Stress and temperature in the bending lithosphere as constrained by experimental rock mechanics

Summary. Previous attempts to deduce the stress distribution in the bending lithosphere near a consuming plate margin have relied on the observed bathymetry and an assumed constitutive relation for lithospheric behaviour, e.g. perfectly elastic, viscous/perfectly plastic, or elastic perfectly plastic. From the point of view of rock mechanics, each of these approximations fails to describe one or more of several basic phenomena, including brittle failure of rock, temperature dependence of elasticity, and temperature and/or strain rate dependence of ductile behaviour. In order to formulate a more realistic constitutive relation, a limiting yield strength curve, which is primarily a function of temperature, is constructed from data from brittle failure and ductile flow experiments. The moments which can be supported by plates with this constitutive behaviour are compared to the moments calculated from bathymetric profiles. The comparison indicates that moments required by the bathymetric data are consistent with moments supported by plates with experimentally determined constitutive laws as extrapolated to geologically reasonable temperatures and strain rates. The stresses developed in such models are required to reach values greater than 100 MPa† in the depth range 25–45 km. Geotherms necessary for strength curves consistent with moments calculated from the bathymetric data match those derived from heat flow data for the Aleutian, Bonin, Mariana and Tonga trenches. Of the trenches studied, only the geotherm inferred from the Kuril trench data is significantly different, perhaps implying that the Kuril plate is weaker than the others. The strength curves show that as a first approximation it is better to assume that bending moment is independent of curvature of the plate than to assume that bending moment and curvature are linearly related.     

Kinematics of SDSS subdwarfs: structure and substructure of the Milky Way halo

We construct a new sample of ∼1700 solar neighbourhood halo subdwarfs from the Sloan Digital Sky Survey (SDSS), selected using a reduced proper-motion diagram. Radial velocities come from the SDSS spectra and proper motions from the light-motion curve catalogue of Bramich et al. Using a photometric parallax relation to estimate distances gives us the full phase-space coordinates. Typical velocity errors are in the range  30–50 km s⁻¹  . This halo sample is one of the largest constructed to date and the disc contamination is at a level of ≲1 per cent. This enables us to calculate the halo velocity dispersion to excellent accuracy. We find that the velocity dispersion tensor is aligned in spherical polar coordinates and that  (σ _r , σ_φ, σ_θ) = (143 ± 2, 82 ± 2, 77 ± 2) km s⁻¹  . The stellar halo exhibits no net rotation, although the distribution of   v _φ  shows tentative evidence for asymmetry. The kinematics are consistent with a mildly flattened stellar density falling with distance like   r ^−3.75  .
Using the full phase-space coordinates, we look for signs of kinematic substructure in the stellar halo. We find evidence for four discrete overdensities localized in angular momentum and suggest that they may be possible accretion remnants. The most prominent is the solar neighbourhood stream previously identified by Helmi et al., but the remaining three are new. One of these overdensities is potentially associated with a group of four globular clusters (NGC 5466, NGC 6934, M2 and M13) and raises the possibility that these could have been accreted as part of a much larger progenitor.     

Cloud motion analysis using multichannel correlation-relaxation labeling

Cloud motion vectors derived from sequences of remotely sensed data are widely used by numerical weather prediction models and other meteorological and climatic applications. One approach to computing cloud motion vectors is the correlation-relaxation labeling technique, in which a set of candidate vectors for each template is refined using relaxation labeling to provide a local smoothness constraint. In this letter, an extension of the correlation-relaxation labeling framework to tracking clouds in multichannel imagery is presented. As this multichannel approach takes advantage of the diversity between channels, it has the potential for producing motion vectors with a superior quality and coverage than can be achieved by any individual channel. Results for visible and infrared images from Meteostat Second Generation confirm the benefits of the multichannel approach.     

Searching for social justice in GIScience publications

ABSTRACT

Maps are explicitly positioned within the realms of power, representation, and epistemology; this article sets out to explore how these ideas are manifest in the academic Geographic Information Science (GIScience) literature. We analyze 10 years of literature (2005–2014) from top tier GIScience journals specific to the geoweb and geographic crowdsourcing. We then broaden our search to include three additional journals outside the technical GIScience journals and contrast them to the initial findings. We use this comparison to discuss the apparent technical and social divide present within the literature. Our findings demonstrate little explicit engagement with topics of social justice, marginalization, and empowerment within our subset of almost 1200 GIScience papers. The social, environmental, and political nature of participation, mapmaking, and maps necessitates greater reflection on the creation, design, and implementation of the geoweb and geographic crowdsourcing. We argue that the merging of the technical and social has already occurred in practice, and for GIScience to remain relevant for contributors and users of crowdsourced maps, researchers and practitioners must heed two decades of calls for substantial and critical engagement with the geoweb and crowdsourcing as social, environmental, and political processes.     

Intercomparison of NO,NO2 and HNO3 measurements with photochemical theory

The simultaneous measurements of NO, NO₂ and HNO_A mixing‐ratio profiles carried out on the Stratoprobe balloon flight of 22 July 1974 have been simulated with a time‐dependent model using the measured temperature and ozone profiles. The calculated ratios of NO/NO₂, HNO₃/NO₂ using currently accepted photochemistry are consistent with the measured ratios within the experimental errors of the measurements. The measured NO₂/NO ratio is almost a factor of two smaller than predicted, although the discrepancy is still within the experimental errors. A remarkable proportionality in the NO₂ and O₃ profiles has been noted and is unexplained. A time‐dependent simulation has been employed to convert the measurements into diurnally‐averaged profiles suitable for intercomparison with two‐dimensional stratospheric models and a comparison with constituent profiles from Prinn et al. (1975) is carried out as an example. The NO_V mixing ratio, formed from the sum of the NO, NO₂ and HNO₂ measurements is similar to the NO_V mixing ratio from several one‐ and two‐dimensional models used to predict the effects of SST's on the ozone layer. The odd nitrogen mixing ratio is roughly constant from 20 to 35 km at 11 ppbv.     

Polyatomic Interferences Produced by Macroelements During Direct Multi-Elemental ICP-MS Hydrochemical Analysis

An experimental study of the interferences produced by macroelements (Na, K, Ca, Mg, Sr, S, Cl, Si, N and C) contained in natural waters during inductively coupled plasma-mass spectrometry (ICP-MS) is presented. The most significant interferences created by these elements were found to be SO, CO, CAr, SiH, SiO, NaH, NaAr, MgAr, CaO, KO and KAr, the magnitude of which was dependant on the concentration of each macroelement. To reduce these interferences, different approaches, for example, desolvating nebulisation, high resolution and dynamic reaction cell ICP-MS were applied and compared. All three approaches were found to be useful tools for significantly reducing various polyatomic interferences. Advantages and disadvantages for each approach are discussed.