微波等离子体炬质谱技术快速鉴别天然石材与人造石材

天然石材主要有大理石、花岗岩等;人造石材多以不饱和聚酯树脂为基料,添加适量的无机物粉料和添加剂固化制成。由于石材种类繁多,并且各种石材的岩体所含矿物成分也有差异,当前很少应用化学成分分析方法准确、快速鉴别天然和人造石材,仅有的红外光谱法由于对待测物纯度的要求较高而具局限性。本文基于微波等离子体炬源(MPT)同时具有热解吸与强电离能力,能在短时间内离子化待测物的特点,采用微波等离子体炬质谱(MPT-MS)技术,无需样品复杂预处理直接对天然与人造石材进行分析,获得正离子检测模式下在m/z 50~1000之间的石材的指纹谱图,并运用化学计量学的主成分分析(PCA)方法处理所获取的数据,实现了不同建筑石材的区分。结果表明,MPT-MS能够获得石材丰富的指纹谱图,结合PCA方法能够快速鉴别天然石材与人造石材,天然石材中解吸出的物质主要为CO₂和H₂O的团簇分子;而人造石材中解吸出的主要成分为有机物(人为添加的黏合剂等)。本研究采用的MPT-MS技术无需采用喷雾、激光、基质和加热等方法辅助,并且无需对石材进行任何复杂的处理即可进行质谱分析,从而获取石材表面及内部物质的质谱信息,为快速直接鉴定石材样品提供了一种新的质谱分析方法。     

中国东北地区中生代构造体制的转变:来自火山岩时空分布与岩石组合的制约

东北地区中生代经历了蒙古-鄂霍茨克构造体系向太平洋构造体系的转换,形成了不同期次火山活动。本文归纳总结了露头区与覆盖区中生代火山岩的年代学、空间分布、岩石组合以及地球化学特征,揭示了两个构造域的时空分布范围。该区火山岩锆石U-Pb年龄统计结果表明中生代存在五期火山活动:早-中侏罗世(190~160Ma)、晚侏罗世(160~145Ma)、早白垩世早期(145~120Ma)、早白垩世晚期(120~100Ma)、晚白垩世早期(100~90Ma)。早-中侏罗世火山岩分布较少,火山岩仅分布在大兴安岭西部满洲里地区和东部张广才岭以及南侧辽宁北票-朝阳地区,火山岩属于高钾钙碱性系列,为蒙古-鄂霍茨克海闭合和法拉隆板块双俯冲作用的产物。晚侏罗世东北地区火山活动明显增强,主要分布在大兴安岭地区,张广才岭以及小兴安岭也有少量分布。西部大兴安岭地区以粗面安山岩、粗面岩为主,属于同碰撞造山成因,为蒙古-鄂霍茨克海闭合造山环境产物。东部以中酸性、酸性岩为主,为法拉隆板块背离欧亚大陆,岩石圈伸展引起的壳源物质熔融产物。早白垩世早期火山活动最为强烈,火山岩主要分布在大兴安岭地区。岩性以高钾钙碱性系列的粗面玄武安山岩、粗面安山岩、安山岩、粗面岩为主,为蒙古-鄂霍茨克海闭合造山后伸展环境产物。早白垩世晚期火山岩主要分布在松辽盆地内部。火山岩以中酸性岩为主,属于中钾-高钾钙碱性系列,为伊泽奈崎板块俯冲引起的弧后拉张,软流圈上涌导致年轻地壳熔融的产物。晚白垩世早期火山岩仅分布在小兴安岭及吉林、黑龙江省东部地区。火山岩为一套玄武岩、玄武安山岩、安山岩和英安岩组合,属于中钾钙碱性系列,是伊泽奈崎-库拉板块高角度俯冲的大陆边缘岩浆活动产物。东北地区中生代不同期次火山岩记录了蒙古-鄂霍茨克构造域向太平洋构造域转换过程及其时空影响范围。     

微量污染物应急及在线监测技术在珠江流域水源地的应用

法国AQUAPOD Light分析仪和AQUAPOD case应急监测仪用于微量有毒有机物和常规水质参数的在线监测,可对未知有机污染物发出报警,是实用性很强的微量污染物在线监测技术手段。基于该系统已建立了17个珠江流域特征有毒污染物的在线监测模型,将其应用于珠江重点饮用水源地,并对数据模型进行了检验;系统还具备常规参数的监测能力,其对COD、TOC和硝酸盐类等污染物监测的数据经与实验室内测试结果相比较,数据误差分布的检验结果表明其准确度和精密度均较好。     

松嫩平原耕层土壤固碳潜力估算

提高土壤碳收集能力对减缓全球温室效应具有重要意义。利用松嫩平原南部第二次土壤普查及多目标区域地球化学调查获取的两期表层土壤有机碳数据,根据近20年来各土壤类型不同土地利用方式土壤有机碳量变化趋势,估算了松嫩平原南部各土壤类型、各用地方式下土壤碳源、汇潜力。由估算得出,如果目前的土地利用方式、气候条件、耕作方式、种植技术不变,松嫩平原耕地土壤0~20 cm土层的固碳潜力为-1.229Tg碳,各土壤类型的林地土壤固碳潜力绝大多数为正值,说明林业用地为碳汇区,固碳潜力合计为3.169Tg碳,而天然牧草地绝大多数的固碳潜力为负值,固碳潜力合计为-2.235Tg碳,为碳源区,本次研究估算得出,松嫩平原总体的固碳潜力为-0.917Tg碳。     

贵州册亨岩架黑苗湾组的发现及其地质意义

作者在册亨尾排金矿普查地质填图工作中,于岩架镇高苕一带发现晚三叠世卡尼早期地层.根据岩性特征,将其划为黑苗湾组.本文对该地黑苗湾组的出露与分布及岩石地层特征进行详细介绍,并讨论其地质意义.     

黄土高原渭河宝鸡段北岸大型深层滑坡动力学机制研究

为研究渭河盆地黄土塬边大型深层滑坡运动机制,通过对渭河宝鸡段北岸斜坡构造地貌过程解析、滑体地质剖面平衡计算与运动过程的动态数值模拟,结合黏土岩滑动带发育的宏观力学背景、物理结构变化特征与剪切蠕变、滑动力学行为特征研究,确定了渭河北岸大型深层滑坡的几何学、运动学特征,初步揭示了黏土岩质滑带塑性流动挤出的控滑机制。研究表明:①大型深层滑坡的运动变形由后缘向坡脚传递,后缘下降、前缘隆起,整体变形由底部泥岩控制,具有一定的水平位移,是旋转-平移复活式滑坡;②黏土岩滑动带结构损伤形成蠕变变形带,滑动过程中,塑性变形区在滑体下方呈倾斜三角形状,产生塑性流动变形,逆冲向上运动中形成翻卷结构,滑体前缘以流动状态隆起挤出;③黏土岩的塑性流动变形是黏土矿物含量增加、活性增强的结果,滑带土内的粘粒含量(2μm)由初始的17.94%增加到50.22%,蒙脱石的绝对含量从初始的13.19%增加至26.38%,而其比表面积平均由124.55增加至215.08,从而降低滑动带的强度、恶化水理性质,引起滑体剧烈变形,而滑体内赋存的高孔隙水压力可推动滑体滑动。     

Mineral characteristics and their geological significance of black shales in southeastern Ordos Basin by X-ray diffraction analysis

X-ray diffraction analysis of black shale of Upper Triassic Member Chang 7 of the Yanchang Formation in southeastern Ordos Basin showed that black shales were deposited in brackish, strongly reducing, semi-deep-deep lacustrine facies, and mainly composed of quartz, feldspar, carbonate （dolomite）, clay minerals （illite and il- lite/smectite） and a certain amount of pyrite. The mineral composition characteristics of this set of black shales are similar to those of highly productive shale gas in North America, for example shallow burial, low clay mineral and abundant brittle mineral, so the strata are conducive to the development of cracks and fractures. Thus, this area is favorable for shale oil/gas exploration and development.     

Correlation analysis and partial least square modeling to quantify typical minerals with Chang＇E-3 visible and near-infrared imaging spectrometer＇s ground validation data

In 2013, Chang＇E-3 program will develop lunar mineral resources in-situ detection. A Visible and Near-infrared Imaging Spectrometer （VNIS） has been selected as one payload of CE-3 lunar rover to achieve this goal. It is critical and urgent to evaluate VNIS＇ spectrum data quality and validate quantification methods for mineral composition before its launch. Ground validation experiment of VNIS was carried out to complete the two goals, by simulating CE-3 lunar rover＇s detection environment on lunar surface in the laboratory. Based on the hyperspectral reflectance data derived, Correlation Analysis and Partial Least Square （CA-PLS） algorithm is applied to predict abundance of four lunar typical minerals （pyroxene, plagioclase, ilmenite and olivine） in their mixture. We firstly selected a set of VNIS＇ spectral parameters which highly correlated with minerals＇ abundance by correlation analysis （CA）, and then stepwise regression method was used to find out spectral parameters which make the largest contri- butions to the mineral contents. At last, functions were derived to link minerals＇ abundance and spectral parameters by partial least square （PLS） algorithm. Not considering the effect of maturity, agglutinate and Fe~, we found that there are wonderful correlations between these four minerals and VNIS＇ spectral parameters, e.g. the abundance of pyroxene correlates positively with the mixture＇s absorption depth, the value of absorption depth added as the in- creasing of pyroxene＇s abundance. But the abundance of plagioclase correlates negatively with the spectral parame- ters of band ratio, the value of band ratio would decrease when the abundance of plagioclase increased. Similar to plagioclase, the abundance of ilmenite and olivine has a negative correlation with the mixture＇s reflectance data, if the abundance of ilmenite or olivine increase, the reflectance values of the mixture will decrease. Through model validation, better estimates of pyroxene, plagioclase and ilmenite＇s abundances are given. It is concluded that VNIS has the capability to be applied on lunar minerals＇ identification, and CA-PLS algorithm has the potential to be used on lunar surface＇s in-situ detection for minerals＇ abundance prediction.     

The Metastable Phase Equilibria of the MeX-MgCl_2-H_2O Systems

正1 Introduction The Pingluoba brine,which characterized as high concentration with sodium,potassium,boron,lithium,and rubidium,possess great development value.The main composition of the brine can be summarized to the     

The Solid-liquid Transformation of Low-grade Solid Potash Deposit in Dalangtan Basin and the Simplification of the Liquid Phase System

正We studied the solid-liquid transformation of low-grade solid potash deposit in Dalangtan Basin and simplified the liquid phase system.We did experiments to optimize conditions of the solid-liquid transformation.The Suitable