Cation exchange capacity of loess and overlying soil in the non-carbonate loess sections, North-Western Croatia

The adsorption properties in terms of cation exchange capacity and their relation to the soil and sediment constituents (clay minerals, Fe-, Mn-, and Al-oxyhydroxides, organic matter) were investigated in loess, soil-loess transition zone, and soil at four loess-soil sections in North-Western Croatia. Cation exchange capacity of the bulk samples, the samples after oxalate extraction of Fe, Mn and Al, and after removal of organic matter, as well as of the separated clay fraction, was determined using copper ethylenediamine. Cation exchange capacity (pH～7) of the bulk samples ranges from 5 to 12 cmol _c /kg in soil, from 7 to 15 cmol _c /kg in the soil-loess transition zone, and from 12 to 20 cmol _c /kg in loess. Generally, CEC values increase with depth. Oxalate extraction of Fe, Mn, and Al, and removal of organic matter cause a CEC decrease of 3–38% and 8–55%, respectively, proving a considerable influence of these constituents to the bulk CEC values. In the separated clay fraction (<2 μm) CEC values are up to several times higher relative to those in the bulk samples. The measured CEC values of the bulk samples generally correspond to the clay mineral content identified. Also, a slight increase in muscovite/illite content with depth and the vermiculite occurrence in the loess horizon are concomitant with the CEC increase in deeper horizons, irrespective of the sample pretreatment.     

Regional trends in European induction data

n ¶rt;a, n¶rt;mau 531 au ¶rt; u aum m u¶rt;uu n mumu ana¶rt;, ¶rt; u -m n, aauum ¶rt;um u u amuaa n¶rt;naa ma ua aama. uu nmam an¶rt;u ¶rt; u aum aam ¶rt;au cuu uP _n ^m , n¶rt;am mn n=1, 2, 3 u 5 (m n). u uua ¶rt;a¶rt;amu uu n¶rt;mauu uum au (a. 1) u u n aumam uu nmu, m n¶rt;mam u¶rt; am uuu ¶rt; u aum (u. 1–4). annuau 2 u 5 mn nm ma am mmmu m (u. 5, 6). ama uuu u m aam amu uu uma.     

Mechanism of solar-terrestrial relations and changes of atmospheric circulation

Summary As a result of investigating the relations between the variations of geomagnetic activity and meteorological factors [1, 2] a mechanism of solar-terrestrial relationships and a model of the changes of atmospheric circulation in the Northern Hemisphere are proposed; this provides an explanation of the causes of the fluctuation of the climate, of dry and cold periods and differing vegetation conditions in various years in dependence on the intensity of geomagnetic activity.     

Secondary vorticity centres as centres of secondary (streamwise) vorticity

Summary The theory of secondary vorticity is used to explain the essence of so-called secondary or upper vorticity centres, discovered on satellite photographs. The general equation of vorticity, which is then adjusted by means of the equations of state and motion, is transformed into a specially selected intrinsic co-ordinate system. Three-component equations of vorticity are discussed for cases important meteorologically. The conclusion could be drawn that the secondary vorticity centres may be identified with centres of so-called secondary vorticity and that the theoretical facts about their origin and occurrence may be used, together with satellite photographs, to improve weather forecasts.     

GIS-based land suitability analysis integrating multi-criteria evaluation for the allocation of potential pollution sources

The geological environment has been heavily polluted by chemical substances over the past few decades. Pollution sources located on the earth’s surface or underground have affected the quality of the environment. A significant amount of impact could be reduced if the allocation of potential pollution sources was based on an evaluation of environmental conditions. The main objective of this study was to develop a methodology for the allocation of potential pollution sources by employing GIS and multi-criteria evaluation techniques. This methodology was applied to a study area located in the eastern part of Lithuania. A GIS-based land suitability analysis was performed after identifying 16 factors concerning the geological and socio-economic environment, which were important for environmental protection, land use and spatial planning. The environmental and socio-economic factors were divided into eliminating and limiting criteria. Criteria maps based on the selected factors were compiled. Areas delineated by eliminating criteria were identified as unsuitable for development (according to national legislation). Limiting criteria were evaluated according to the suitability level, which were determined in this study considering the principles of sustainable development. The relative importance of each criterion was assessed utilising the Analytical Hierarchy Process (AHP). A land suitability index (LSI) was calculated and the final result of the land suitability analysis was summarized in three suitability maps (environmental, socio-economic and composite). Four suitability classes (unsuitable, least, moderately and most suitable) for the allocation of potential pollution sources in the study area were used, and the nine most suitable candidate sites were selected according to the proposed methodology.     

Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.