A Simple Model for the Vertical Transport of Reactive Species in the Convective Atmospheric Boundary Layer

We have developed a simple, steady-state, one-dimensional second-order closure model to obtain continuous profiles of turbulent fluxes and mean concentrations of non-conserved scalars in a convective boundary layer without shear. As a basic tool we first set up a model for conserved species with standard parameterizations. This leads to formulations for profiles of the turbulent diffusivity and the ratio of temperature-scalar covariance to the flux of the passive scalar. The model is then extended to solving, in terms of profiles of mean concentrations and fluxes, the NO _x –O₃ triad problem. The chemical reactions involve one first-order reaction, the destruction of NO₂ with decay time τ, and one second-order reaction, the destruction of NO and O₃ with the reaction constant k. Since the fluxes of the sum concentrations of NO _x = NO + NO₂ and O₃ + NO₂ turn out to be constant throughout the boundary layer, the problem reduces to solving two differential equations for the concentration and the flux of NO₂. The boundary conditions are the three surface fluxes and the fluxes at the top of the boundary layer, the last obtained from the entrainment velocity, and the concentration differences between the free troposphere and the top of the boundary layer. The equations are solved in a dimensionless form by using 1/(kτ) as the concentration unit, the depth h of the boundary layer as the length unit, the convective velocity scale w _* as the velocity unit, and the surface temperature flux divided by w _* as the temperature unit. Special care has been devoted to the inclusion of the scalar–scalar covariance between the concentrations of O₃ and NO. Sample calculations show that the fluxes of the reactive species deviate significantly from those of non-reactive species. Further, the diffusivities, defined by minus the flux divided by the concentration gradient may become negative for reactive species in contrast to those of non-reactive species, which in the present model are never negative.     

Sulfur dioxide in the tropical marine boundary layer: dry deposition and heterogeneous oxidation observed during the Pacific Atmospheric Sulfur Experiment

Research flights with the National Center for Atmospheric Research (NCAR) C-130 airborne laboratory were conducted over the equatorial ocean during the Pacific Atmospheric Sulfur Experiment (PASE). The focused, repetitive flight plans provided a unique opportunity to explore the principal pathways of sulfur processing in remote marine environments in close detail. Fast airborne measurements of SO₂ using the Drexel University APIMS (Atmospheric Pressure Ionization Mass Spectrometer) instrument further provided unprecedented insight into the complete budget of this important sulfur gas. In general, turbulent mixing in the marine boundary layer (MBL) continuously depletes SO₂ due to the shallow convection of the tropical trade wind regime by venting the gas into the buffer layer (BuL) above. However, on nearly one-third of the flights a net import of SO₂ into the MBL from the BuL was observed. Concurrent measurements of the DMS budget allowed for a heterogeneous S(IV) oxidation rate to be inferred from the SO₂ budget residual. The average heterogeneous loss rate was found to be 0.05 h⁻¹, which taken in conjunction with the observed aerosol surface area distributions and O₃ levels indicates that the supermicron aerosols maintain a near neutral pH. The average dry deposition velocity of SO₂ was found to be 0.4 cm s⁻¹, about 30% lower than predicted by standard parameterizations. The yield of SO₂ from DMS oxidation was found to be near unity. The mission averages indicate that approximately 57% of the SO₂ in the MBL is lost to aerosols, 27% is subject to dry deposition, 7% is mixed into the BuL, and 10% is oxidized by OH.     

Dynamik des Phytoplanktons der Oberwarnow 1984–1986

The development of the phytoplankton was observed from 1984 to 1986 in the Warnow-River (GDR, Mecklenburg). The dominant algae throughout the year were the Bacillariophyceae with their maximum in spring (1984: 36.1 mm³/1, 1986: 32.3 mm³/1) or in autumn (1985: 48.3 mm³/1). There is not any limitation of phytoplankton by inorganic nutritation (N, P) throughout the year. The phytoplankton production was most influenced by the turbulance of water. Classification of banked-up rivers with the help of the plankton-quotients of Thunmark and Nygaard is impossible.     

The stably stratified boundary layer over the great plains

Airplane measurements of the stably stratified boundary layer obtained during the Severe Environmental Storms and Mesoscale Experiment (SESAME) over rolling terrain in south-central Oklahoma indicate that considerable horizontal variability exists in the flow on scales of several kilometers. Much of this wave-like structure appears to be tied to the terrain. The criteria for existence of stationary gravity waves indicate that these waves can exist under the observed conditions. The spectrum of terrain variations also supports the existence of these waves. Observed spectra of the vertical velocity have two peaks: one at wavelengths of several kilometers, which is due to waves and the other at wavelengths of about 100 m, which is due to turbulence. The variance at several kilometers wavelength increases somewhat with height at least up to about 800 m, but the variance contributed by turbulence decreases rapidly with height.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Shallow Drainage Flows

Two-dimensional sonic anemometers and slowresponse thermistors were deployedacross a shallow gully during CASES99. Weak gully flow of a few tenths of m s^-1 anda depth of a few metres develops in the earlyevening on most nights with clear skies.Flow down the gully developed sometimes evenwhen the opposing ambient wind exceeded10 m s^-1 at the top of the60–m tower. Cold air drainage fromlarger-scale slopes flows over the top ofthe colder gully flow. The gully flowand other drainage flows are generally eliminated in the middle of the night in conjunctionwith flow acceleration abovethe surface inversion layer and downwardmixing of warmer air and highermomentum. As the flow decelerates later inthe night, the gully flow may re-form.The thin drainage flows decouple standard observational levels of3–10 m from the surface.Under such common conditions, eddy correlationflux measurements cannot be used toestimate surface fluxes nor even detect thethin gully and drainage flows. The gentlegully system in this field program is typical ofmuch of the Earths land surface.