试解页岩气储层随钻评价关键参数

基于致密砂岩、碳酸盐岩油气层录井随钻评价方法,以及最新页岩气录井研究成果,给出了页岩气储层随钻评价关键参数的测量方法与评价标准、解释交会图,并结合在中上扬子地台川东褶皱带石柱复向斜钻探成功的J111井实钻资料进行了分析和探讨,为大家进行页岩气、致密砂岩气、致密碳酸盐岩气解释研究提供了有益的参考。     

Highly Oxidized Magma and Fluid Evolution of Miocene Qulong Giant Porphyry Cu‐Mo Deposit,Southern Tibet,China

The Miocene Qulong porphyry Cu‐Mo deposit, which is located at the Gangdese orogenic belt of Southern Tibet, is the largest porphyry‐type deposit in China, with confirmed Cu ～10 Mt and Mo ～0.5 Mt. It is spatially and temporally associated with multiphase granitic intrusions, which is accompanied by large‐scale hydrothermal alteration and mineralization zones, including abundant hydrothermal anhydrite. In addition to hydrothermal anhydrite, magmatic anhydrite is present as inclusions in plagioclase, interstitial minerals between plagioclase and quartz, and phenocrysts in unaltered granodiorite porphyry, usually in association with clusters of sulfur‐rich apatite in the Qulong deposit. These observations indicate that the Qulong magma‐hydrothermal system was highly oxidized and sulfur‐rich. Three main types of fluid inclusions are observed in the quartz phenocrysts and veins in the porphyry: (i) liquid‐rich; (ii) polyphase high‐salinity; and (iii) vapor‐rich inclusions. Homogenization temperatures and salinities of all type inclusions decrease from the quartz phenocrysts in the porphyry to hydrothermal veins (A, B, D veins). Microthermometric study suggests copper‐bearing sulfides precipitated at about 320–400°C in A and B veins. Fluid boiling is assumed for the early stage of mineralization, and these fluids may have been trapped at about 35–60 Mpa at 460–510°C and 28–42 Mpa at 400–450°C, corresponding to trapping depths of 1.4–2.4 km and 1.1–1.7 km, respectively.     

Fluid Inclusions and Hydrogen,Oxygen, Sulfur Isotopes of Nuri Cu‐W‐Mo Deposit in the Southern Gangdese,Tibet

The Nuri Cu‐W‐Mo deposit is located in the southern subzone of the Cenozoic Gangdese Cu‐Mo metallogenic belt. The intrusive rocks exposed in the Nuri ore district consist of quartz diorite, granodiorite, monzogranite, granite porphyry, quartz diorite porphyrite and granodiorite porphyry, all of which intrude in the Cretaceous strata of the Bima Group. Owing to the intense metasomatism and hydrothermal alteration, carbonate rocks of the Bima Group form stratiform skarn and hornfels. The mineralization at the Nuri deposit is dominated by skarn, quartz vein and porphyry type. Ore minerals are chalcopyrite, pyrite, molybdenite, scheelite, bornite and tetrahedrite, etc. The oxidized orebodies contain malachite and covellite on the surface. The mineralization of the Nuri deposit is divided into skarn stage, retrograde stage, oxide stage, quartz‐polymetallic sulfide stage and quartz‐carbonate stage. Detailed petrographic observation on the fluid inclusions in garnet, scheelite and quartz from the different stages shows that there are four types of primary fluid inclusions: two‐phase aqueous inclusions, daughter mineral‐bearing multiphase inclusions, CO₂‐rich inclusions and single‐phase inclusions. The homogenization temperature of the fluid inclusions are 280°C–386°C (skarn stage), 200°C–340°C (oxide stage), 140°C–375°C (quartz‐polymetallic sulfide stage) and 160°C–280°C (quartz‐carbonate stage), showing a temperature decreasing trend from the skarn stage to the quartz‐carbonate stage. The salinity of the corresponding stages are 2.9%–49.7 wt% (NaCl) equiv., 2.1%–7.2 wt% (NaCl) equiv._, 2.6%–55.8 wt% (NaCl) equiv. and 1.2%–15.3 wt% (NaCl) equiv., respectively. The analyses of CO₂‐rich inclusions suggest that the ore‐forming pressures are 22.1 M Pa–50.4 M Pa, corresponding to the depth of 0.9 km–2.2 km. The Laser Raman spectrum of the inclusions shows the fluid compositions are dominated in H₂O, with some CO₂ and very little CH₄, N₂, etc. δD values of garnet are between ?114.4‰ and ?108.7‰ and δ¹⁸O_H2O between 5.9‰ and 6.7‰; δD of scheelite range from ?103.2‰ to ?101.29‰ and δ¹⁸O_H2O values between 2.17‰ and 4.09‰; δD of quartz between ?110.2‰ and ?92.5‰ and δ¹⁸O_H2O between ?3.5‰ and 4.3‰. The results indicate that the fluid came from a deep magmatic hydrothermal system, and the proportion of meteoric water increased during the migration of original fluid. The δ³⁴S values of sulfides, concentrated in a rage between ?0.32‰ to 2.5‰, show that the sulfur has a homogeneous source with characteristics of magmatic sulfur. The characters of fluid inclusions, combined with hydrogen‐oxygen and sulfur isotopes data, show that the ore‐forming fluids of the Nuri deposit formed by a relatively high temperature, high salinity fluid originated from magma, which mixed with low temperature, low salinity meteoric water during the evolution. The fluid flow through wall carbonate rocks resulted in the formation of layered skarn and generated CO₂ or other gases. During the reaction, the ore‐forming fluid boiled and produced fractures when the pressure exceeded the overburden pressure. Themeteoric water mixed with the ore‐forming fluid along the fractures. The boiling changed the pressure and temperature, oxygen fugacity, physical and chemical conditions of the whole mineralization system. The escape of CO₂ from the fluid by boiling resulted in scheelite precipitation. The fluid mixing and boiling reduced the solubility of metal sulfides and led the precipitation of chalcopyrite, molybdenite, pyrite and other sulfide.     

中国南方震旦纪大地构造单元划分与地层分区

本文以板块理论为指导，重点探讨地层分区与大地构造单元划分及沉积相展布的关系，提出以构造为主导，构造－地层－沉积相三位一体的地层分区原则和方法。中国南方震旦纪基底构造格架是两隆一坳，即扬子板块、华夏板块及其间的华南残留盆地，晋宁运动使扬子板块与华夏板块拼接在一起，进入相对稳定的发展阶段。震旦纪沉积作用与相带展布与上述古构造格局是一致的。根据上述区划原则和古构造、沉积相的研究结论，将中国南方震旦系划分为２个Ⅰ级地层区，６个Ⅱ级地层分区和１２个Ⅲ级地层小区。     

川东及邻区上二叠统生物礁的白云岩化

白云岩化是川东及邻区上二叠统礁体的重要成岩事件。根据矿物岩石学、X光衍射、流体包裹体、碳氧稳定同位素、微量元素及阴极发光等项目的研究,笔者认为,礁体白云岩主要是埋藏交代成因,礁顶有少量微-粉晶白云岩为潮坪成因。本文着重讨论礁体围岩为生屑灰岩的埋藏压实流体白云岩化模式,简述礁控白云岩储集特征及其成因。在此研究基础上,提出了一个白云石结构成因分类方案。     

北京密云麻粒岩相区变质作用演化及PTt轨迹的研究

北京密云麻粒岩相区在早前寒武纪时期主要经历了两期变质作用。每期变质作用又可划分为三个连续的变质阶段,峰期阶段的Ｐ－Ｔ条件均达到了麻粒岩相．第一期变质作用约结束于２５００Ｍａ,具有与造山带相似的顺时针ＰＴｔ轨迹,峰期阶段Ｔ为８００～９００℃,Ｐ＝０．９８～１．０２ＧＰａ,这种轨迹主要与早期平卧褶皱和推覆构造使地壳大幅度增厚有密切关系。第二期变质作用约发生在１８００Ｍａ,ＰＴｔ轨迹为具近等压加热（ＩＢＨ）特点的顺时针轨迹,峰期阶段Ｔ为７６０～８１０℃,Ｐ为０．９６～１．０４ＧＰａ,这种轨迹与大陆地壳的拉伸作用有密切关系。     

宁芜陶村磁铁矿矿床成矿流体及成矿作用

陶村磁铁矿矿床位于长江中下游成矿带宁芜盆地中段,矿床地质特征及岩浆构造背景与Kiruna型磷灰石-铁氧化物矿床相似。本文在野外工作基础上,通过流体包裹体测温和氢氧硫同位素研究,探讨该矿床成矿流体性质、来源及成矿作用。陶村主要矿石类型为浸染状和脉状磁铁矿,脉状矿石形成稍晚。通过包裹体显微测温获得:磷灰石中包裹体的均一温度集中在210~390℃,盐度集中在15%~23%NaCl_(eqv);石英中包裹体的均一温度集中在330~390℃,盐度主要集中在9%~13%NaCl_(eqv),此外还存在部分高盐度原生包裹体。石英的δD为-96‰~-54‰,δ~(18)O_(H2O)除了一个为8.3‰,其余为1.9‰~4.0‰,指示原始成矿流体为岩浆来源,后期有地表水加入。黄铁矿δ~(34)S为4.8‰~9.3‰,平均值为7.4‰,综合中段地区硫同位素资料,认为成矿流体中的硫来自三叠纪膏盐层与岩浆硫的混合。结合矿床地质特征,陶村成矿作用过程可概括为:岩浆出溶形成的高温含矿气液同化三叠纪膏盐层,带入SO_4~(2-)、Cl~-、Na~+等矿化剂;这种高温气液在岩体内以钠质交代形式富集Fe后,于岩体上部形成浸染状磁铁矿,岩体顶部和边部断裂部位形成(网)脉状磁铁矿。     

湘西-黔东下寒武统清虚洞组藻灰岩沉积特征及其找矿意义

铅锌矿是湘西-黔东地区的优势矿种,资源丰富,开发历史悠久,找矿潜力巨大。综合分析前人有关湘西-黔东生物礁的资料,介绍了藻灰岩的沉积特征,并结合大量实际地质资料,对藻灰岩控矿进行了论述。结果表明: 成矿物质主要来源于藻类及碳酸盐泥对Pb²⁺、Zn²⁺离子的吸取,矿床成因属于沉积成岩矿床类型,兼有成岩期后矿床性质; 藻礁灰岩与不同岩性的接合部位及其附近等微地球化学障区,往往就是铅锌富矿体产出部位; 藻礁灰岩与礁间通道的薄层泥质白云质灰岩呈指状交叉接触处,也常有铅锌富矿体产出; 铅锌富矿体基本上产于清虚洞组灰岩段中,且明显受该段藻礁灰岩控制。为满足国内外对铅锌矿日益增长的消费需要,深入研究区内铅锌矿的地层岩相岩石控矿因素及其富集规律,指导该地区藻灰岩中铅锌矿找矿工作,具有重要的现实意义。     

Porosity and wave velocity evolution of granite after high-temperature treatment: a review

The evolution of porosity and changes in wave velocity in granite after high-temperature treatment has been experimentally investigated in different studies. Statistical analysis of the test results shows that there is a temperature threshold value that leads to variations in porosity and wave velocity. At a temperature that is less than 200 °C, the porosity of granite slowly increases with increases in temperature, while the wave velocity decreases. When the temperature is greater than 200 °C (especially between 400 and 600 °C), the porosity quickly increases, while the wave velocity substantially decreases. The temperature ranges of room temperature to 200 and 200–400 °C correspond to the undamaged state and the micro-damage state, respectively. The results confirm that there is an important link between the variations of physical and mechanical properties in response to thermal treatment. By studying the relationships among rock porosity, wave velocity and temperature, this provides the basis for solving multi-variable coupling problems under high temperatures for the thermal exploitation of petroleum and safe disposal of nuclear waste.     

济阳坳陷惠民凹陷临盘地区始新统孔店组一段—沙河街组四段红层划分和对比

受气候控制的洪水事件沉积因其短暂性、广布性和周期性等特征,具有相对的等时效应,可以作为地层划分和对比的标志层。通过分析不同规模周期下的事件沉积和正常沉积特征,并结合基准面旋回理论,识别出济阳坳陷惠民凹陷临盘地区始新统孔店组一段—沙河街组四段下亚段红层短期、中期和长期三个级次的基准面旋回特征,短期旋回以洪水期和间洪水期内发育的不同类型沉积微相组合为特征,中期旋回以发育一套完整的洪水期—间洪水期沉积为标志,长期旋回则以多个中期旋回组成的地层叠加为特征;以此为依据将惠民凹陷临盘地区孔店组一段—沙河街组四段下亚段划分为5个长期旋回、16个中期旋回及若干个短期旋回层序,并对第一个长期旋回进行了精细层序地层对比,在此基础上建立了干旱气候控制下的红层层序的划分和对比模式。