西藏努日矽卡岩型铜钨钼矿辉钼矿 Re-Os定年及其地质意义

西藏努日层状矽卡岩型铜钨钼矿床是冈底斯东段南缘斑岩-矽卡岩铜多金属成矿带上规模最大的矿床。笔者对采自该矿床的9件不同产状、不同形态含钼矿石中的辉钼矿进行了Re-Os同位素组成分析,获得其模式年龄为23.46~24.77 Ma,等时线年龄为(23.36±0.49) Ma(MSWD=0.60),模式年龄与等时线年龄结果基本一致。由于辉钼矿与黄铜矿、白钨矿呈共生关系,并考虑到该矿区内黄铜矿的年龄〔(23.75±0.18) Ma〕(作者未发表数据),表明努日矽卡岩型铜钨钼矿床的成矿时代为23~24 Ma。结合前人研究资料可见,冈底斯南缘克鲁-冲木达斑岩-矽卡岩铜多金属成矿带从32 Ma至23 Ma发生了强烈的成矿作用。该成矿带的成矿时代明显有别于后碰撞期地壳伸展环境下形成的冈底斯斑岩铜矿带,显示出其为一套独立的成矿事件。该成矿事件可能主要受冈底斯南缘的晚碰撞走滑环境的控制。努日矿床成矿时代的确定及晚碰撞成矿事件的厘定,为今后研究和勘查该成矿带内同类型矿床提供了重要依据。     

LIMS在我国地矿行业实验室的应用现状

实验室信息管理系统(LIMS)为实验室提供了便捷、准确、及时、规范的技术服务,已经被越来越多的实验室认可与应用。我国的LIMS研究和开发工作,相对于国外发达国家还处于落后水平。目前LIMS在我国地矿行业实验室还没有得到全面推广和应用,一些实验室仍然采用人工管理模式开展实验室相关任务的管理工作。本文通过较为广泛的调研,结果表明,地矿行业相关实验室对LIMS的建设主动性较高,大部分实验室希望通过自行研制或引进先进成果建设数字管理模式,实现信息化管理水平。     

双误差回归模型在ICP-MS测定饮用水中锶的不确定度评定的简化应用

在计算电感耦合等离子体质谱法测定饮用水中锶的浓度(x)时,由于标准系列配制和仪器检测过程中信号(y)漂移产生的不确定度会传递给最终的计算结果。普通的一次或多次线性拟合结果不能真实地反映对于x、y值都含误差的数据拟合情况。文章对标准曲线进行了双误差回归计算,从双误差回归线性方程推导出校准曲线拟合过程产生不确定度的计算公式,建立了方法检出限与曲线拟合参数(x、y、曲线截距和斜率)及其相关不确定度之间的关系式,依据误差连续传递公式及不确定度分量计算公式简化了合成不确定度的表达式。从合成不确定度计算公式中可得出,水样中锶含量的浓度越低,其对应的不确定度越大;标准系列配制过程不细致、仪器灵敏度低,方法检出限越差,与实际测试情况符合。     

南天山南缘下二叠统玄武质岩浆的地球化学特征及其构造意义

南天山造山带南缘发育大量的下二叠统火山岩。地球化学指标显示南天山南缘西段拜城县宿相厄肯沟出露的下二叠统小提坎立克组玄武岩为拉斑玄武岩(里特曼指数δ=2.93)。 该套岩石低FeO^T、MgO和全碱(Na₂O+K₂O),高CaO和Al₂O₃,相对高钠,低钾; Rb、K、U和Ba 等大离子亲石元素富集; 稀土配分曲线整体协调一致,为向右缓倾的曲线,轻稀土元素(LREE)相对富集; 微量元素配分型式呈"驼峰状"; 玄武岩的母岩浆经历了以单斜辉石为主的分离结晶作用和强烈的陆壳混染作用。同位素组成 ¹⁴³ Nd/¹⁴⁴ Nd =0.512 849±0.000 005, ⁸⁷ Sr/⁸⁶ Sr =0.706 845±0.000 014; -10<ε_Nd(t)<0,且ε_Sr(t)>0,模式年龄T_DM 为1.463 279 765 Ga。 结合区域地质资料表明,小提坎立克组玄武岩形成于板内伸展环境,具有主动裂谷作用性质,说明南天山造山带南缘当时处于碰撞后伸展背景。     

Chronology of the Tungsten Deposits in Southern Jiangxi Province,and Episodes and Zonation of the Regional W‐Sn Mineralization – Evidence from High‐precision Zircon U‐Pb,Molybdenite Re‐Os and Muscovite Ar‐Ar Ages

Previous studies have obtained some petrogenetic and metallogenic chronological data with SHRIMP (sensitive high-resolution ion microprobe) zircon U-Pb, zircon LA-ICPMS (laser-ablation–inductively coupled plasma mass spectroscopy) U-Pb, molybdenite Re-Os isochron and muscovite Ar-Ar methods in southern Jiangxi Province and its adjacent areas. Based on these, the purpose of this paper is to study the petrogenetic and metallogenic ages and their time gap for different genetic types of W-Sn deposits, and thus to research their numerous episodes, zonal arrangement and their geodynamic background. The result shows that the large-scale W-Sn mineralization in southern Jiangxi Province occurred in the middle to late Jurassic (170–150 Ma), the skarn W-Sn-polymetallic deposits formed much earlier (170–161 Ma), and all of the wolframite – quartz vein type, greisen type, altered granite type and fractured zone type tungsten deposits formed in the late Jurassic (160–150 Ma). In one ore field or ore district, greisen type tungsten deposits formed earlier than quartz vein type ones hosted in the endo- or exo-contact zone; and quartz vein type hosted in the endocontact zone formed earlier than that of exocontact zone. There is no significant time difference between tungsten-tin mineralization and its intimately associated parent granite emplacement (1–6 Ma). They all formed in the same rock-forming and ore-forming system and under the same geodynamic setting. Regionally, rock-forming and ore-forming processes of the W-Sn deposits in the Nanling region (include southern Jiangxi Province, southern Hunan Province, northern Guangdong Province and eastern Guangxi Zhuang Autonomous Region) exhibit numerous episodes. The mineralization in the Nanling region mainly occurred at (240–210) Ma, (170–150) Ma and (130–90) Ma. The tungsten-tin deposits in this region are centered by the largest scale in southern Jiangxi Province and southern Hunan Province, and become small in the east, west, south and north directions. This displays a zonal arrangement and temporal and spatial distribution regularity. Integrated with the latest research results, it is concluded that the W-Sn mineralization in southern Jiangxi Province and its adjacent areas corresponds to the second large-scale mineralization in South China. The Indosinian W-Sn mineralization formed under the extensional tectonic regime between collisional compressional stages, while the Yanshanian large-scale petrogenetic and metallogenic processes occurred in the Jurassic intraplate extensional geodynamic setting of lithosphere extension.     

延边八家子镇上南沟“大理岩”地质地球化学特征及地质意义

传统观点认为,延边八家子镇上南沟"大理岩"为碳酸盐岩地层经过区域变质作用形成。通过详细的野外和镜下观察,发现该"大理岩"并不发育层理等典型沉积岩的特征,而主要呈岩株和岩墙产出,与围岩新东村岩组片岩、片麻岩呈港湾状侵入式接触;且其中发育大量围岩捕虏体,"大理岩"局部还发育有冷凝边;除上南沟"大理岩"外,在上南沟及周边地区并没有碳酸盐岩地层的发育。分析显示,上南沟"大理岩"具有与火成碳酸岩相似的微量元素和稀土元素组成特征,C、O同位素组成处于火成碳酸岩受低温蚀变的演化趋势之内。因此,初步认为延边八家子上南沟"大理岩"并不是由碳酸盐岩地层经区域变质作用形成,其成因可能存在以下2种解释:一种是上南沟"大理岩"为火成碳酸岩,很可能是华北克拉通破坏事件在北缘的响应;另一种可能是大规模富含CO2流体运移的产物,是大规模流体运移成矿的典型范例。     

层序古地理背景下河南省二_1煤聚集规律研究

对河南省晚石炭世-早二叠世含煤岩系(太原组中部碎屑岩段、上部灰岩段和山西组二1煤层段、大占砂岩段)进行层序分析,共识别出以胡石砂岩底面、二1煤底面、大占砂岩底面和香炭砂岩底面为代表的4个层序界面,将该层段含煤岩系划分为3个三级层序。通过对层序S1和层序S3岩相古地理图和二1煤厚度等值线图耦合分析发现,障壁岛-潟湖沉积环境为二1煤的聚集提供一个较好的前期环境,分流间湾沉积环境为二1煤的保存提供一个较好的后期环境,而分流河道对二1煤的保存起到了破坏性的作用。     

http://www.sciencedirect.com/science/article/pii/S1674987112000606

Magmatic sulfide deposits are significantly valuable because more than 60%of the nickel and 99%of the platinum-group elements in the world are produced from these deposits,although Ni-laterite deposits are also an important type of nickel resource.The magmatic sulfide deposits are grouped into sulfide-rich Ni-Cu-(PGE) deposits and sulfide-poor PGE deposits.Although the research on the     

Vulnerability of groundwater systems with sea level rise in coastal aquifers, South Korea

Groundwater systems in coastal aquifers may be affected by sea level change as increased seawater intrusion occurs with sea level rise. Artificial pumping taking place at the same time will increase this impact. In order to estimate the vulnerability of groundwater systems with sea level rise within coastal aquifers in South Korea, long-term groundwater data were analyzed using basic statistics, trend analysis, and correlation analysis. Conductivity depth profiling was also periodically conducted. Groundwater levels increased in wells with relatively low groundwater elevations but decreased in wells with higher groundwater elevations. At the same time, conductivity variations were greater in wells located in reclaimed land areas, which vertical conductivity profiles indicated were more affected by sea level variations, but decreased on the mainland. Results of auto-correlation analysis showed a decreasing trend with cyclic variations and significant periodic patterns during dry seasons, indicating that groundwater levels were not affected by artificial factors and that those in reclaimed land areas were less affected by rainfall than on the mainland. These results coincided with those from cross-correlation analysis showing that groundwater level was affected by sea level variation during the dry season. Sea level changes, which may be related to climate change, as well as rainfall in South Korea can influence groundwater levels, and the groundwater system in reclaimed land areas may be more affected than on the mainland, especially under dry conditions.     

Assessment of changes in the area of the water conservation forest in the Qilian Mountains of China’s Gansu province, and the effects on water conservation

The Qilian Mountains water conservation forest in Gansu province is an important ecological barrier surrounding the oasis in China’s Hexi Corridor. The water they provide is the basis for the existence and sustainable socioeconomic development of those oases. As a result of unsustainable use of the water conservation forest until the 1980s, the oasis ecosystems of the Hexi region were seriously damaged, and the oasis areas experienced deterioration of their ecological environment. In this paper, Landsat images were used to monitor the temporal and spatial changes in area of water conservation in Qilian Mountains of China’s Gansu province and to assess the effect on water conservation by analyzed relationship between water conservation forest area, climatic data and hydrological data. The results showed that the forest covered 15.1% of the study area in 2007 and has followed different trends during the study period. From 1978 to 1990, the forest area decreased; however, from 1990 to 2007, the forest area increased, with a faster rate of increase from 1990 to 2000, and the rate of increase averaged 2,733.89 ha per year since 1990. The water conservation forest appears to play an important role in flood control, runoff regulation, the prevention of soil erosion, and water conservation; and these benefits increase with an increasing area of forest.