Deposits related to degradation processes on Piton des Neiges Volcano (Reunion Island): overview and geological hazard

Piton des Neiges (PN) Volcano on Reunion Island offers a rare opportunity to study deposits related to degradation processes in a deeply eroded oceanic shield volcano. Both the inner parts and flanks reveal a large amount of resedimented volcaniclastic material, including extensive debris avalanche deposits. PN litho–structural units, first studied by Upton and Wadsworth [1965, Philos. Trans. R. Soc. Lond., A 271, pp. 105–130], are re-examined. This review highlights the importance of long volcanic repose periods and erosion processes during PN history. volcaniclastic deposits have been studied in the field in order to evaluate the spatial and temporal distribution of the three main types of PN degradation processes. The deposits of these processes have been classified into: (1) talus, (2) mudflow and debris flow, and (3) debris avalanche. Lithology, frequency and estimated volumes of each deposit type imply that the structural evolution of PN can be considered in terms of the competition between the volcanic productivity and the degradation and erosion processes. The occurrence of huge catastrophic avalanches produced by flank failure is convincingly linked to the basaltic activity of PN, which implies a very low risk at present. On the contrary, mudflows and debris flows pose an important risk due to the high population density focussed around the basin outlets. Moreover, if smaller debris avalanches can occur in the cirques of PN, another major risk must be evaluated.     

Seismically induced shale diapirism: the Mine d’Or section,Vilaine estuary,Southern Brittany

The Pénestin section (southern Brittany) presents large regular undulations, commonly interpreted as evidence of periglacial pingos. It is an upper Neogene palaeoestuary of the Vilaine River reactivated during the middle Quaternary (middle terrace). It is incised into a thick kaolinitic saprolite and deformed by saprolite diapirs. This paper presents the arguments leading to a mechanistic interpretation of the deformations at Pénestin. Neither recent transpressive tectonics nor diagnostic evidence of periglacial pingo have been found despite evidence for a late paleo-permafrost. The major deformational process is shale diapirism, initially triggered by co-seismic water supply, with further loading and lateral spreading on an already deformed and deeply weathered basement, which allowed the shale diapirism to develop. Deformations are favoured by the liquefaction of the saprolite and a seaward mass movement and recorded, rather distant, effects of an earthquake (c. 280 ka B.P.) resulting from the progressive subsidence of the southern Armorican margin. These deformations triggered by an earthquake are similar to those induced by classical shale diapirism. They are probably common in tectonically active continental environments with shallow water table.     

Te-Rich argyrodite occurrence in Roşia Montană ore deposit,Apuseni Mountains,Romania

A new argyrodite occurrence has been discovered in the Ro?ia Montan? ore deposit located in the South Apuseni Mountains, Romania. Argyrodite is associated with common base metal sulfides and sulfosalts (galena, sphalerite, chalcopyrite, tetrahedrite ± alabandite, pyrite, and marcasite), tellurides (hessite, altaite, sylvanite) and rare electrum grains in the Ag-rich Cârnicel vein hosted by an extracraterial phreatomagmatic breccia within the Cârnic massif. SEM and EPMA analyses revealed that this argyrodite is Te-rich and a mean Ag_8.04Ge_0.9Te_2.07S_3.77 formula was calculated. This phase could be the germaniferous equivalent of the previously-described Te-rich canfieldite. To cite this article: L. Bailly et al., C. R. Geoscience 337 (2005).     

Structural Interpretation of Sparse Fault Data Using Graph Theory and Geological Rules

Structural uncertainty exists when associating sparse fault interpretations made from two-dimensional seismic lines or limited outcrop observations. Here, a graph formalism is proposed that describes the problem of associating spatial fault evidence. A combinatorial analysis, relying on this formalism, shows that the number of association scenarios is given by the Bell number, and increases exponentially with the number of pieces of evidence. As a result, the complete exploration of uncertainties is computationally highly challenging. The available prior geological knowledge is expressed by numerical rules to reduce the number of scenarios, and the graph formalism makes structural interpretation easier to reproduce than manual interpretation. The Bron–Kerbosch algorithm, which finds maximal cliques in undirected graphs, is used to detect major possible structures. This framework opens the way to a numerically assisted exploration of uncertainties during structural interpretation.

     

Natural attenuation of TCE, As, Hg linked to the heterogeneous oxidation of Fe(II): an AFM study

Hydrous ferric oxide (HFO) colloids formed, in strictly anoxic conditions upon oxidation of Fe²⁺ ions adsorbed on mineral surface, were investigated under in situ conditions by contact mode atomic force microscopy (AFM). Freshly cleaved and acid-etched large single crystals of near endmember phlogopite were pre-equilibrated with dissolved Fe(II) and then reacted with Hg(II), As(V) and trichlorethene (TCE)-bearing solutions at 25 °C and 1 atm. HFO structures are found to be of nanometer scale. The As(V)–Fe(II) and Hg(II)–Fe(II) reaction products are round (25 nm) microcrystallites located predominantly on the layer edges and are indicative of an accelerated Fe(II) oxidation rate upon formation of Fe(II) inner sphere surface complexes with the phyllosilicate edge surface sites. On the other hand, TCE–Fe(II)–phlogopite reaction products are needle-shaped (45 nm long) particles located on the basal plane along the Periodic Bond Chains (PCBs) directions. Experiments with additions of sodium chloride confirm the importance of the Fe(II) adsorption step in the control of the overall heterogeneous Fe(II)–TCE electron transfer reaction.

Kinetic measurements at the nanomolar level of Hg° formed upon reduction of Hg(II) by Fe(II) in presence of phlogopite particles provide further convincing evidence for reduction of Hg(II)_aq coupled to the oxidation of Fe(II) adsorbed at the phlogopite–fluid interface, and indicate that sorption of Fe(II) to mineral surfaces enhances the reduction rate of Hg(II) species. The Hg(II) reduction reaction follows a first-order kinetic law. Under our experimental conditions, which were representative of many natural systems, 80% of the mercury is transferred to the atmosphere as Hg° in less than 2 h.

The reduction of a heavy metal (Hg), a toxic oxyanion (arsenate ion) and a chlorinated solvent (TCE) thus appear to be driven by the high reactivity of adsorbed Fe(II). This is of environmental relevance since these three priority pollutants are that way reductively transformed to a volatile, an immobilizable and a biodegradable species, respectively. Such kinetic data and reaction pathways are important in the evaluation of natural evaluation scenarios, in the optimization of Fe(II)/mineral mixtures as reductants in technical systems, and in general, in predicting the fate and transport of pollutants in natural systems.     

Sorption and catalytic oxidation of Fe(II) at the surface of calcite

The effect of sorption and coprecipitation of Fe(II) with calcite on the kinetics of Fe(II) oxidation was investigated. The interaction of Fe(II) with calcite was studied experimentally in the absence and presence of oxygen. The sorption of Fe(II) on calcite occurred in two distinguishable steps: (a) a rapid adsorption step (seconds-minutes) was followed by (b) a slower incorporation (hours-weeks). The incorporated Fe(II) could not be remobilized by a strong complexing agent (phenanthroline or ferrozine) but the dissolution of the outmost calcite layers with carbonic acid allowed its recovery. Based on results of the latter dissolution experiments, a stoichiometry of 0.4 mol% Fe:Ca and a mixed carbonate layer thickness of 25 nm (after 168 h equilibration) were estimated. Fe(II) sorption on calcite could be successfully described by a surface adsorption and precipitation model (Comans & Middelburg, GCA51 (1987), 2587) and surface complexation modeling (Van Cappellen et al., GCA57 (1993), 3505; Pokrovsky et al., Langmuir16 (2000), 2677). The surface complex model required the consideration of two adsorbed Fe(II) surface species, >CO₃Fe⁺ and >CO₃FeCO₃H⁰. For the formation of the latter species, a stability constant is being suggested. The oxidation kinetics of Fe(II) in the presence of calcite depended on the equilibration time of aqueous Fe(II) with the mineral prior to the introduction of oxygen. If pre-equilibrated for >15 h, the oxidation kinetics was comparable to a calcite-free system (t_1/2 = 145 ± 15 min). Conversely, if Fe(II) was added to an aerated calcite suspension, the rate of oxidation was higher than in the absence of calcite (t_1/2 = 41 ± 1 min and t_1/2 = 100 ± 15 min, respectively). This catalysis was due to the greater reactivity of the adsorbed Fe(II) species, >CO₃FeCO₃H⁰, for which the species specific rate constant was estimated.     

Optimization framework for calibration of constitutive models enhanced by neural networks

A two‐level procedure designed for the estimation of constitutive model parameters is presented in this paper. The neural network (NN) approach at the first level is applied to achieve the first approximation of parameters. This technique is used to avoid potential pitfalls related to the conventional gradient‐based optimization techniques, considered here as a corrector that improves predicted parameters. The feed‐forward NN (FFNN) and the modified Gauss–Newton algorithms are briefly presented. The proposed framework is verified for the elasto‐plastic modified Cam Clay model that can be calibrated based on standard triaxial laboratory tests, i.e. the isotropic consolidation test and the drained compression test. Two different formulations of the input data to the NN, enhanced by a dimensional reduction of experimental data using principal component analysis, are presented. The determination of model characteristics is demonstrated, first on numerical pseudo‐experiments and then on the experimental data. The efficiency of the proposed approach by means of accuracy and computational effort is also discussed. Copyright © 2008 John Wiley & Sons, Ltd.     

Theoretical and numerical studies of the Vishniac instability in supernova remnants

Vishniac instability has been theoretically studied in supernova remnants where it is supposed to explain the fragmentation of the interstellar medium. However its role is not fully demonstrated in these astrophysical objects. Conditions and assumptions required for the instability growth are explained in detail in the present paper. In addition the HYDRO-MUSCL hydrodynamic code has been used to simulate this instability in order to compare the numerical growth rate with the Vishniac analytical solution.