Chemical aspects of iron oxide coagulation in water: Laboratory studies and implications for natural systems

Initial coagulation rates of colloidal hematite (-Fe₂O₃) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 10⁴ in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G _ads ⁰ >G _coul ⁰ ) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10^–7 to 10^–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10^–3 to 10^–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems.     

基于ArcObjects的GIS系统的二次开发--以济源市水土保持决策支持系统为例

COM技术是新一代组件式GIS发展的主流，文章阐述了COM，COMGIS的基本原理，介绍了AreOhjects的组成结构、开发的关键技术、开发方式，以及AreGIS Engine的功能，对使用两种组件式GIS进行二次开发进行了比较。最后给出了使用ArcObjects开发的一个实例——济源市水土保持决策支持系统，描述了系统的设计原则。系统的结构设计和系统的功能，并简要说明了系统的主要功能所使用的关键接口。     

An experimental study of anorthosite dissolution in lunar picritic magmas: Implications for crustal assimilation processes

Experiments characterizing the kinetics of anorthosite dissolution in lunar picritic magmas (very low-Ti, low-Ti, and high-Ti picritic glasses) were conducted at 0.6 GPa and 1250-1400 °C using the dissolution couple method. Reaction between the anorthosite and lunar picritic magmas at 1250-1300 °C produced a spinel + melt layer. Reaction between the anorthosite and an olivine-saturated low-Ti magma at 1250-1300 °C produced a crystal-free region between the spinel + melt layer and the olivine-saturated magma. The anorthosite dissolution experiments conducted at 1400 °C simply dissolved anorthosite and did not result in a crystal-bearing region. The rate of anorthosite dissolution strongly depends on temperature and composition of the reacting melt. Concentration profiles that develop during anorthosite dissolution are nonlinear and extend from the picritic glass compositions to anorthite. These profiles feature a large and continuous variation in melt density and viscosity from the anorthosite-melt interface to the initial picritic magmas. In both the low-Ti and high-Ti magmas the diffusive fluxes of TiO₂, Al₂O₃, and SiO₂ are strongly coupled to the concentration gradients of CaO and FeO. Anorthosite dissolution may play an important role in producing the chemical variability of the lunar picritic magmas, the origin of spinel in the lunar basalts and picritic glasses, and the petrogenesis of the high-Al basalts.     

下庄铀矿田337矿床成矿流体稀土元素示踪

337铀矿床位于下庄矿田东缘,区内发育近EW向、NNE向构造裂隙群及NW向辉绿岩和正长岩脉体,发育以碱性为主的多种围岩蚀变。区内矿床主要赋矿围岩的稀土元素特征属壳源型。矿石内金属矿物以沥青铀矿为主,矿石的LREE/HREE比值为3.25,Sm/Nd比值平均为0.307,Ce/Yb比值为7.127,这些数据都显示出成矿流体具有较深来源。矿石较围岩亏损稀土元素尤其是轻稀土元素,稀土元素分布模式平缓,与幔源辉绿岩特别是与正长岩的稀土元素分布模式相近,负铕异常比围岩更为强烈,反映成矿流体的来源具有幔源性。结合区域地质特征,可以认为337矿床成矿流体来源具有幔源性质。     

Zircon LA-ICP-MS U-Pb age, Ce^4＋/Ce^3＋ ratios and the geochemical features of the Machangqing complex associated with copper deposit

1IntroductionQuite a number of porphyry copper deposits havebeen found in the Cenozoic alkali-intrusions along theJinshajiang-Ailaoshan-Red River fault zone,whichconstitute the Cenozoic ore belt in China.The Cenozo-ic alkali-intrusive rocks are similar in…     

用BP神经网络预测土抗剪强度指标c、ψ

提出了应用BP神经网络来预测土抗剪强度指标c、ψ.结合工程实例,详细介绍了该方法的建模过程,结果表明预测结果和实测结果很接近,神经网络在土性参数方面应用前景很广阔.     

电子地图中多尺度地图数据显示的研究

将计算机三维模型简化中的LOD思想引入到电子地图的组织和显示中,提出了同一比例尺数字地图不同详细程度的分层显示方法和不同比例尺数字地图嵌套显示方法,实现了电子地图的多级缩放。     

非等截面桩超声波成孔质量检测

分析了非等截面超声波成孔质量检测的几个主要影响因素,给出了相应得改进措施。用工程实例说明超声波反射技术是一种保证非等截面桩成孔质量和成桩质量必不可少的检测方法。     

南海西南部曾母盆地早中新世以来沉降史分析

采用回剥法和局部均衡模式研究曾母盆地早中新世以来的沉降史，并探讨了该盆地构造演化特征。曾母盆地自早中新世以来经历了17．5-11．6Ma、11．6-5．5Ma、5．5-3．0Ma和3．0-0Ma的4次快速沉降作用，其构造演化受控于曾母地块与南沙地块及婆罗洲地块的碰撞和盆地两侧的万安-卢帕尔断裂与廷贾走滑断裂的综合作用，可划分为南北双向挤压（晚始新世-早中新世）、走滑改造（中中新世-晚中新世）和区域沉降（上新世-第四纪）3个演化阶段。     

渭北东部奥陶系岩溶地下水环境同位素特征分析

本文通过对渭北东部岩溶地下水环境同位素组成特征的研究,分析了大气降水、地表水、地下水三者之间的转化关系,并对研究区岩溶地下水的形成进行了初步探讨,认为大气降水是研究区岩溶地下水的补给源,地表水与地下水之间存在水力联系,地表水对地下水的补给占补给水源的74.3%.西部岩溶裸露区为岩溶水的直接补给区,其周边浅埋区为岩溶水的间接补给区,东南部的岩溶中-深埋区为岩溶水的径流排泄区.