Electrical resistivity investigation of the arsenic affected alluvial aquifers in West Bengal,India: usefulness in identifying the areas of low and high groundwater arsenic

This study aims at finding out possible relation between lithology and spatial pattern of dissolved arsenic (As) in groundwater around Chakdaha municipality, West Bengal, India. Satellite image, coupled with electrical resistivity survey and borehole drilling helps to delineate surface and sub-surface lithological framework of the As affected alluvial aquifers. The satellite imagery demonstrate that the high As area are presumably under active flood plain environment (low-lying areas), that constantly receive organics due to periodic flooding. Thick low resistive (fine-grained) layer was observed at the top around the high As areas, which, however, not found in low As areas. The result suggests that hydraulic properties of the surface/sub-surface soil/sediment have an important control on the fate and transport of As in the aquifer. This study demonstrates that electrical resistivity tools can be effectively used for the reconnaissance survey in characterizing the plausible lithological framework of an alluvial aquifer containing As.     

New insight on aliphatic linkages in the macromolecular organic fraction of Orgueil and Murchison meteorites through ruthenium tetroxide oxidation

Ruthenium tetroxide oxidation was used to examine the macromolecular insoluble organic matter (IOM) from the Orgueil and Murchison meteorites and especially to characterize the aliphatic linkages. Already applied to various terrestrial samples, ruthenium tetroxide is a selective oxidant which destroys aromatic units, converting them into CO₂, and yields aliphatic and aromatic acids. In our experiment on chondritic IOM, it produces mainly short aliphatic diacids and polycarboxylic aromatic acids. Some short hydroxyacids are also detected.Aliphatic diacids are interpreted as aliphatic bridges between aromatic units in the chemical structure, and polycarboxylic aromatic acids are the result of the fusion of polyaromatic units. The product distribution shows that aliphatic links are short with numerous substitutions. No indigenous monocarboxylic acid was detected, showing that free aliphatic chains must be very short (less than three carbon atoms). The hydroxyacids are related to the occurrence of ester and ether functional groups within the aliphatic bridges between the aromatic units. This technique thus allows us to characterize in detail the aliphatic linkages of the IOMs, and the derived conclusions are in agreement with spectroscopic, pyrolytic, and degradative results previously reported.Compared to terrestrial samples, the aliphatic part of chondritic IOM is shorter and highly substituted. Aromatic units are smaller and more cross-linked than in coals, as already proposed from NMR data. Orgueil and Murchison IOM exhibit some tiny differences, especially in the length of aliphatic chains.     

Natural tracer profiles across argillaceous formations

Argillaceous formations generally act as aquitards because of their low hydraulic conductivities. This property, together with the large retention capacity of clays for cationic contaminants, has brought argillaceous formations into focus as potential host rocks for the geological disposal of radioactive and other waste. In several countries, programmes are under way to characterise the detailed transport properties of such formations at depth. In this context, the interpretation of profiles of natural tracers in pore waters across the formations can give valuable information about the large-scale and long-term transport behaviour of these formations. Here, tracer-profile data, obtained by various methods of pore-water extraction for nine sites in central Europe, are compiled. Data at each site comprise some or all of the conservative tracers: anions (Cl⁻, Br⁻), water isotopes (δ¹⁸O, δ²H) and noble gases (mainly He). Based on a careful evaluation of the palaeo-hydrogeological evolution at each site, model scenarios are derived for initial and boundary pore-water compositions and an attempt is made to numerically reproduce the observed tracer distributions in a consistent way for all tracers and sites, using transport parameters derived from laboratory or in situ tests. The comprehensive results from this project have been reported in Mazurek et al. (2009). Here the results for three sites are presented in detail, but the conclusions are based on model interpretations of the entire data set. In essentially all cases, the shapes of the profiles can be explained by diffusion acting as the dominant transport process over periods of several thousands to several millions of years and at the length scales of the profiles. Transport by advection has a negligible influence on the observed profiles at most sites, as can be shown by estimating the maximum advection velocities that still give acceptable fits of the model with the data. The advantages and disadvantages of different conservative tracers are also assessed. The anion Cl⁻ is well suited as a natural tracer in aquitards, because its concentration varies considerably in environmental waters. It can easily be measured, although the uncertainty regarding the fraction of the pore space that is accessible to anions in clays remains an issue. The stable water isotopes are also well suited, but they are more difficult to measure and their values generally exhibit a smaller relative range of variation. Chlorine isotopes (δ³⁷Cl) and He are more difficult to interpret because initial and boundary conditions cannot easily be constrained by independent evidence. It is also shown that the existence of perturbing events such as the activation of aquifers due to uplift and erosion, leading to relatively sharp changes of boundary conditions, can be considered as a pre-requisite to obtain well-interpretable tracer signatures. On the other hand, gradual changes of boundary conditions are more difficult to parameterise and so may preclude a clear interpretation.     

Whiting-related sediment export along the Middle Miocene carbonate ramp of Great Bahama Bank

Modern aragonite needles are present all along the modern leeward margin of Great Bahama Bank (ODP Leg 166), while Middle Miocene sediments contain needles only in more distal areas (Sites 1006 and 1007). In contrast to the rimmed, flat-topped platform topography during the Plio-Pleistocene, the Miocene Great Bahama Bank morphology is a carbonate ramp profile. This might imply a different location and precipitation type for Miocene aragonite needles. In this study, aragonite needles in Miocene sediments were isolated using a granulometric separation method. Furthermore, the isolation of the various carbonate components enables the identification of primary versus diagenetic components. The Miocene aragonite needles are concentrated in the finest granulometric sediment fractions (<12 μm). The fraction-specific geochemical analyses (δ¹³C, δ¹⁸O and Sr elemental abundance) represent useful tools to assess the possible sources of the aragonite mud. The geochemical variation of the fractions, rich in pristine aragonite needles, and the characteristics of the needle morphology point to whiting phenomena as the main sediment source and algal fragmentation as a minor component. Both components indicate shallow-water environments as the main sediment source area. Ramp-top-related fine-grained particles now present at distal sites were likely exported as suspended material similar to present-day transport mechanisms. The scarcity of needles at proximal sites is probably linked to hydrodynamic processes but dissolution and recrystallization processes cannot be excluded. The granulometric separation approach applied here enables a better characterization of the finest carbonate particles representing an important step towards the discrimination between primary and diagenetic fine-grained components.     

Anatexis and fluid regime of the deep continental crust: New clues from melt and fluid inclusions in metapelitic migmatites from Ivrea Zone (NW Italy)

We investigate the inclusions hosted in peritectic garnet from metapelitic migmatites of the Kinzigite Formation (Ivrea Zone, NW Italy) to evaluate the starting composition of the anatectic melt and fluid regime during anatexis throughout the upper amphibolite facies, transition, and granulite facies zones. Inclusions have negative crystal shapes, sizes from 2 to 10 μm and are regularly distributed in the core of the garnet. Microstructural and micro‐Raman investigations indicate the presence of two types of inclusions: crystallized silicate melt inclusions (i.e., nanogranitoids, NI), and fluid inclusions (FI). Microstructural evidence suggests that FI and NI coexist in the same cluster and are primary (i.e., were trapped simultaneously during garnet growth). FI have similar compositions in the three zones and comprise variable proportions of CO₂, CH₄, and N₂, commonly with siderite, pyrophyllite, and kaolinite, suggesting a COHN composition of the trapped fluid. The mineral assemblage in the NI contains K‐feldspar, plagioclase, quartz, biotite, muscovite, chlorite, graphite and, rarely, calcite. Polymorphs such as kumdykolite, cristobalite, tridymite, and less commonly kokchetavite, were also found. Rehomogenized NI from the different zones show that all the melts are leucogranitic but have slightly different compositions. In samples from the upper amphibolite facies, melts are less mafic (FeO + MgO = 2.0–3.4 wt%), contain 860–1700 ppm CO₂ and reach the highest H₂O contents (6.5–10 wt%). In the transition zone melts have intermediate H₂O (4.8–8.5 wt%), CO₂ (457–1534 ppm) and maficity (FeO + MgO = 2.3–3.9 wt%). In contrast, melts at granulite facies reach highest CaO, FeO + MgO (3.2–4.7 wt%), and CO₂ (up to 2,400 ppm), with H₂O contents comparable (5.4–8.3 wt%) to the other two zones. Our results represent the first clear evidence for carbonic fluid‐present melting in the Ivrea Zone. Anatexis of metapelites occurred through muscovite and biotite breakdown melting in the presence of a COH fluid, in a situation of fluid–melt immiscibility. The fluid is assumed to have been internally derived, produced initially by devolatilization of hydrous silicates in the graphitic protolith, then as a result of oxidation of carbon by consumption of Fe³⁺‐bearing biotite during melting. Variations in the compositions of the melts are interpreted to result from higher T of melting. The H₂O contents of the melts throughout the three zones are higher than usually assumed for initial H₂O contents of anatectic melts. The CO₂ contents are highest at granulite facies, and show that carbon‐contents of crustal magmas are not negligible at high T. The activity of H₂O of the fluid dissolved in granitic melts decreases with increasing metamorphic grade. Carbonic fluid‐present melting of the deep continental crust represents, together with hydrate‐breakdown melting reactions, an important process in the origin of crustal anatectic granitoids.     

Geochemical Features of the Two Early Paleozoic Ophiolitic Zones and Volcanic Rocks in the Central —Southern Tianshan Region ,Xinjiang

This paper deals with the geochemical features of the two Early Paleozoic ophiolite zones in the central-southem Tianshan region and the central Tianshan igneous rock belt between them.Study results suggest that the central Tianshan belt was an Ordovician volcanic arc with an affinity of continental crust, and the Kumux-Hongluhe ophiolitic zone that is located on the southern margin of central Tianshan has a crustal affinity to back-arc marginal sea.The Aqqikkudug-Weiya ophiolitic zone is an accretionary boundary between the Tuha continental block and the central Tianshan volcanic arc during Late Silurian to Devoniann;Ordovician ophi-olitic blocks,Silurian flysch sequence and HP metamorphic rock relics are distributed along the Aqqikkudug-Weiya zone.Geochemically,ophiolitic rocks in the Aqqikkudug-Weiya zone have an affinity to oceanic crust,reflecting a tectonic setting of paleo-trench or subduction zone .The Early Carboniferous red molasses were deposited unconformably on the pre-Carboniferous meta-mrophosed and ductile sheared volcanic and flysch rocks,providing an upper limit age of the central and southern Tianshan belts.     

MUREX: a land-surface field experiment to study the annual cycle of the energy and water budgets

The MUREX (monitoring the usable soil reservoir experimentally) experiment was designed to provide continuous time series of field data over a long period, in order to improve and validate the Soil-vegetation-Atmosphere Transfer (SVAT) parameterisations employed in meteorological models. Intensive measurements were performed for more than three years over fallow farmland in southwestern France. To capture the main processes controlling land-atmosphere exchanges, the local climate was fully characterised, and surface water and energy fluxes, vegetation biomass, soil moisture profiles, surface soil moisture and surface and soil temperature were monitored. Additional physiological measurements were carried out during selected periods to describe the biological control of the fluxes. The MUREX data of 1995, 1996, and 1997 are presented. Four SVAT models are applied to the annual cycle of 1995. In general, they succeed in simulating the main features of the fallow functioning, although some shortcomings are revealed.     

CARAIB陆地碳循环模型研究进展及其应用

陆地生态系统碳循环是全球变化研究中的重要组成部分,多种模型已用于陆地生态系统碳循环的模拟。文中着重论述了陆地生物圈碳循环模型CARAIB的原理、方法及其应用和最新进展。CARAIB模型主要是基于叶面光合作用子模型、冠层子模型和木质呼吸作用3个子模型的耦合,应用大气环流模式气候数据模拟出生态系统碳存储量和生物群区分布。介绍了欧洲利用植物数字化地理配准数据库重新划分植物群组(BAGs)的方法,比较BAGs与传统的植物功能型(PFTs)划分在方法上的差异,根据植物群组应用CARAIB模型进行生物群区分布模拟,并提出利用CARAIB模型模拟我国陆地碳循环和生物群区分布的可行性,为研究中国植被对气候变化的响应模型和预测提供区域尺度的新方法。     

Interannual variability of deep convection in the Northwestern Mediterranean simulated with a coupled AORCM

A hindcast experiment of the Mediterranean present-day climate is performed using a fully-coupled Atmosphere–Ocean Regional Climate Model (AORCM) for the Mediterranean basin. The new model, called LMDz-NEMO-Med, is composed of LMDz4-regional as atmospheric component and of NEMOMED8 as oceanic component. This AORCM equilibrates freely, without any flux adjustment, neither in fresh water nor in heat. At its atmospheric lateral boundary conditions, it is driven by ERA-40 data from 1958 to 2001, after a spin-up of 40 years in coupled configuration. The model performance is assessed and compared with available observational datasets. The model skill in reproducing mean state and inter-annual variability of main atmospheric and oceanic surface fields is in line with that of state-of-the-art AORCMs. Considering the ocean behaviour, the inter-annual variations of the basin-scale heat content are in very good agreement with the observations. The model results concerning salt content could not be adequately validated. High inter-annual variability of deep convection in the Gulf of Lion is simulated, with 53 % of convective winters, representative of the present climate state. The role of different factors influencing the deep convection and its inter-annual variability is examined, including dynamic and hydrostatic ocean preconditioning and atmospheric surface forcing. A conceptual framework is outlined and validated in linking the occurrence of deep convection to the efficiency of the integrated surface buoyancy fluxes along the winter season to mix the initially stratified averaged water column down to the convective threshold depth. This simple framework (based only on 2 independent variables) is able to explain 60 % (resp. 69 %) of inter-annual variability of the deep water formation rate (resp. maximum mixed layer depth) for the West Mediterranean Deep Water (WMDW) formation process.