Sorption Characteristics of Rare Earth Element Eu^3＋ onto Silica-Water Interfaces Studied by Fluorescence Spectroscopy

The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献   

Late Quaternary downcutting rates of the Qianyou River from U/Th speleothem dates, Qinling mountains, China

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1IntroductionArc-shaped bays are quite common on exposed sediment coast in South China, where the crenulate-bay beaches occur with the presence of two consecutive headlands and a predominant wave approach oblique to the alignment of the upcoast and downcoast headlands (Yasso, 1965). Oblique persistent swell striking a shoreline transports sediment alongshore and sculptures a coast into arc-shaped beaches. The shoreline of beach appearance mainly consists of straight segment and shadow segment…     

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