A feather hydrogen isoscape for Mexico

Developing useful biological isoscapes for areas of the world is a priority. This is the case for Mexico that hosts a large percentage of North America's Neotropical migrant birds. Here we investigated the use of House Sparrow (Passer domesticus) feathers to create a spatially explicit feather deuterium isoscape for that country using samples (n = 461) that were collected across Mexico. Considerable and useful spatial hydrogen isotopic structure was observed, suggesting that isotopes may be a potential forensic tool for evaluating origins of Mexican derived fauna and flora. The most positive feather δD values occurred in the northeast and most negative in the south-central part of the country, roughly matching δD patterns observed in groundwater. A weak negative isotopic relationship was found with altitude in both the Pacific and Atlantic drainage systems. The most parsimonious model describing isotopic spatial variation in feathers between 300 and 3000 m a.s.l. included groundwater δD (δD_gw; precipitation proxy), sex, amount of precipitation, and the coefficient of variation in amount of precipitation. Overall, δD_gw was a poor predictor of sparrow δD_f values for all of Mexico. However, this relationship was considerably strengthened when we considered sex separately, removed the Baja peninsula from our sample, and considered the Atlantic and Pacific drainage basins separately. The strongest relationship between δD_gw and δD_f was found for female sparrows in the Atlantic drainage basin (r² = 0.464). We recommend that researchers interested in inferring origins of migratory birds and other animals in Mexico create species specific isotopic basemaps that may be guided by the isotopic patterns we have observed for House Sparrows and groundwater.     

Mathematical models for petroleum-forming processes: carbon isotope fractionation

A mathematical model has been developed in which carbon isotope fractionation during thermal cracking of n-paraffins can be simulated. The model has been calibrated based on data from laboratory cracking experiments carried out on n-octadecane. Relative rate constants for cleavage of C¹²-C¹², C¹²-C¹³ and C¹³-C¹³ bonds agree with the experimental values obtained by other workers.Application of this model to the process of petroleum formation gives good agreement with some existing experimental data, but suggests that a review of our understanding of isotope fractionation during thermal cracking may be necessary. The relative importance of the degree to which the organic material has been cracked and of the type of the organic material in influencing δC¹³ values is discussed.The present model predicts that cracking of n-paraffin distributions having initial odd or even carbon number predominances can induce isotopic inhomogeneity among the homologs of the resulting distribution. The model exhibits some deficiencies in explaining or predicting the δC¹³ values of ethane and propane in relation to methane in gases and of oils and associated methane. Explanations for these discrepancies may lie in the simplicity of our mathematical model, in our assumption of initial isotopic homogeneity within molecules and in our use of only n-paraffins as the source molecules for the cracking reactions.     

Dynamics of epiphytic photoautotrophs and heterotrophs inZostera marina (eelgrass) microcosms: Responses to nutrient enrichment and grazing

The combined effects of nutrient enrichment and grazing by isopods and amphipods on abundances of seagrass epiphytes were tested inZostera marina L. (eelgrass) microcosms. Using epifluorescence microscopy, densities of epiphytic diatoms, cyanobacteria, heterotrophic flagellates, and heterotrophic bacteria were enumerated after 1 mo and 2 mo of treatment. In general, numbers of diatoms decreased, in the presence of grazers and showed little response to nutrient enrichment, whereas numbers of cyanobacteria increased with nutrient enrichment and showed little response to grazing. Thus, macrofaunal grazing maintained a photoautotrophic community domainated by cyanobacteria, particularly under nutrient enriched conditions. Following 2 mo of treatment, dense macroalgal growth under nutrient-enriched conditins with grazers absent appeared to limit populations of both epiphytic autotrophs. Patterns of abundance of heterotrophic bacteria suggested that the original bacteria population was nutrient limited. Bacteria populations may have been limited by organic carbon supplies at the end of the experiment. Abundances of heterotrophic flagellates and bacteria were strongly correlated on both sampling dates. Results suggest that heterotrophic flagellates might serve as a link between heterotrophic bacterial production and higher trophic levels in seagrass epiphyte food webs.     

Effects of intraborehole flow on groundwater age distribution

Environmental tracers are used to estimate groundwater ages and travel times, but the strongly heterogeneous nature of many subsurface environments can cause mixing between waters of highly disparate ages, adding additional complexity to the age-estimation process. Mixing may be exacerbated by the presence of wells because long open intervals or long screens with openings at multiple depths can transport water and solutes rapidly over a large vertical distance. The effect of intraborehole flow on groundwater age was examined numerically using direct age transport simulation coupled with the Multi-Node Well Package of MODFLOW. Ages in a homogeneous, anisotropic aquifer reached a predevelopment steady state possessing strong depth dependence. A nonpumping multi-node well was then introduced in one of three locations within the system. In all three cases, vertical transport along the well resulted in substantial changes in age distributions within the system. After a pumping well was added near the nonpumping multi-node well, ages were further perturbed by a flow reversal in the nonpumping multi-node well. Results indicated that intraborehole flow can substantially alter groundwater ages, but the effects are highly dependent on local or regional flow conditions and may change with time.     

On the role of evidence in physical and human geography

While physical geographers are united in a commitment to the scientific method with its emphasis on quantitative evidence, human geographers face a dilemma in deciding whether to adopt a scientific or humanistic approach in their research. The scientific approach offers a more secure, objective knowledge, but limits the scholar to a relatively narrow range of topics. The humanistic approach allows the scholar to explore a wide range of human experiences, but it lacks rigorous procedures of objective verification. The difficulty of the application of theoretical ideas to human societies can, to some extent, be avoided by adopting an historical approach, with an emphasis on the empirical investigation of human activity as a reflection of ideas. As long as human geographers have a commitment to basing their interpretations of geographical phenomena on objective evidence the possibility of a profitable co-operation exists among proponents of different philosophical approaches. A unified human geography embracing scholars of diverse views depends for its success on the identification of geographical problems that transcend philosophical and theoretical points of view.     

Mathematical models for petroleum-forming processes: n-paraffins and isoprenoid hydrocarbons

Mathematical models have been developed which simulate both random and nonrandom thermal cracking of branched and straight-chain hydrocarbons. Application of these models to n-paraffins suggests that thermal cracking alone cannot be the dominant mechanism in formation of the n-paraffin distributions present in crude oils. Application to isoprenoid hydrocarbons indicates that nonrandom cracking could be important in producing the isoprenoid distributions found in oils.Results of the mathematical modeling show that methane formation should, as predicted from energy considerations, be kinetically disfavored. It therefore is likely that substantial quantities of methane are produced from saturated hydrocarbons only under thermal conditions more severe than those under which oil is produced.The mathematical models employed are adaptable for other geochemical applications, such as isotope fractionation.     

Organic versus inorganic trace metal complexes in sulfidic marine waters—some speculative calculations based on available stability constants

A theoretical model has been developed in order to test the hypothesis that simple organic acids are the chief agents of trace metal solubility in H₂S-rich marine waters. The model utilizes stability constant given by Sillen and Martell (1964, 1971) and assumes that the free cation activity of each metal is controlled by simple solubility products. Typical values of pH, pS and Eh are employed in the calculations. The results indicate that free amino acids and hydrocarboxylic acids probably are not effective but that bisulfide and polysulfide complexes may be the chief agents of trace metal solubility. To the extent that it is present, the effect of dissolved organic matter on trace metal solubility probably resides in highly polymerized substances (e.g. humic acids).     

West Nile virus in American crows (Corvus brachyrhynchos) in Canada: projecting the influence of climate change

The present study examined the influence of climate change on the spread of West Nile virus (WNV) in Canada among American crows (Corvus brachyrhynchos) by first identifying the significant climatic and environmental determinants of positive WNV cases in American crow specimens from 2009 to 2013. Using this information, we projected climate change scenarios on the potential spread of WNV in American crow species in Canada for three time periods: 2015–2039, 2040–2069, and 2070–2099. Using bird specimen, meteorological and land-use data, the statistical association between positive WNV cases in American crows and the environment was assessed by means of a general linear mixed model. Statistical results revealed that temperature and precipitation were significantly related to positive cases of WNV in American crows. Thus, climate change projections of summer mean temperature averages were projected for the three time periods. Climate change scenarios were created and imported into Quantum Geographic Information System (QGIS) and an algorithm was applied using the raster calculator to spatially delineate current and future areas of risk. Spatial analyses revealed that increased warming in the near future may increase the latitudinal extension of WNV in American crows in Canada.     

Replacing coal with wood: sustainable, eco-neutral, conservation harvest of natural tree-fall in old-growth forests

Kleidon (2009) concludes that warm climates impose important constraints on the evolution of large brains relative to body size, confirming our previous hypothesis (Schwartzman and Middendorf 2000). Here we update the case for our hypothesis and present a first approximation estimate of the cooling required for hominin brain size increase using a simple model of heat loss. We conclude that Pleistocene glacial episodes were likely sufficient to serve as prime releasers for emergence of Homo habilis and Homo erectus. In addition, we propose that atmospheric oxygen levels may been an analogous constraint on insect encephalization.