The alteration history of the Jbilet Winselwan CM carbonaceous chondrite: An analog for C‐type asteroid sample return

Jbilet Winselwan is one of the largest CM carbonaceous chondrites available for study. Its light, major, and trace elemental compositions are within the range of other CM chondrites. Chondrules are surrounded by dusty rims and set within a matrix of phyllosilicates, oxides, and sulfides. Calcium‐ and aluminum‐rich inclusions (CAIs) are present at ≤1 vol% and at least one contains melilite. Jbilet Winselwan is a breccia containing diverse lithologies that experienced varying degrees of aqueous alteration. In most lithologies, the chondrules and CAIs are partially altered and the metal abundance is low (<1 vol%), consistent with petrologic subtypes 2.7–2.4 on the Rubin et al. ( 2007 ) scale. However, chondrules and CAIs in some lithologies are completely altered suggesting more extensive hydration to petrologic subtypes ≤2.3. Following hydration, some lithologies suffered thermal metamorphism at 400–500 °C. Bulk X‐ray diffraction shows that Jbilet Winselwan consists of a highly disordered and/or very fine‐grained phase (73 vol%), which we infer was originally phyllosilicates prior to dehydration during a thermal metamorphic event(s). Some aliquots of Jbilet Winselwan also show significant depletions in volatile elements such as He and Cd. The heating was probably short‐lived and caused by impacts. Jbilet Winselwan samples a mixture of hydrated and dehydrated materials from a primitive water‐rich asteroid. It may therefore be a good analog for the types of materials that will be encountered by the Hayabusa‐2 and OSIRIS‐REx asteroid sample‐return missions.     

Resurge gullies and “inverted sombrero” morphology,Flynn Creek impact structure,Tennessee

The Flynn Creek impact structure is an approximately 3.8 km diameter, marine‐target impact structure, which is located in north central Tennessee, USA. The target stratigraphy consists of several hundreds of meters of Ordovician carbonate strata, specifically Knox Group through Catheys‐Leipers Formation. Like other, similarly sized marine‐target impact craters, Flynn Creek's crater moat‐filling deposits include, in stratigraphic order, gravity‐driven slump material, aqueous resurge deposits, and secular (postimpact) aqueous settling deposits. In the present study, we show that Flynn Creek also possesses previously undescribed erosional resurge gullies and an annular, sloping surface that comprises an outer crater rim surrounding an inner, nested bowl‐shaped crater, thus forming a concentric crater structure. Considering this morphology, the Flynn Creek impact structure has a crater shape that has been referred to at other craters as an “inverted sombrero.” In this paper, we describe the annular rim and the inner crater at Flynn Creek using geographic information system technology. We relate these geomorphic features to the marine environment of crater formation, and compare the Flynn Creek impact structure with other marine‐target impact structures having similar features.     

Alkali‐halogen metasomatism of the CM carbonaceous chondrites

Meteorite Hills (MET) 01075 is unique among the CM carbonaceous chondrites in containing the feldspathoid mineral sodalite, and hence it may provide valuable evidence for a nebular or parent body process that has not been previously recorded by this meteorite group. MET 01075 is composed of aqueously altered chondrules and calcium‐ and aluminum‐rich inclusions (CAIs) in a matrix that is predominantly made of serpentine‐ and tochilinite‐rich particles. The chondrules have been impact flattened and define a foliation petrofabric. Sodalite occurs in a 0.6 mm size CAI that also contains spinel, perovskite, and diopside together with Fe‐rich phyllosilicate and calcite. By analogy with feldspathoid‐bearing CAIs in the CV and CO carbonaceous chondrites, the sodalite is interpreted to have formed by replacement of melilite or anorthite during alkali‐halogen metasomatism in a parent body environment. While it is possible that the CAI was metasomatized in a precursor parent body, then excavated and incorporated into the MET 01075 parent body, in situ metasomatism is the favored model. The brief episode of relatively high temperature water–rock interaction was driven by radiogenic or impact heating, and most of the evidence for metasomatism was erased by subsequent lower temperature aqueous alteration. MET 01075 is very unusual in sampling a CM parent body region that underwent early alkali‐halogen metasomatism and has retained one of its products.     

Smart Cartographic Background Symbolization for Map Mashups in Geoportals: A Proof of Concept by Example of Landuse Representation

Geospatial data are now widely available to the general public thanks to geoportals and online mapping platforms. However, creating a map involves more than just combining data layers. Thus we develop cartographic functions for geoportals to support better visual hierarchy in user map mashups. This includes a couple of preparatory steps followed by a smart cartographic background symbolization derived from the original layer style. We evaluate different approaches to background symbolization: greyscale, desaturation, and smart background. The different background symbolization methods are analysed with two concrete map examples and evaluated with a survey. The smart background symbolization developed in this work improves the visual hierarchy of the map mashup by reducing the visual importance of the background layers.     

Environmental Perception,Sense of Place,and Residence Time in the Okavango Delta,Botswana

Integral to the geographic discipline are cross-cultural analyses, many of which use languages outside of the researcher’s own. There are few analyses, however, that address issues of translation that are inherently geographic; namely, that language is understood as a manifestation of place and culture. This article argues that the results of environmental interviews must be interpreted through a lens that evaluates how the translation of a word, or even a concept, is understood differentially based on one’s sense of place. Interviews were conducted in three of the Etsha villages situated in the Okavango Delta, Botswana, comparing perceptions of changes in both the local area and the flooding regime. Findings show qualitatively and quantitatively how residents perceive environmental change in light of their residential histories and their production of place. These results highlight that environmental change in an area is perceived in the context of previous residences, including the length of time spent in residence and the environmental characterization of that place. The process of interviewing regarding such change, especially when translation is necessary, should therefore proceed by incorporating inquiries about previous residences and the environments of those areas to correctly contextualize environmental change in a particular area.     

The Avalon Zone: A Pan-African terrane in the Appalachian Orogen of Canada

The Precambrian sequences of the Avalon Zone in Canada (southeastern margin of the Appalachian Orogen) are interpreted as a Pan-African orogenic belt incorporated into the Appalachian Orogen during Palaeozoic times as its southeastern margin. The Precambrian evolution of the Avalon Zone was genetically unrelated to subsequent Palaeozoic evolution. The Avalon Zone shows marked similarities in age, tectonic history, and facies development to the Pan-African belts adjacent to the West African Craton. Precambrian evolution of the zone began with circa 800 Ma rifting of a sialic gneissic basement and deposition of a Middle Proterozoic(?) carbonate-clastic cover sequence. Early crustal rifting was associated with localized partial melting and metamorphism. Limited crustal separation led to the restricted development of circa 760 Ma oceanic volcanics. Continued rifting and subsequent closure of these narrow ocean basins led to the eruption of widespread subaerial volcanic suites, block faulting, granite plutonism, and local, late Proterozoic sedimentary basin formation. Precambrian evolution of the zone terminated with the Avalonian Orogeny (circa 650-600 Ma), a deformational event, the affects of which are most evident locally along the northwestern margin of the zone. The controlling features of the Proterozoic evolution of the Avalon Zone are a series of linear intracratonic troughs and small ocean basins that formed during thinning and separation of the crust by ductile spreading, rupture, and delamination (cf. Martin and Porada 1977). The variation in degree of crustal separation led to subsequent variation in orogenesis during late Proterozoic compression. The zone marks the original westward limit of Pan-African activity and displays no apparent genetic link with the Appalachian Orogen in Canada until Devonian times.     

Deepwater fold and thrust belt classification,tectonics, structure and hydrocarbon prospectivity: A review

Deepwater fold and thrust belts (DWFTBs) are classified into near-field stress-driven Type 1 systems confined to the sedimentary section, and Type 2 systems deformed by either far-field stresses alone, or mixed near- and far-field stresses. DWFTBs can occur at all stages of the Wilson cycle up to early stage continent continent collision. Type 1 systems have either weak shale or salt detachments, they occur predominantly on passive margins but can also be found in convergent-related areas such as the Mediterranean and N. Borneo. Examples include the Niger and Nile deltas, the west coast of Africa, and the Gulf of Mexico. Type 2 systems are subdivided on a tectonic setting basis into continent convergence zones and active margin DWFTBs. Continent convergence zones cover DWFTBs developed during continent–arc or continent–continent collision, and those in a deepwater intracontinental setting (e.g. W. Sulawesi, Makassar Straits). Active margins include accretionary prisms and transform margins. The greatest variability in DWFTB structural style occurs between salt and shale detachments, and not between tectonic settings. Changes in fold amplitude and wavelength appear to be more related to thickness of the sedimentary section than to DWFTB type. In comparison with shale, salt detachment DWFTBS display a lower critical wedge taper, more detachment folds, long and episodic duration of deformation and more variation in vergence. Structures unique to salt include canopies and nappes. Accretionary prisms also standout from other DWFTBs due to their relatively long, continuous duration, rapid offshore propagation of the thrust front, and large amount of shortening. In terms of petroleum systems, many similar issues affect all DWFTBs, these include: the oceanward decrease in heat flow, offshore increase in age of mature source rock, and causes of trap failure (e.g. leaky oblique and frontal thrust faults, breach of top seal by fluid pipes). One major difference between Type 1 and Type 2 systems is reservoir rock. High quality, continent-derived, quartz-rich sandstones are generally prevalent in Type 1 systems. More diagenetically reactive minerals derived from igneous and ophiolitic sources are commonly present in Type 2 systems, or many are simply poor in well-developed turbidite sandstone units. However, some Type 2 systems, particularly those adjacent to active orogenic belts are partially sourced by high quality continent-derived sandstones (e.g. NW Borneo, S. Caspian Sea, Columbus Basin). In some cases very high rates of deposition in accretionary prisms adjacent to orogenic belts, coupled with uplift due to collision, results in accretionary prism related fold belts that pass laterally from sub-aerial to deepwater conditions (e.g. S. Caspian Sea, Indo-Burma Ranges). The six major hydrocarbon producing regions of DWFTBs worldwide (Gulf of Mexico, Niger Delta, NW Borneo, Brazil, West Africa, S. Caspian Sea) stand out as differing from most other DWFTBs in certain fundamental ways, particularly the very large volume of sediment deposited in the basins, and/or the great thickness and extent of salt or overpressured shale sdetachments.     

Application of entropy analysis of in situ droplet-size spectra in evaluation of oil chemical dispersion efficacy

In situ droplet-size distributions were measured using a laser in situ scattering and transmissiometry (LISST-100X) particle size analyzer during the evaluation of natural and chemical dispersion efficiency of crude oils under different wave and current conditions. An entropy grouping of the in situ dispersed oil droplet-size spectra has classified the multi-modal droplet-size distributions into different groups based on similar droplet-size spectra characteristics within groups and distinction between groups. A generalized linear logistic regression model was fitted to analyze the effects of a number of factors and their interactions on the grouping of oil droplet-size spectra. The grouped results corresponded to the oil dispersion efficiency at different levels. This new method for droplet-size distribution data analysis can have significant implication in field evaluation of natural and chemical dispersion efficiency of oil.     

Impacts of diverted freshwater on dissolved organic matter and microbial communities in Barataria Bay, Louisiana, U.S.A

Here we present results of an initial assessment of the impacts of a water diversion event on the concentrations and chemical composition of dissolved organic matter (DOM) and bacterioplankton community composition in Barataria Bay, Louisiana U.S.A, an important estuary within the Mississippi River Delta complex. Concentrations and spectral properties of DOM, as reflected by UV/visible absorbance and fluorescence, were strikingly similar at 26 sites sampled along transects near two western and two eastern areas of Barataria Bay in July and September 2010. In September 2010, dissolved organic carbon (DOC) was significantly higher (568.1-1043 μM C, x=755.6+/-117.7 μM C, n=14) than in July 2010 (249.1-577.1 μM C, x=383.7+/-98.31 μM C, n=14); conversely, Abs254 was consistently higher at every site in July (0.105-0.314) than in September (0.080-0.221), averaging 0.24±0.06 in July and 0.15±0.04 in September. Fluorescence data via the fluorescence index (FI450/500) revealed that only 30% (8 of 26) of the July samples had an FI450/500 above 1.36, compared to 96% (25 of 26) for the September samples. This indicates a more terrestrial origin for the July DOM. Bacterioplankton from eastern sites differed in composition from bacterioplankon in western sites in July. These differences appeared to result from reduced salinities caused by the freshwater diversion. Bacterioplankton communities in September differed from those in July, but no spatial structure was observed. Thus, the trends in bacterioplankton and DOM were likely due to changes in water masses (e.g., input of Mississippi River water in July and a return to estuarine waters in September). Discharge of water from the Davis Pond Freshwater Diversion (DPFD) through Barataria Bay may have partially mitigated some adverse effects of the oil spill, inasmuch as DOM is concerned.