Imaging of long‐range reverberation from ocean basin topography

A technique is currently under development a the Naval Research Laboratory for imaging of backscatterec acoustic returns from ocean basin topography. The method is straightforward. An explosive sound source is detonated near the center of an ocean basin and the round‐trip travel time from source to reflectors and return is measured. Distance to back‐scattering topography is assumed to be proportional to round‐trip time, with a proportionality constant equal to half the sound speed. A multielement receiving array is used to determine the azimuthal directions to topographic features. Reverberation data are output to an imaging system to study the spatial distribution of sea bottom reverberation. The images are in the form of two‐dimensional maps of backscattered acoustic energy. Typical maps are larger than 2,000 km x 2,000 km (or area coverage greater than 4 x 10⁶ km²). After correction of maps from individual shot detonations for range‐dependent propagation losses, we average ("integrate") maps together on a pixel by pixel basis for a clear picture of major basin reverberators.     

Astrometric parameters of visual double stars derived from simulated hipparcos measurements

Summary In the course of the reduction ofHipparcos data the astrometric parameter determination of visual binaries is reduced to the parameter determination of single stars. This approach assumes that the off-set of the binary components with respect to the conventional light point directly measured by the Hipparcos telescope are known on the individual scanning circles. The computer algorithms are outlined, preliminary results based on simulated measurements are discussed. Presented by H.-H. Bernstein.     

An assessment of hydrothermal alteration in the Santiaguito lava dome complex, Guatemala: implications for dome collapse hazards

A combination of field mapping, geochemistry, and remote sensing methods has been employed to determine the extent of hydrothermal alteration and assess the potential for failure at the Santiaguito lava dome complex, Guatemala. The 90-year-old complex of four lava domes has only experienced relatively small and infrequent dome collapses in the past, which were associated with lava extrusion. However, existing evidence of an active hydrothermal system coupled with intense seasonal precipitation also presents ideal conditions for instability related to weakened clay-rich edifice rocks. Mapping of the Santiaguito dome complex identified structural features related to dome growth dynamics, potential areas of weakness related to erosion, and locations of fumarole fields. X-ray diffraction and backscattered electron images taken with scanning electron microscopy of dacite and ash samples collected from around fumaroles revealed only minor clay films, and little evidence of alteration. Mineral mapping using ASTER and Hyperion satellite images, however, suggest low-temperature (<150 °C) silicic alteration on erosional surfaces of the domes, but not the type of pervasive acid-sulfate alteration implicated in collapses of other altered edifices. To evaluate the possibility of internal alteration, we re-examined existing aqueous geochemical data from dome-fed hot springs. The data indicate significant water–rock interaction, but the Na–Mg–K geoindicator suggests only a short water residence time, and δ¹⁸O/δD ratios show only minor shifts from the meteoric water line with little precipitation of secondary (alteration) minerals. Based on available data, hydrothermal alteration on the dome complex appears to be restricted to surficial deposits of hydrous silica, but the study has highlighted, importantly, that the 1902 eruption crater headwall of Santa María does show more advanced argillic alteration. We also cannot rule out the possibility of advanced alteration within the dome complex interior that is not accessible to the methods used here. It may therefore be prudent to employ geophysical methods to make further assessments in the future.     

The infrared spectra of nitriles and related compounds frozen in Ar and H2O

We present the 2320-2050 cm-1 (4.31-4.88 micrometers) infrared spectra of 16 solid-state nitriles, isonitriles, and related compounds in order to facilitate the assignment of absorption features in a spectral region now becoming accessible to astronomers for the first time through the Infrared Space Observatory (ISO). This frequency range spans the positions of the strong C triple bond N stretching vibration of these compounds and is inaccessible from the ground due to absorption by CO2 in the terrestrial atmosphere. Band positions, profiles, and intrinsic strengths (A values) were measured for compounds frozen in Ar and H2O matrices at 12 K. The molecular species examined included acetonitrile, benzonitrile (phenylcyanide), 9-anthracenecarbonitrile, dimethylcyanamide, isopropylnitrile (isobutyronitrile), methylacrylonitrile, crotononitrile, acrylonitrile (vinyl cyanide), 3-aminocrotononitrile, pyruvonitrile, dicyandiamide, cyanamide, n-butylisocyanide, methylisocyanoacetate, diisopropylcarbodiimide, and hydrogen cyanide. The C triple bond N stretching bands of the majority of nitriles fall in the 2300-2200 cm-1 (4.35-4.55 micrometers) range and have similar positions in both Ar and H2O matrices, although the bands are generally considerably broader in the H2O matrices. In contrast, the isonitriles and a few exceptional nitriles and related species produce bands at lower frequencies spanning the 2200-2080 cm-1 (4.55-4.81 micrometers) range. These features also have similar positions in both Ar and H2O matrices, and the bands are broader in the H2O matrices. Three of the compounds (pyruvonitrile, dicyandiamide, and cyanamide) show unusually large shifts of their C triple bond N stretching frequencies when changing from Ar to H2O matrices. We attribute these shifts to the formation of H2O:nitrile complexes with these compounds. The implications of these results for the identification of the 2165 cm-1 (4.62 micrometers) "XCN" interstellar feature and the 4550 cm-1 (2.2 micrometers) feature of various objects in the solar system are discussed.     

Hydrological change in the central interior of British Columbia,Canada: diatom and pollen evidence of millennial-to-centennial scale change over the Holocene

Diatom-based inferences of post-glacial hydrological change from a sedimentary record from Felker Lake, British Columbia, show millennial-scale pacing of climate over the past approximately 11670 calendar years with change at ca. 8140 cal. year BP, ca. 6840 cal. year BP, ca. 5700 cal. year BP, and ca. 2230 cal. year BP. Early postglacial diatom assemblages are dominated by fragilaroid taxa, suggesting that cool and moist climate conditions and relatively high lake levels prevailed at this time. Early Holocene warming near ca. 8140 cal. year BP promoted Cyclotella bodanica var. lemanica, a fall bloomer competitive in limnological conditions associated with warmer water and stratified conditions. Short-lived peaks of Stephanodiscus parvus/minutulus between ca. 6340 cal. year BP and ca. 5860 cal. year BP indicate periodic increases in nutrient availability and prolonged mixing likely associated with long cool and moist spring seasons. The diatom-inferred depth of Felker Lake increased during the mid-Holocene to reach a record high-stand at ca. 5860 cal. year BP. Large changes in hydrological variability and terrestrial vegetation at Felker Lake occurred after ca. 2230 cal. year BP when high-amplitude centennial-scale fluctuations in diatom-inferred lake depth and salinity are observed. Change is first documented in terrestrial vegetation at this time by a shift from open Pinus parklands to a landscape that periodically supported populations of Cupressaceae. Three record low-stand high-salinity events are reconstructed between ca. 1910 cal. year BP and ca. 1800 cal. year BP, ca. 1030 cal. year BP and ca. 690 cal. year BP, and ca. 250 cal. year BP and ca. 140 cal. year BP. The low lake-level episode of ca. 1030 cal. year BP–ca. 690 cal. year BP is coeval with the Medieval Warm Period (ca. 1000 cal. year BP–ca. 600 cal. year BP), a period of intense drought in western North America. Post-glacial hydrological change at Felker Lake is coherent with regional, hemispherical, and global paleoclimate events, suggesting that millennial-and centennial-scale shifts in water availability are a persistent feature of the climate of western North America.