Noble gases and mineralogy of meteorites from China and the Grove Mountains,Antarctica: A 0.05 Ma cosmic ray exposure age of GRV 98004

Abstract— We determined the mineralogical and chemical characteristics and the He, Ne, and Ar isotopic abundances of 2 meteorites that fell in China and of 2 meteorites that were recovered by the 15th Chinese Antarctic Research Expedition. Guangmingshan (H5), Zhuanghe (H5), and Grove Mountain (GRV) 98002 (L5) yield cosmic ray exposure (CRE) ages of 68.7 ± 10.0 Ma, 3.8 ± 0.6 Ma, and 17.0 ± 2.5 Ma, respectively. These ages are within the range typically observed for the respective meteorite types. GRV 98004 (H5) had an extremely short parent body‐Earth transfer time of 0.052 ± 0.008 Ma. Its petrography and mineral chemistry are indistinguishable from other typical H5 chondrites. Only 3 other meteorites exist with similarly low CRE ages: Farmington (L5), Galim (LL6), and ALH 82100 (CM2). We show that several asteroids in Earth‐crossing orbits, or in the main asteroid belt with orbits close to an ejection resonance, are spectrally matching candidates and may represent immediate precursor bodies of meteorites with CRE ages ≤0.1 Ma.     

Magnetic susceptibility variations of the Edicaran cap carbonates in the Yangtze platform and their implications for paleoclimate

1 INTRODUCTION One of the most intriguing phenomena in the late Neoproterozoic (~750 to 543 Ma) is the globa occurrence of thin carbonates that directly overlie glacial deposits in almost every continent (Kennedy 1996; Hoffman et al., 1998; Hoffman and Schrag 2002; Brasier and Shields, 2000; James et al., 2001 Jiang et al., 2003; Nogueira et al., 2003). These “cap carbonates”, commonly several to tens of meters thick, have attracted enormous interests because o their unusually negati…     

贵州和四川盆地云量的气候研究

贵州和四川盆地是我国云量最多的地区,素有“天无三日晴”和“蜀犬吠日”之说,盆地西缘的雅安古时还有“雅州天漏”的谚语。从全球日照百分率分布推知,川黔地区也是世界上天气最阴沉的地区之一。川黔之阴一向为国内外气象界所注意,本文根据1951—1980     

Energetic solar electrons in the interplanetary medium

ISEE-3 measurements extending down to 2 keV energy have provided a new perspective on energetic solar electrons in the interplanetary medium. Impulsive solar electron events are observed, on average, several times a day near solar maximum, with 40% detected only below 15 keV. The electron energy spectra have a nearly power-law shape extending smoothly down to 2 keV, indicating that the origin of these events is high in the corona. These coronal flare-like events often produced ³He-rich particle events.In large solar flares which accelerate electrons and ions to relativistic energies, the electron spectrum appears to be modified by a second acceleration which results in a double power-law shape above 10 keV with a break near 100 keV and flattening from 10–100 keV. Large flares result in long-lived (many days) streams of outflowing electrons which dominate the interplanetary fluxes at low energies. Even in the absence of solar activity, significant fluxes of low energy electrons flow out from the Sun.Solar type-III radio bursts are produced by the escaping 2–10² keV electrons through a beam-plasma instability. The detailed ISEE-3 measurements show that electron plasma waves are generated by the bump-on-tail distribution created by the faster electrons running ahead of the slower ones. These plasma waves appear to be converted into radio emission by nonlinear wave-wave interactions.     

Advances in our understanding of the gem corundum deposits of the West Pacific continental margins intraplate basaltic fields

Recent discoveries over the last decade of new gemfields, exploitation of new and existing deposits, and application of relatively new techniques have greatly increased our knowledge of the basalt-derived gem sapphire–ruby–zircon deposits. In this paper we focus on the Late Mesozoic to Cenozoic intraplate basaltic fields of the West Pacific continental margins. We review advances made in understanding the genesis of these deposits, based on the application of newer techniques. We also critically review existing data on the gem corundum deposits, in order to further refine a model for their origin.In some of the intraplate basaltic fields, corundum-bearing xenoliths have been found showing a range of PT formation conditions from 790 °C at 0.85 GPa to as much as 1100 to 1200 °C at 1.0 to 2.5 GPa. Although most magmatic sapphires contain syngenetic inclusions of columbite-group phases, zircon, spinel and rutile, some contain additional nepheline and K-feldspar, suggesting crystallization from more undersaturated alkaline magma while the Weldborough field of NE Tasmania also contains molybdenite and beryl, suggesting at least some interaction with more fractionated ‘granitic-type’ magmas. There is a large range in PT conditions calculated for the metamorphic rubies (from 780 to 940 °C, through 800 to 1150 °C up to 1000 to 1300 °C). Fluid/melt inclusion studies on magmatic corundums generally suggest that they formed in a CO₂-rich environment from a ‘syenitic’ melt under a range of T conditions from 720 to 880 °C up to 1000 to 1200 °C. Oxygen isotope studies reveal that typical magmatic corundums have values of + 4.4 to 6.9‰, whereas metamorphic corundums from the same basaltic host have lower values of + 1.3 to 4.2‰.Geochronological studies have shown that some fields produced a simple eruptive and zircon/corundum crystallization event while others had multiple eruptive events but only one or two zircon crystallization events. For a few fields, some corundums/zircons crystallized in storage regions and then remained relatively inert for periods of 200 to 400 Ma without significant change before transport to the surface in the Cenozoic. Tectonic studies of the Australian region suggest that many of the corundums crystallized from magmas related to episodic basaltic volcanism in a tectonic regime of extension, associated with the opening of the Tasman and Coral Seas. For the Asian region, the magmatic–polygenetic corundums within the basaltic fields largely crystallized in a tectonic regime of distributed E–W extension, whereas the metamorphic-metasomatic corundums crystallised in a transpressional regime associated with the collision of the Indian Plate with the Eurasian Plate (e.g., [Garnier, V., Giuliani, G., Maluski, H., Ohnenstetter, D., Deloule, E., 2003. Ar–Ar and U–Pb ages of marble-hosted ruby deposits from Central and South-east Asia. Geophysical Research Abstracts 5, 03751; Garnier, V., Giuliani, G., Ohnenstetter, D., and Schwarz, D., 2004. Les gisements de corindon: classification et genese. Les placers a corindon gemme. Le Regne Mineral 55, 7-47; Garnier, V., Ohnenstetter, D., Giuliani, G., Maluski, H., Deloule, E., Phan Trong, T., Pham Van, L., Hoang Quang, V., 2005a. Age and significance of ruby-bearing marble from the Red River Shear Zone, Northern Vietnam. Canadian Mineralogist 43, 1315–1329]).     

纺织品中偶氮染料还原液内芳香胺的电喷雾电离质谱分析

在优化的条件下,用电喷雾电离质谱(ESI-MS)检测了多种纺织品中由偶氮染料还原获得的芳香胺。当毛细管温度为100℃、鞘气流速为25单位、进样流速为10μL/min、电压为5kV时,信号的总离子流强度高且较稳定。实验分析了19种致癌芳香胺标准溶液的二级质谱,获得了相应物质的特征碎片离子;在此基础上,建立了基于ESI-MS对毛巾、棉布等样品中芳香胺进行快速定性分析的方法,具有灵敏度高、特异性好、检测速度快等优点。     

火试金法测定铜精矿中金含量结果的不确定度评定

对火试金法测定铜精矿中金含量的结果进行不确定度评定。分析了铜精矿样品称量、铜精矿样品的不均匀性和配料处理,以及金粒称量等因素对金含量测量结果不确定度的影响,并得出火试金法测量铜精矿中金含量的扩展不确定度。     

等离子体质谱法测定玄武岩中微量元素三种样品预处理方法的比较

在测定玄武岩的微量元素时,为了保证得到的微量元素结果反映源区特征,需经预处理去除玄武岩的孔洞中充填的碳酸盐等物质。选取雷州半岛新生代玄武岩三个样品,每一个样品用三种预处理方法进行预处理,等离子体质谱法测定其中的微量元素。分析结果表明,用稀硝酸浸泡样品,会导致玄武岩中大多数微量元素严重丢失,得到的数据失真;而用稀盐酸浸泡去除碳酸盐的方法基本不改变玄武岩中微量元素的含量。     

赣南淘锡坑钨多金属矿床花岗岩和云英岩岩石特征及云英岩中白云母40Ar/39Ar定年

赣南崇义县淘锡坑钨矿位于南岭东西向构造带东段,属于以黑钨矿石英脉型为主的钨多金属矿床。矿床形成与燕山期中酸性岩浆作用有密切关系,石英矿脉受一组北西向断裂控制,穿切新元古界。本文在淘锡坑钨矿区3个揭露到花岗岩体顶部的中段（206、106、56中段）采集到岩体顶部云英岩样品,利用40Ar/39Ar同位素定年测得云英岩中的白云母的坪年龄分别为152.7 ± 1.5 Ma（206中段）,153.4 ± 1.3 Ma（106中段）,155.0 ± 1.4 Ma（56中段）。与前人用其他方法测定的花岗岩成岩和成矿年龄几乎一致。花岗岩和云英岩全岩稀土元素均具有M型四分组效应和强烈的Eu亏损特征,反映出花岗质岩浆经历了高度分异演化及其岩体结晶晚期流体/熔体相互作用。综合前人在南岭地区同类矿床的研究资料,可知南岭地区160～150Ma成岩成矿作用主要分布于南岭中-东段,可能为大陆边缘弧后岩石圈伸展的构造动力学背景的产物。     

Zircon U–Pb and Hf isotopic study of gneissic rocks from the Chinese Altai: Progressive accretionary history in the early to middle Palaeozoic

Gneissic rocks in the Chinese Altai Mountains have been interpreted as either Paleozoic metasedimentary rocks or Precambrian basement. This study reports geochemical and geochronological data for banded paragneisses and associated gneissic granitoids collected along a NE–SW traverse in the northwestern Chinese Altai. Petrological and geochemical data suggest that the protoliths of the banded gneisses were possibly immature sediments with significant volcanic input and that the gneissic granitoids were derived from I-type granites formed in a subduction environment. Three types of morphological features can be recognized in zircons from the banded gneisses and are interpreted to correlate with different sources. Zircons from five samples of banded paragneiss cluster predominantly between 466 and 528 Ma, some give Neoproterozoic ages, and a few yield discordant Paleoproterozoic to Archean ages. Zircon Hf isotopic compositions indicate that both juvenile/mantle and crust materials were involved in the generation of the source rocks from which these zircons were derived. In contrast, zircons occur ubiquitously as elongated euhedral prismatic crystals in the four samples of the gneissic granitoids, and define single populations for each sample with mean ages between 380 and 453 Ma. The general absence of Precambrian inheritance and positive zircon ?Hf values for these granitoids suggest insignificant crustal contribution to the generation of the precursor magmas. Our data can be interpreted in terms of a progressive accretionary history in early to middle Palaeozoic times, and the Chinese Altai may possibly represent a magmatic arc built on a continental margin dominated by Neoproterozoic rocks.