented for the development of a high-precision and high-resolution mean sea surface model utilising radar altimetric sea surface heights extracted from the geodetic phase of the European Space Agency (ESA) ERS-1 mission. The methodology uses a cubic-spline fit of dual ERS-1 and TOPEX crossovers for the minimisation of radial orbit error. Fourier domain processing techniques are used for spectral optimal interpolation of the mean sea surface in order to reduce residual errors within the initial model. The EGM96 gravity field and sea surface topography models are used as reference fields as part of the determination of spectral components required for the optimal interpolation algorithm. A comparison between the final model and 10 cycles of TOPEX sea surface heights shows differences of between 12.3 and 13.8 cm root mean square (RMS). An un-optimally interpolated surface comparison with TOPEX data gave differences of between 15.7 and 16.2 cm RMS. The methodology results in an approximately 10-cm improvement in accuracy. Further improvement will be attained with the inclusion of stacked altimetry from both current and future missions. Received: 22 December 1999 / Accepted: 6 November 2000     

Chloride loading in the South Fork of the Shenandoah River,Virginia, U.S.A.

Loading trends and sources of CI^– in the South Fork of the Shenandoah River, Virginia were analyzed for the period 1929–1982. CI^– has increased from approximately 2 mg/L (2,776 tons/yr) to over 10 mg/L (14,256 tons/yr). Natural CI^– is estimated to be 1.01 mg/L (1,388 tons/yr) with precipitation providing 0.99 mg/L and rocks 0.02 mg/L. From 1929 to 1949 CI^– concentrations were relatively constant and independent of discharge, conforming to the Type II curve of Davis and Zobrist (1978), indicative of natural or relatively uncontaminated streams. Since 1952 CI^– concentrations increased exponentially as river discharge decreases conforming to the Type I curve of Davis and Zobrist for polluted streams. Since 1965 anthropogenic CI^– loading at 12,868 tons/yr has remained relatively constant. Four major sources contribute 92.2 percent (11,871 tons/yr) of the anthropogenic CI^–: (1) deicing salts—4,149 tons/yr, (2) domestic sewage—3,015 tons/yr, (3) livestock and poultry wastes—2,458 tons/yr, and (4) commercial fertilizers—2,249 tons/yr.     

1.1 Ga K-rich alkaline plutonism in the SW Grenville Province

U–Pb zircon and baddeleyite dating of six syenitic stocks establishes that the ultrapotassic, potassic alkaline and shoshonitic magmatism with island-arc affinities in the Central Metasedimentary Belt (CMB) of the southwestern Grenville Province, Canada took place between 1089 and 1076 Ma, along a 400-km-long, northeast-trending plutonic belt. These ages indicate that ultrapotassic rocks with arc affinities are not unique to the Phanerozoic. West to east emplacement ages along a northern and southern cross-section of this belt range from 1083±2 Ma (Kensington), through 1081±2 Ma (Lac Rouge) to 1076 _–1 ⁺³ Ma (Loranger) in the north, and from 1089 _–3 ⁺⁴ Ma (loon Lake) and 1088±2 Ma (Calabogie), to 1076±2 Ma (Westport) in the south. Although closely spaced in time, in detail these ages suggest a slight younging of this magmatic activity to the southeast. Integration of the geochronological data with the spatial extent and potassic character of the plutons shows that the K-rich alkaline suite is distinct from the nepheline-syenite belt of the Bancroft terrane and from the syenite-monzonite suite of the Frontenac terrane of the CMB, and it is considered to be a magmatic episode unique to the Elzevir terrane and its Gatineau segment. The timing and the postmetamorphic emplacement of these plutons indicate that the regional greenschist to granulite-facies metamorphism of the country rock (precise age unknown) is older than 1089 Ma throughout the entire Elzevir terrane. The potassic magmatism is interpreted as the initiation of the 1090–1050 Ma Ottawan Orogeny in the Elzevir terrane; thus, the regional metamorphism in this terrane, previously assigned to the Ottawan Orogeny, is an earlier event. The contemporaneous emplacement of this postmetamorphic plutonic belt with Keweenawan volcanism is at variance with current tectonic models which consider the Keweenawan rift to be formed at the same time as regional metamorphism in the CMB.     

The concept of hydrological connectivity and its contribution to understanding runoff‐dominated geomorphic systems

The term ‘connectivity’ is increasingly being applied in hydrological and geomorphological studies. Relevant research encompasses aspects of landscape connectivity, hydrological connectivity and sedimentological connectivity. Unlike other disciplines, notably ecology, published studies show no consensus on a standard definition. This paper provides an overview of how existing research relates to the concept of connectivity in both ecology and hydrology by proposing and evaluating a conceptual model of hydrological connectivity that includes five major components: climate; hillslope runoff potential; landscape position; delivery pathway and lateral connectivity. We also evaluate a proposed measure of connectivity called the volume to breakthrough to quantify changing connectivity between different environments and catchments. Copyright © 2007 John Wiley & Sons, Ltd.