Rječina River sediments (Croatia): from captured spring to polluted prodelta

Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na, B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles.     

Arsenic Speciation in Lichens and in Coarse and Fine Airborne Particulate Matter by HPLC–UV–HG–AFS

A three-step sequential extraction procedure with Milli-Q, CaCl₂ and H₃PO₄ was applied for extraction of arsenic species in lichen transplants and airborne particulate matter (fine and coarse fractions). The samples used in this work were collected in 1994–1995 near coal-fired power plants. Both transplant lichens and airborne particulate matter were submitted to the same environment simultaneously. Arsenic species identification and quantification was performed by HPLC–UV–HG–AFS. Inorganic forms of arsenic (arsenite and arsenate) were present in significant amounts in most of the samples. Only in lichens also organic forms of arsenic (monomethyl arsonic acid and dimethyl arsinic acid) were identified which may indicate biotransformation of inorganic arsenic.     

A note on the performance of the multiply-upstream semi-Lagrangian advection schemes for one-dimensional nonlinear momentum conservation equation

Summary Two-time-level multiply-upstream semi-Lagrangian schemes were examined in the case of the self-advecting, one-dimensional nonlinear momentum conservation equation. The shock formation process was analyzed. It is pointed out that the shocks cannot be created in the truncated systems satisfying the Pudykiewicz, Benoit and Staniforth criterion.The numerical integrations were restricted to 12 h. It was shown that, at least in the sub-CFL range, increased complexity of the scheme can compensate reduced horizontal resolution. A considerable sensitivity of the schemes with respect to the time step was detected. In the super-CFL mode, several windows on various time scales were found within which the Pudykiewicz, Benoit and Staniforth criterion was satisfied. The time step of 1.44 times the maximum time step allowed by the CFL criterion was used in the semi-Lagrangian runs.The super-CFL, semi-Lagrangian solutions were diverging progressively from the sub-CFL ones as the forecasts advanced. This was also reflected in the energy spectra.Unacceptably large energy losses were encountered in the super-CFL, semi-Lagrangian runs. Most of these losses could be explained by the reduced mean wind speed, i.e., the amplitude of the zero wavenumber wave. At the same time, the energy content in the shorter waves increased. In a more complex model, such a situation would resemble a loss of zonal, and an increase of transient eddy kinetic energy.A trajectory error measure was defined as the maximum absolute value of the distance between the actual arriving point of the particle originating at the estimated departure point, and the grid point assumed to be the arrival point in the semi-Lagrangian procedure. In contrast to the sub-CFL regime, this measure could reach a considerable fraction of the grid distance in the computations with the super-CFL time steps.In the physical system considered, the trajectories are determined only by the velocities at the departure points. With the semi-Lagrangian schemes the distances traveled by the particles are estimated on the basis of the velocities at the points downstream with respect to the departure points. Thus, unless the solution is smooth (in space and time) on the scales of the extrapolation distances/times, the upstream extrapolation does not promise the convergence of the solution.With 16 Figures     

Gridded Croatian climatology for 1961–1990

In climatology, one of the most important pieces of information about the climate of a place or a region is information about the Climatological Normals (CLINO)—the average values of meteorological elements for a 30-year period. This kind of information usually comes in tables and is available for different observation sites from national meteorological services or from World Meteorological Organisation publications. The key issue, then, becomes how to interpolate these values over the entire area of interest to get reliable and accurate estimates (maps) of climatic elements. Here, the regression kriging framework has been applied for mapping of 20 climatological parameters for the 1961–1990 period for the 56,594 km² of Croatian territory, with a resolution of 1 km. In total, 152 main and climatological and 567 precipitation-measuring stations have been used in the analysis. Extensive pre-processing of metadata on station co-ordinates has been done, as well as completion of missing monthly averages. The final results are 20 climatological maps available in high resolution together with error maps and accuracy assessment measures.     

Discontinuous Nature of the Lower Part of the South American Wadati-Benioff Zone in The Arica Elbow Region

The Arica Elbow region represents that part of Andean South America where the azimuth of the strike of the Peru-Chile trench changes from 150° to 190°. The area under study is roughly bounded by latitudes 17 °S and 23 °S, The shape of the Wadati-Benioff zone was studied in terms of the distribution of ISC hypocentres dated between 1964 and 1993. A system of 22 vertical cross-sections, perpendicular to the trench axis, and a map of epicentres was used to derive the detailed shape of the Wadati-Benioff zone of the presently descending slab. The distribution of earthquake foci indicates a fingerlike shape of the lower part of the Wadati-Benioff zone beneath the aseismic gap. The slab length shows small changes around 350 km in the northern sections, pronounced length oscillations between 350 and 750 km in the neighbouring central sections and a constant value of 650 km in the southern sections. The dip and thickness of the Wadati-Benioff zone are practically constant in all sections. Fault plane solutions, separated spatially into three zones, were used to estimate the state of stress in the slab.     

Lysosomal membrane stability and metallothioneins in digestive gland of Mussels (Mytilus galloprovincialis Lam.) as biomarkers in a field study

The lysosomal membrane destabilization and the metallothionein content in the digestive gland cells of mussels (Mytilus galloprovincialis Lam.), collected along the east coast of the North Adriatic (Istrian and Kvarnerine coast, Croatia), were examined over a period of four years (1996–1999). The lysosomal membrane stability, as a biomarker of general stress, showed that the membrane labilization period in mussels from polluted, urban- and industrial-related areas was significantly decreased (p<0.05) when compared to mussels from control, clean sea water sites. In the harbour of Rijeka, the most contaminated site, the lysosomal membrane stability was reduced by more than 70% compared to the control. This method also proved to be a useful biomarker for detection of additional stress caused by short-term hypoxia that occurred once during this study inside the polluted and periodically quite eutrophic Pula Harbour. The concentration of metallothioneins in the mussel digestive gland, as a specific biomarker of exposure to heavy metals, did not reveal significant differences (p<0.05) between sites covered by this study.