Controls on ostracod valve geochemistry, Part 1: Variations of environmental parameters in ostracod (micro-)habitats

The variations of environmental conditions (T°, pH, δ¹³C_DIC, [DIC], δ¹⁸O, Mg/Ca, and Sr/Ca) of ostracod habitats were examined to determine the controls of environmental parameters on the chemical and isotopic composition of ostracod valves. Results of a one-year monitoring of environmental parameters at five sites, with depths of between 2 and 70 m, in Lake Geneva indicate that in littoral to sub-littoral zones (2, 5, and 13 m), the chemical composition of bottom water varies seasonally in concert with changes in temperature and photosynthetic activity. An increase of temperature and photosynthetic activity leads to an increase in δ¹³C values of DIC and to precipitation of authigenic calcite, which results in a concomitant increase of Mg/Ca and Sr/Ca ratios of water. In deeper sites (33 and 70 m), the composition of bottom water remains constant throughout the year and isotopic values and trace element contents are similar to those of deep water within the lake. The chemical composition of interstitial pore water also does not reflect seasonal variations but is controlled by calcite dissolution, aerobic respiration, anaerobic respiration with reduction of sulphate and/or nitrate, and methanogenesis that may occur in the sediment pores. Relative influence of each of these factors on the pore water geochemistry depends on sediment thickness and texture, oxygen content in bottom as well as pore water. Variations of chemical compositions of the ostracod valves of this study vary according to the specific ecology of the ostracod species analysed, that is its life-cycle and its (micro-)habitat. Littoral species have compositions that are related to the seasonal variations of temperature, δ¹³C values of DIC, and of Mg/Ca and Sr/Ca ratios of water. In contrast, the compositions of profundal species are largely controlled by variations of pore fluids along sediment depth profiles according to the specific depth preference of the species. The control on the geochemistry of sub-littoral species is a combination of controls for the littoral and profundal species as well as the specific ecology of the species.     

Natural tracer profiles across argillaceous formations

Argillaceous formations generally act as aquitards because of their low hydraulic conductivities. This property, together with the large retention capacity of clays for cationic contaminants, has brought argillaceous formations into focus as potential host rocks for the geological disposal of radioactive and other waste. In several countries, programmes are under way to characterise the detailed transport properties of such formations at depth. In this context, the interpretation of profiles of natural tracers in pore waters across the formations can give valuable information about the large-scale and long-term transport behaviour of these formations. Here, tracer-profile data, obtained by various methods of pore-water extraction for nine sites in central Europe, are compiled. Data at each site comprise some or all of the conservative tracers: anions (Cl⁻, Br⁻), water isotopes (δ¹⁸O, δ²H) and noble gases (mainly He). Based on a careful evaluation of the palaeo-hydrogeological evolution at each site, model scenarios are derived for initial and boundary pore-water compositions and an attempt is made to numerically reproduce the observed tracer distributions in a consistent way for all tracers and sites, using transport parameters derived from laboratory or in situ tests. The comprehensive results from this project have been reported in Mazurek et al. (2009). Here the results for three sites are presented in detail, but the conclusions are based on model interpretations of the entire data set. In essentially all cases, the shapes of the profiles can be explained by diffusion acting as the dominant transport process over periods of several thousands to several millions of years and at the length scales of the profiles. Transport by advection has a negligible influence on the observed profiles at most sites, as can be shown by estimating the maximum advection velocities that still give acceptable fits of the model with the data. The advantages and disadvantages of different conservative tracers are also assessed. The anion Cl⁻ is well suited as a natural tracer in aquitards, because its concentration varies considerably in environmental waters. It can easily be measured, although the uncertainty regarding the fraction of the pore space that is accessible to anions in clays remains an issue. The stable water isotopes are also well suited, but they are more difficult to measure and their values generally exhibit a smaller relative range of variation. Chlorine isotopes (δ³⁷Cl) and He are more difficult to interpret because initial and boundary conditions cannot easily be constrained by independent evidence. It is also shown that the existence of perturbing events such as the activation of aquifers due to uplift and erosion, leading to relatively sharp changes of boundary conditions, can be considered as a pre-requisite to obtain well-interpretable tracer signatures. On the other hand, gradual changes of boundary conditions are more difficult to parameterise and so may preclude a clear interpretation.     

Relation between two common localisation methods for the EnKF

This study investigates the relation between two common localisation methods in ensemble Kalman filter (EnKF) systems: covariance localisation and local analysis. Both methods are popular in large-scale applications with the EnKF. The case of local observations with non-correlated errors is considered. Both methods are formulated in terms of tapering of ensemble anomalies, which provides a framework for their comparison. Based on analytical considerations and experimental evidence, we conclude that in practice the two methods should yield very similar results, so that the choice between them should be based on other criteria, such as numerical effectiveness and scalability.     

Whiting-related sediment export along the Middle Miocene carbonate ramp of Great Bahama Bank

Modern aragonite needles are present all along the modern leeward margin of Great Bahama Bank (ODP Leg 166), while Middle Miocene sediments contain needles only in more distal areas (Sites 1006 and 1007). In contrast to the rimmed, flat-topped platform topography during the Plio-Pleistocene, the Miocene Great Bahama Bank morphology is a carbonate ramp profile. This might imply a different location and precipitation type for Miocene aragonite needles. In this study, aragonite needles in Miocene sediments were isolated using a granulometric separation method. Furthermore, the isolation of the various carbonate components enables the identification of primary versus diagenetic components. The Miocene aragonite needles are concentrated in the finest granulometric sediment fractions (<12 μm). The fraction-specific geochemical analyses (δ¹³C, δ¹⁸O and Sr elemental abundance) represent useful tools to assess the possible sources of the aragonite mud. The geochemical variation of the fractions, rich in pristine aragonite needles, and the characteristics of the needle morphology point to whiting phenomena as the main sediment source and algal fragmentation as a minor component. Both components indicate shallow-water environments as the main sediment source area. Ramp-top-related fine-grained particles now present at distal sites were likely exported as suspended material similar to present-day transport mechanisms. The scarcity of needles at proximal sites is probably linked to hydrodynamic processes but dissolution and recrystallization processes cannot be excluded. The granulometric separation approach applied here enables a better characterization of the finest carbonate particles representing an important step towards the discrimination between primary and diagenetic fine-grained components.     

There’s more to the picture than meets the eye: Sampling microphytobenthos in a heterogeneous environment

Distributions of microphytobenthos are highly heterogeneous at scales as small as a few centimetres. However, the sampling protocols currently used for the absolute determination of microphytobenthos biomass through chlorophyll a concentration measurements in surface sediments are too limited to take this variability into account, typically relying on 3-5 samples taken within a randomly located 1 m² quadrat in a given environment. We address this issue by objectively and quantitatively inferring the minimum number of samples required to obtain reliable estimates of microphytobenthos biomass on the basis of high-resolution sub-sampling (225 regularly spaced samples) within each of nine 1 m² quadrats at an unvegetated sheltered intertidal sandbank of the Gold Coast (Queensland, Australia). The results were generalised using data obtained in previous studies on an exposed sandy shore and on sheltered estuarine sandy muds of the Eastern English Channel. Estimates of chlorophyll a concentration exhibited a high degree of heterogeneity, both between and within quadrats. The number of samples needed to estimate the average chlorophyll a concentration, and hence mean microphytobenthos biomass with 95% confidence intervals, ranged from 15 to 115, and mainly depended on the presence of global and local gradients within the quadrats. These results have major implications for intertidal ecology by implying a possible systematic bias in the measurement of both microphytobenthos biomass and production of up to 40%. Finally, we emphasise that this issue can be circumvented using field spectrometry or PAM fluorescence measurements coupled with traditional sediment sampling techniques, and urge for unified protocols to be adopted for the routine use of these combined methods.     

The impact of soil moisture–atmosphere coupling on daily maximum surface temperatures in Southeastern South America

Based on a series of experiments conducted by two regional climate models (RCA4 and LMDZ) with and without soil moisture-atmosphere coupling, we investigate the role of soil moisture on the occurrence of surface air temperature extremes and its persistence in Southeastern South America. Our analysis reveals that both factors, soil moisture-atmosphere coupling and relatively drier soil conditions, enhance the temperature extremes. In addition, the existence of soil-atmosphere coupling and the associated soil moisture variability is crucial for the development of the extremes in SESA. The key role of soil-atmosphere coupling is also reflected in the intrinsic persistence of hot days, which is greater in simulations with interactive soil moisture than in those with prescribed soil conditions. In the absence of soil-atmosphere coupling, the imprint of the anomalous dry (and also wet) soil conditions on the intensity and persistence of hot days is weaker.

     

Variation of surface temperature during the last millennium in a simulation with the FGOALS-gl climate system model

A reasonable past millennial climate simulation relies heavily on the specified external forcings, including both natural and anthropogenic forcing agents. In this paper, we examine the surface temperature responses to specified external forcing agents in a millennium-scale transient climate simulation with the fast version of LASG IAP Flexible Global Ocean-Atmosphere-Land System model (FGOALS-gl) developed in the State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics, Institute of Atmospheric Physics (LASG/IAP). The model presents a reasonable performance in comparison with reconstructions of surface temperature. Differentiated from significant changes in the 20th century at the global scale, changes during the natural-forcing-dominant period are mainly manifested in the Northern Hemisphere. Seasonally, modeled significant changes are more pronounced during the wintertime at higher latitudes. This may be a manifestation of polar amplification associated with sea-ice-temperature positive feedback. The climate responses to total external forcings can explain about half of the climate variance during the whole millennium period, especially at decadal timescales. Surface temperature in the Antarctic shows heterogeneous and insignificant changes during the preindustrial period and the climate response to external forcings is undetectable due to the strong internal variability. The model response to specified external forcings is modulated by cloud radiative forcing (CRF). The CRF acts against the fluctuations of external forcings. Effects of clouds are manifested in shortwave radiation by changes in cloud water during the natural-forcing-dominant period, but mainly in longwave radiation by a decrease in cloud amount in the anthropogenic-forcing-dominant period.     

The quasi-stationary feature of nocturnal precipitation in the Sichuan Basin and the role of the Tibetan Plateau

The nocturnal precipitation in the Sichuan Basin in summer has been studied in many previous works. This paper expands the study on the diurnal cycle of precipitation in the Sichuan Basin to the whole year. Results show that the nocturnal precipitation has a specific quasi-stationary feature in the basin. It occurs not only in summer but also in other three seasons, even more remarkable in spring and autumn than in summer. There is a prominent eastward timing delay in the nocturnal precipitation, that is, the diurnal peak of precipitation occurs at early-night in the western basin whereas at late-night in the center and east of the basin. The Tibetan Plateau plays an essential role in the formation of this quasi-stationary nocturnal precipitation. The early-night peak of precipitation in the western basin is largely due to strong ascending over the plateau and its eastern lee side. In the central and eastern basin, three coexisting factors contribute to the late-night peak of precipitation. One is the lower-tropospheric southwesterly flow around the southeastern edge of the Tibetan Plateau, which creates a strong cyclonic rotation and ascendance in the basin at late-night, as well as brings abundant water vapor. The second is the descending motion downslope along the eastern lee side of the plateau, together with an air mass accumulation caused by the warmer air mass transport from the southeast of the Yunnan-Guizhou Plateau, creating a diabatic warming at low level of the troposphere in the central basin. The third is a cold advection from the plateau to the basin at late-night, which leads to a cooling in the middle troposphere over the central basin. All these factors are responsible for precipitation to occur at late-night in the central to eastern basin.     

Interannual variability of deep convection in the Northwestern Mediterranean simulated with a coupled AORCM

A hindcast experiment of the Mediterranean present-day climate is performed using a fully-coupled Atmosphere–Ocean Regional Climate Model (AORCM) for the Mediterranean basin. The new model, called LMDz-NEMO-Med, is composed of LMDz4-regional as atmospheric component and of NEMOMED8 as oceanic component. This AORCM equilibrates freely, without any flux adjustment, neither in fresh water nor in heat. At its atmospheric lateral boundary conditions, it is driven by ERA-40 data from 1958 to 2001, after a spin-up of 40 years in coupled configuration. The model performance is assessed and compared with available observational datasets. The model skill in reproducing mean state and inter-annual variability of main atmospheric and oceanic surface fields is in line with that of state-of-the-art AORCMs. Considering the ocean behaviour, the inter-annual variations of the basin-scale heat content are in very good agreement with the observations. The model results concerning salt content could not be adequately validated. High inter-annual variability of deep convection in the Gulf of Lion is simulated, with 53 % of convective winters, representative of the present climate state. The role of different factors influencing the deep convection and its inter-annual variability is examined, including dynamic and hydrostatic ocean preconditioning and atmospheric surface forcing. A conceptual framework is outlined and validated in linking the occurrence of deep convection to the efficiency of the integrated surface buoyancy fluxes along the winter season to mix the initially stratified averaged water column down to the convective threshold depth. This simple framework (based only on 2 independent variables) is able to explain 60 % (resp. 69 %) of inter-annual variability of the deep water formation rate (resp. maximum mixed layer depth) for the West Mediterranean Deep Water (WMDW) formation process.