Acigöl rhyolite field,Central Anatolia (part 1): high-resolution dating of eruption episodes and zircon growth rates

Protracted pre-eruptive zircon residence is frequently detected in continental rhyolites and can conflict with thermal models, indicating briefer magma cooling durations if scaled to erupted volumes. Here, we present combined U-Th and (U-Th)/He zircon ages from the Acigöl rhyolite field (Central Anatolia, Turkey), which is part of a Quaternary bimodal volcanic complex. Unlike other geochronometers, this approach dates crystallization and eruption on the same crystals, allowing for internal consistency testing. Despite the overall longevity of Acigöl rhyolite volcanism and systematic trends of progressive depletion in compatible trace elements and decreasing zircon saturation temperatures, we find that zircon crystallized in two brief pulses corresponding to eruptions in the eastern and western part of the field during Middle and Late Pleistocene times, respectively. For Late Pleistocene zircon, resolvable differences exist between interior (average: 30.7 ± 0.9 ka; 1σ error) and rim (21.9 ± 1.3 ka) crystallization ages. These translate into radial crystal growth rates of ~10^?13 to 10^?14 cm/s, broadly consistent with those constrained by diffusion experiments. Rim crystallization and (U-Th)/He eruption ages (24.2 ± 0.4 ka) overlap within uncertainty. Evidence for brief zircon residence at Acigöl contrasts with many other rhyolite fields, suggesting that protracted zircon crystallization in, or recycling from, long-lived crystal mushes is not ubiquitous in continental silicic magma systems. Instead, the span of pre-eruptive zircon ages is consistent with autochthonous crystallization in individual small-volume magma batches that originated from basaltic precursors.     

In Situ Destruction of Perchlorate and Nitrate Using Gaseous Electron Donor Injection Technology

Perchlorate and nitrate in vadose‐zone soil can be continuing sources of groundwater contamination and technologies for remediation of these sources are limited. Gaseous electron donor injection technology (GEDIT) is an in situ approach that was demonstrated at a site in California. A mixture of hydrogen, carbon dioxide, liquefied petroleum gas (LPG), and nitrogen was injected into the vadose zone over a period of 5 months followed by 3 months of LPG alone. Perchlorate and nitrate plus nitrite nitrogen concentrations were reduced by over 90% and both were capable of being reduced to nondetectable concentrations. Hydrogen was required for perchlorate destruction, although concentrations as low as 0.5% were effective. Hydrogen was not required for nitrate destruction. Contaminant destruction was observed in both fine‐grained and coarse‐grained soils ranging from clay to gravel. Hydrogen was an effective electron donor because of its low molecular weight and high diffusivity which likely promoted its penetration into low‐permeability formations. Contaminant destruction was also observed in moisture contents ranging from 6.8% to 36% demonstrating that GEDIT was effective in low‐ and high‐moisture soils. The radius of influence (ROI) for perchlorate destruction was approximately 3.0 to 4.6 m while that for nitrate was greater than 17 m. The ROI was limited by use of a single injection location. Use of a grid injection system is anticipated to greatly increase efficiency. This research represents the first demonstration of GEDIT for treatment of contaminants in the vadose zone.     

Timing of basin inversion on the Isle of Wight: New evidence from geophysical log correlation, seismic sections and lateral facies change in the Palaeogene Headon Hill Formation

Paleogene thickness patterns across the Bouldnor Syncline and Porchfield Anticline in the northwestern Isle of Wight have been deduced using outcrop information, borehole correlation, gamma-ray logs and seismic reflection data. The thickness patterns provide evidence for an early phase of basin inversion at around the Bartonian-Priabonian boundary (Late Eocene) in the Isle of Wight. Paleogene strata older than the Becton Sand Formation show little evidence for significant lateral changes in thickness, even though the boreholes are located at various structural positions around the Bouldnor Syncline and Porchfield Anticline. In contrast, both seismic reflection and borehole data provide evidence for marked thinning of Paleogene strata onto the Porchfield Anticline at around the level of the Becton Sand Formation and basal Headon Hill Formation (Totland Bay Member) which probably results from an episode of basin inversion and growth folding. The inversion event was relatively minor and short-lived and continues to point toward the main phase of the basin inversion being late Oligocene or younger. However, it still has important implications for understanding structural control on sedimentation patterns in the Headon Hill Formation, with the migration of sandy channelised depositional systems into the axis of the Bouldnor Syncline, and the sequence stratigraphic significance of the important Bartonian-Priabonian regression event, which may related to tectonics rather than global sea-level change.     

An efficient forward model of the climate controls on interannual variation in tree-ring width

We present a simple, efficient, process-based forward model of tree-ring growth, called Vaganov–Shashkin-Lite (VS-Lite), that requires as inputs only latitude and monthly temperature and precipitation. Simulations of six bristlecone pine ring-width chronologies demonstrate the interpretability of model output as an accurate representation of the climatic controls on growth. Ensemble simulations by VS-Lite of two networks of North American ring-width chronologies correlate with observations at higher significance levels on average than simulations formed by regression of ring width on the principal components of the same monthly climate data. VS-Lite retains more skill outside of calibration intervals than does the principal components regression approach. It captures the dominant low- and high-frequency spatiotemporal ring-width signals in the network with an inhomogeneous, multivariate relationship to climate. Because continuous meteorological data are most widely available at monthly temporal resolution, our model extends the set of sites at which forward-modeling studies are possible. Other potential uses of VS-Lite include generation of synthetic ring-width series for pseudo-proxy studies, as a data level model in data assimilation-based climate reconstructions, and for bias estimation in actual ring-width index series.     

Source Identification of Florida Bay's Methylmercury Problem: Mainland Runoff Versus Atmospheric Deposition and <Emphasis Type="Italic">In situ</Emphasis> Production

The first advisory to limit consumption of Florida Bay fish due to mercury was issued in 1995. Studies done by others in the late 1990s found elevated water column concentrations of both total Hg (THg) and methylmercury (MeHg) in creeks discharging from the Everglades, which had its own recognized mercury problem. To investigate the significance of allochthonous MeHg discharging from the upstream freshwater Everglades, we collected surface water and sediment along two transects from 2000 to 2002. Concentrations of THg and MeHg, ranging from 0.36 ng THg/L to 5.98 ng THg/L and from <0.02 ng MeHg/L to 1.79 ng MeHg/L, were elevated in the mangrove transition zone when compared both to upstream canals and the open waters of Florida Bay. Sediment concentrations ranged from 5.8 ng THg/g to 145.6 ng THg/g and from 0.05 ng MeHg/g to 5.4 ng MeHg/g, with MeHg as a percentage of THg occasionally elevated in the open bay. Methylation assays indicated that sediments from Florida Bay have the potential to methylate Hg. Assessment of mass loading suggests that canals delivering stormwater from the northern Everglades are not as large a source as direct atmospheric deposition and in situ methylation, especially within the mangrove transition zone.     

Standard candles from the Gaia perspective

The ESA Gaia mission will bring a new era to the domain of standard candles. Progresses in this domain will be achieved thanks to unprecedented astrometric precision, whole-sky coverage and the combination of photometric, spectrophotometric and spectroscopic measurements. The fundamental outcome of the mission will be the Gaia catalogue produced by the Gaia Data Analysis and Processing Consortium (DPAC), which will contain a variable source classification and specific properties for stars of specific variability types. We review what will be produced for Cepheids, RR Lyrae, Long Period Variable stars and eclipsing binaries.     

Platinum–palladium–gold mineralization in the Nkenja mafic–ultramafic body, Ubendian metamorphic belt, Tanzania

Significant and widespread enrichment of platinum, palladium, and gold has been found within the Nkenja mafic–ultramafic body located in southern Tanzania in the central part of the Ubendian metamorphic belt. This body is dominated by partly serpentinized chromitiferous dunite, wehrlite and olivine clinopyroxenite, which are tectonically intercalated with amphibolitized metagabbro. The dunites contain both disseminated and seam-type chrome spinel with an Al-rich composition. The seams are thin, impersistent and, together with enclosing dunite, often show deformation at granulite facies conditions. Forsterite contents of olivine in the dunite range from 87 to 92?mol%. Clinopyroxene in wehrlite and clinopyroxenite is diopsidic with significant contents of Al and Na. Clinopyroxene forms irregular bands and crosscutting veins in the dunite, as well as occurring as weakly dispersed isolated grains in the dunite. Elevated levels of Pt, Pd and Au occur in all ultramafic rocks, but not amphibolitized metagabbro, and there is a weak correlation between high abundances of platinum-group element (PGE) and chromitites. PGE values are erratically distributed and are associated with trace to minor amounts of disseminated sulphides (pyrrhotite, pentlandite, heazlewoodite, chalcopyrite and bornite). The abundances of all PGE are consistently anomalous, suggesting a primary igneous control by sulphides in ultramafic rock. However, there has evidently been a strong metamorphic and/or hydrothermal overprint on what was probably an original magmatic concentration of PGE-bearing sulphides. Geological mapping and petrological evidence, as well as the style of PGE sulphide mineralization, are consistent with the Nkenja ultramafic body being part of the crustal section of a dismembered Palaeoproterozoic ophiolite.     

Deltas: the fertile dustbins of the continents

Deltas and their associated deep-water submarine fans are the main repositories of sediment produced by continental erosion. The internal structure of prograding deltas is often complicated by changes in loci of deposition and changes in land-sea levels during their formation. The high water content and rapid deposition cause syn-sedimentary deformation. Deltas have been inhabited by man throughout history due to their rich surface resources. Ancient deltas are rich in hydrocarbons which are widely exploited. They are very sensitive to changes in the hinterland and today their existence is threatened by anthropogenic actions such as dam construction and sea-level changes.     

Revised identification of a reported Iguanodon-grade ornithopod tooth from the Scollard Formation, Alberta, Canada

An isolated tooth from the late Maastrichtian strata of the Scollard Formation of Alberta, Canada, has been identified as the only record of a non-hadrosaurid hadrosauriform from the Maastrichtian of North America. Here, we demonstrate that this identification is in error and that the tooth pertains to an indeterminate ceratopsid. In addition, we provide full documentation of the published collection of Scollard Formation fossils from which the tooth was originally derived.