Ionic surfactants adsorption on heterogeneous surfacesAdsorption de tensioactifs ioniques sur les surfaces hétérogènes

The adsorption of surfactants from aqueous solution is a phenomenon of major importance in applications ranging from ore flotation and paint technology to enhanced oil recovery. As this paper will illustrate, the process is very complex and of high scientific interest; its results can be extended to the retention of organic compounds (humic and fulvic acids, pollutants...) on solids in the biosphere. For a good understanding of the mechanisms involved in surfactants adsorption at the hydrophilic solid–aqueous solution interface, thermodynamic models have to take into account: (i) the physical chemistry of the surfactant in aqueous solution for choosing the appropriate reference phase, (ii) the surface heterogeneity of the adsorbing solid, (iii) the intensity of normal adsorbate–adsorbent bonds responsible for adsorption, (iv) the intensity of lateral bonds that favour the formation of surface aggregates through cooperative process and finally, (v) suitable theoretical models to describe adsorption phenomena. Once this has been achieved, two systems can be discussed: systems characterised by strong normal adsorbate–adsorbent bonds, currently used in ore flotation, which lead, in the case of heterogeneous surfaces, to the formation of lamellar aggregates at monolayer concentration and bilayer formation for higher concentrations. Systems characterised by weak normal adsorbate–adsorbent bonds, currently used in enhanced oil recovery and hydrocarbon (bio)remediation, which correspond to: (i) formation of globular micelles at the solid surface near the CMC when the temperature is higher than the Krafft point, (ii) formation of bilayered lamellar aggregates in the opposite case, (iii) three-dimensional condensation on substrate (T<T_Krafft) if the ionic surfactant interacts with cations in the bulk. To cite this article: J.-M. Cases et al., C. R. Geoscience 334 (2002) 675–688.     

Surface heterogeneity of mineralsAnalyse de l'hétérogénéité superficielle des minéraux

The precise study of adsorption mechanisms at solid–liquid interfaces requires a good analysis of the surface heterogeneity of the studied solids. For that purpose, molecular probe technique is one of the most powerful, especially at solid–gas interfaces. Indeed, low-pressure gas adsorption coupled to modelling of derivative adsorption isotherms as a function of logarithm of pressure allows to study qualitatively and quantitatively the effect of surface heterogeneity on the energy distribution of adsorption centres. The present review points out the interests of that approach to determine the shape of particles, the presence of high-energy adsorption sites and the surface polarity. Results comparing adsorption at solid–gas and solid–liquid interfaces are also mentioned. To cite this article: F. Villiéras et al., C. R. Geoscience 334 (2002) 597–609.     

On the dynamics of the metagalaxy

The dynamical aspects of the metagalactic model are studied. In particular, the consequences of high galaxy and quasar red shifts are considered. A number of explosion mechanisms are investigated and limits are given for the velocities they can produce. In case of constant density in the local rest frame limits are also given for the parameter ₀, for our position in the metagalaxy, and for the initial mass.Paper dedicated to Professor Hannes Alfvén on the occasion of his 80th birthday, 30 May 1988.     

Geology of the Edda Field Reservoir

The Edda Field, which was discovered in 1972, is located in the southern part of the Norwegian Sector of the North Sea. As in the nearby Ekofisk Field, chalk reservoir in the Danian (Lower Paleocene) and Maastrichtian (Upper Cretaceous) contain oil which originated in the Upper Jurassic organic rich shale sequence. A 15 slots drilling-production platform was installed on the basis of the results of 3 exploration appraisal wells. Seven producer wells were drilled and completed in 1979 and a production peak of about 33000 BOPD was reached in January 1980. All the development wells encountered less yield than expected and the 3 wells drilled on the southern flank of the structure were dry. Most of the characteristics of the chalk reservoir were known at that time but the existence of a pre-Maastrichtian paleo-relief in that area had not yet been established. This paleo-feature, the Lindesnes Ridge, strongly influenced the distribution and characteristics of the reservoir. Variation in initial porosity is the result of changes in sedimentation mode and rate as well as differential early cementation and mechanical compaction over the paleo-high. Differential porosity preservation is partly due to progressive infill of the trap by hydrocarbons but, as in most chalk fields, overpressure in the porous chalk layers was an important prerequisite.     

The Seafloor Borehole Array Seismic System (SEABASS) and VLF ambient noise

The Seafloor Borehole Array Seismic System (SEABASS) has been developed to measure the pressure and threedimensional particle velocity of the VLF sound field (2–50 Hz) below the seafloor in the deep ocean. The system consists of four three-component borehole seismometers (with an optional hydrophone). a borehole digitizing unit, and a seafloor control and recording package. The system can be deployed using a wireline re-entry capability from a conventional research vessel in Deep Sea Drilling Project (DSDP) and Ocean Drilling Project (ODP) boreholes. Data from below the seafloor are acquired either onboard the research vessel via coaxial tether or remotely on the seafloor in a self-contained package. If necessary the data module from the seafloor package can be released independently and recovered on the surface. This paper describes the engineering specifications of SEABASS, the tests that were carried out, and preliminary results from an actual deep sea deployment. VLF ambient noise levels beneath the seafloor acquired on the Low Frequency Acoustic-Seismic Experiment (LFASE) are within 20 dB of levels from previous seafloor borehole seismic experiments and from land borehole measurements. The ambient noise observed on LFASE decreases by up to 12 dB in the upper 100 m of the seafloor in a sedimentary environment.     

Solar and anthropogenic imprints on Lake Masoko (southern Tanzania) during the last 500 years

The Masoko crater-lake in southern Tanzania provides a continuous record of environmental changes covering the last 500 years. Multi-proxy studies were performed on a 52 cm sediment core retrieved from the deepest part of the lake. Magnetic, organic carbon, geochemical proxies and pollen assemblages indicate a dry climate during the ‘Little Ice Age’ (AD 1550–1850), confirming that the LIA in eastern Africa resulted in marked and synchronous hydrological changes. However, the direction of response varies between different African lakes (low versus high lake-levels), indicating strong regional contrasts that prevent the clear identification of climate trends over eastern Africa at this time. Inferred changes in Masoko lake-levels closely resemble the record of solar activity cycles, indicating a possible control of solar activity on the climate in this area. This observation supports previous results from East African lakes, and extends this relationship southward. Finally, anthropogenic impact is observed in the Masoko sediments during the last 60 years, suggesting that human disturbance significantly affected this remote basin during colonial and post-colonial times.     

Comparison of free-surface and rigid-lid finite element models of barotropic instabilities

The main goal of this work is to appraise the finite element method in the way it represents barotropic instabilities. To that end, three different formulations are employed. The free-surface formulation solves the primitive shallow-water equations and is of predominant use for ocean modeling. The vorticity–stream function and velocity–pressure formulations resort to the rigid-lid approximation and are presented because theoretical results are based on the same approximation. The growth rates for all three formulations are compared for hyperbolic tangent and piecewise linear shear flows. Structured and unstructured meshes are utilized. The investigation is also extended to time scales that allow for instability meanders to unfold, permitting the formation of eddies. We find that all three finite element formulations accurately represent barotropic instablities. In particular, convergence of growth rates toward theoretical ones is observed in all cases. It is also shown that the use of unstructured meshes allows for decreasing the computational cost while achieving greater accuracy. Overall, we find that the finite element method for free-surface models is effective at representing barotropic instabilities when it is combined with an appropriate advection scheme and, most importantly, adapted meshes.     

The coupling of optimal economic growth and climate dynamics

In this paper, we study optimal economic growth programs coupled with climate change dynamics. The study is based on models derived from MERGE, a well established integrated assessment model (IAM). We discuss first the introduction in MERGE of a set of “tolerable window” constraints which limit both the temperature change and the rate of temperature change. These constraints, obtained from ensemble simulations performed with the Bern 2.5-D climate model, allow us to identity a domain intended to preserve the Atlantic thermohaline circulation. Next, we report on experiments where a two-way coupling is realized between the economic module of MERGE and an intermediate complexity “3-D-” climate model (C-GOLDSTEIN) which computes the changes in climate and mean temperature. The coupling is achieved through the implementation of an advanced “oracle based optimization technique” which permits the integration of information coming from the climate model during the search for the optimal economic growth path. Both cost-effectiveness and cost-benefit analysis modes are explored with this combined “meta-model” which we refer to as GOLDMERGE. Some perspectives on future implementations of these approaches in the context of “collaborative” or “community” integrated assessment modules are derived from the comparison of the different approaches.