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111.
The heat of mixing for the binary solid solution diopside–Ca-Tschermak was investigated at T = 980 K by lead borate solution calorimetry. A new statistical technique was applied to overcome the problem of using experimental
data of various precisions. A two-parameter Margules model was fitted to the calorimetric data leading to W
CaTs–DiH = 31.3 ± 3.4 kJ mol−1 and W
H
Di–CaTs = 2.4 ± 4.3 kJ mol−1. The results are in good agreement with calorimetric data given in the literature. They agree also with enthalpy data that
were extracted from phase equilibrium experiments. With configurational entropy values taken from the literature, the volume
and the vibrational entropy, presented in Part I of this work, and the enthalpy data of this study, the activity–composition
relationships of the diopside–Ca-Tschermak binary were calculated. 相似文献
112.
Branka Trček 《Environmental Geology》2007,51(5):761-765
The role of an epikarst zone in the karst aquifer hydraulic behaviour was brought into focus in our studies referring to the
catchment area of the Hubelj spring (SW Slovenia). This study points out the significance of effects of the fast preferential
flow—epiflow, which is the main factor controlling solute/contaminant transport towards the aquifer saturated zone. The so-called
epikarstic hypothesis is verified on the basis of the most significant research results that are supported by the most important
findings from the literature. 相似文献
113.
Intraplate seismicity in the western Bohemian Massif (central Europe): A possible correlation with a paleoplate junction 总被引:5,自引:0,他引:5
Locations of the Eger Rift, Cheb Basin, Quaternary volcanoes, crustal earthquake swarms and exhalation centers of CO2 and 3He of mantle origin correlate with the tectonic fabric of the mantle lithosphere modelled from seismic anisotropy. We suggest that positions of the seismic and volcanic phenomena, as well as of the Cenozoic sedimentary basins, correlate with a “triple junction” of three mantle lithospheres distinguished by different orientations of their tectonic fabric consistent within each unit. The three mantle domains most probably belong to the originally separated microcontinents – the Saxothuringian, Teplá-Barrandian and Moldanubian – assembled during the Variscan orogeny. Cenozoic extension reactivated the junction and locally thinned the crust and mantle lithosphere. The rigid part of the crust, characterized by the presence of earthquake foci, decoupled near the junction from the mantle probably during the Variscan. The boundaries (transitions) of three mantle domains provided open pathways for Quaternary volcanism and the ascent of 3He- and CO2-rich fluids released from the asthenosphere. The deepest earthquakes, interpreted as an upper limit of the brittle–ductile transition in the crust, are shallower above the junction of the mantle blocks (at about 12 km) than above the more stable Saxothuringian mantle lithosphere (at about 20 km), probably due to a higher heat flow and presence of fluids. 相似文献
114.
This paper deals with transformation procedures for observed GPS data from the world geodetic system WGS-84 into the national geodetic grid datum S-UTCN(system of united trigonometric cadaster network) and Baa(the Baltic Sea after adjustment).Transformation from WGS-84 into SUTCN is performed most frequently by means of the 7-element Helmert transformation with three identical points.Geodetic network was adjusted by two ways. 相似文献
115.
Robustness analysis of geodetic horizontal networks 总被引:2,自引:1,他引:2
116.
Effects of the spherical terrain on gravity and the geoid 总被引:3,自引:0,他引:3
117.
Increased human activities since discovery of gold in northern California have changed the structure and function of many ecosystems. To reconstruct the changes in watershed environmental conditions, sediment cores were collected from three montane marshes in northern Sierra Nevada, CA. Pollen analysis was conducted, and water content, bulk density, ash, carbon, nitrogen, phosphorus, major cations, and lead concentrations of sediments were determined. Cores were dated by the 210Pb method. Pollen analyses showed changes in plant communities in this region due to severe logging in the late-1800s and moderate logging in the 1900s. The local changes were more clearly recorded in small marsh pollen profiles than regional changes. The water milfoil (Myriophyllum spicatum L.) introduction into Tahoe Basin was inferred from the pollen record and 210Pb dating. Road construction and maintenance activities were recorded in physical and chemical characteristics, such as increases in sodium, calcium, and magnesium concentrations. Pollen and physical and chemical records also documented the time line of the expansion of dry meadow, and the decrease of pine forest in one of the watersheds. This study showed that sediments in small marshes were especially useful to reconstruct local disturbance by human activities. 相似文献
118.
P. M. Nikolić S. Ðurić D. M. Todorović D. Vasiljević-Radović V. Blagojević P. Mihajlović J. Elazar K. T. Radulović A. I. Bojičić D. Urošević 《Physics and Chemistry of Minerals》2001,28(1):44-51
Electron transport properties of single crystal and polycrystalline natural mineral galena (PbS) samples from the Trep?a mine, Yugoslavia, were determined using the photoacoustic frequency transmission technique. Their thermal diffusivity (D T≈0.16 × 10?5 m2 s?1), the coefficient of diffusion (D between 0.15×10?2 0.16×10?2 m2 s?1) and lifetime of the excess carrier (τ≈35 μs and the front and rear recombination velocity (s g≈65.5 m s?1 and s b≈66.4 m s?1, respectively), were calculated by comparing the experimental results and the theoretical photoacoustic amplitude and phase signals. The lattice parameter obtained by X-ray work was a?=5.936?Å. The free carrier concentration of these single-crystal samples was measured using the Hall method (N?=?3×1018 cm?3). Measurements of the optical reflectivity of the same samples, as a function of wavelength, in the infrared and far infrared ranges, were performed. In the far infrared range a free electron plasma frequency was observed and numerically analyzed, using the least-squares fitting procedure. The values of optical parameters were calculated and the value of the free carrier concentration obtained by the Hall method was confirmed. 相似文献
119.
120.
J. M. Popović Dr. S. Ničković M. B. Gavrilov 《Meteorology and Atmospheric Physics》1996,58(1-4):41-49
Summary Finite-difference analysis of Rossby modes has been performed for two staggered hexagonal grids. The solutions are compared with those obtained in analytical case and for rectangular grids. The result for one of the selected hexagonal grids better fits to the analytical solution then the results for the other considered grids. The obtained results may contribute to better understanding of the appropriateness of hexagonal grids in atmospheric and oceanographic modeling and numerical computations.With 6 Figures 相似文献