Extensional Late Paleozoic deformation on the western margin of Pangea, Patlanoaya area, Acatlán Complex, southern Mexico

New mapping in the northern part of the Paleozoic Acatlán Complex (Patlanoaya area) records several ductile shear zones and brittle faults with normal kinematics (previously thought to be thrusts). These movement zones separate a variety of units that pass structurally upwards from: (i) blueschist-eclogitic metamorphic rocks (Piaxtla Suite) and mylonitic megacrystic granites (Columpio del Diablo granite ≡ Ordovician granites elsewhere in the complex); (ii) a gently E-dipping, listric, normal shear zone with top to the east kinematic indicators that formed under upper greenschist to lower amphibolite conditions; (iii) the Middle–Late Ordovician Las Minas quartzite (upper greenschist facies psammites with minor interbedded pelites intruded by mafic dikes and a leucogranite dike from the Columpio del Diablo granite) unconformably overlain by the Otate meta-arenite (lower greenschist facies psammites and pelites): roughly temporal equivalents are the Middle–Late Ordovician Mal Paso and Ojo de Agua units (interbedded metasandstone and slate, and metapelite and mafic minor intrusions, respectively) — some of these units are intruded by the massive, 461 ± 2 Ma, Palo Liso megacrystic granite: decussate, contact metamorphic muscovite yielded a ⁴⁰Ar/³⁹Ar plateau age of 440 ± 4 Ma; (iv) a steeply-moderately, E-dipping normal fault; (v) latest Devonian–Middle Permian sedimentary rocks (Patlanoaya Group: here elevated from formation status). The upward decrease in metamorphic grade is paralleled by a decrease in the number of penetrative fabrics, which varies from (i) three in the Piaxtla Suite, through (ii) two in the Las Minas unit (E-trending sheath folds deformed by NE-trending, subhorizontal folds with top to the southeast asymmetry, both associated with a solution cleavage), (iii) one in the Otate, Mal Paso, and Ojo de Agua units (steeply SE-dipping, NE–SW plunging, open-close folds), to (iv) none in the Patlanoaya Group. ⁴⁰Ar/³⁹Ar analyses of muscovite from the earliest cleavage in the Las Minas unit yielded a plateau age of 347 ± 3 Ma and show low temperature ages of  260 Ma. Post-dating all of these structures and the Patlanoaya Group are NE-plunging, subvertical folds and kink bands. An E–W, vertical normal fault juxtaposes the low-grade rocks against the Anacahuite amphibolite that is cut by megacrystic granite sheets, both of which were deformed by two penetrative fabrics. Amphibole from this unit has yielded a ⁴⁰Ar/³⁹Ar plateau age of 299 ± 6 Ma, which records cooling through  490 °C and is probably related to a Permo-Carboniferous reheating event during exhumation. The extensional deformation is inferred to have started in the latest Devonian ( 360 Ma) during deposition of the basal Patlanoaya Group, lasting through the rapid exhumation of the Piaxtla Suite at  350–340 Ma synchronous with cleavage development in the Las Minas unit, deposition of the Patlanoaya Group with active fault-related exhumation suggested by Mississippian and Early Permian conglomerates ( 340 and 300 Ma, respectively), and continuing at least into the Middle Permian (≡ 260 Ma muscovite ages). The continuity of Mid-Continent Mississippian fauna from the USA to southern Mexico suggests that this extensional deformation occurred on the western margin of Pangea after closure of the Rheic Ocean.     

U-Pb isotopic dating of zircons (SHRIMP-II) from granulites of the Ol’khon region of Western Baikal area

Doklady Earth Sciences -     

Patterns of urban settlements in Somalia

In this research paper attempts have been made to analyze the distribution of 68 urban settlements in 14 regions of the country. The value of near-neighbour statistic (R) shows nearly random pattern of urban settlements in some regions and approachingly uniform distribution of urban settlements in other regions. Regional distribution of urban settlements and their growth have been explained in context of region's geographical, economic and industrial frameworks.     

The concentration of molecular H2 and CH4 in the stratosphere

Stratospheric profiles of CH₄ and H₂ over eastern Texas have been derived up to 31 km altitude from air samples collected aboard a balloon and analyzed by gas chromatography. For H₂, contamination during flight and measurement presented a problem which has been resolved only recently. The earlier profiles require corrections which are rather large for the highest altitudes.The three profiles indicate an increase of the H₂ concentration in the lower stratosphere from about 0.5 p.p.m. per volume at the tropopause to about 0.8 p.p.m. at around 27 km altitude. Above that altitude the H₂ concentration decreases again. An air sample collected between 44 and 62 km by a rocket-borne cryogenic sampler had an H₂ concentration of 0.4 p.p.m.The five CH₄ profiles showed a decrease in CH₄ concentration with altitude generally with a steeper gradient directly above the tropopause and a weaker gradient at higher altitudes reaching 0.9 p.p.m. at 30 km altitude. The CH₄ concentration in the rocket sample was 0.25 p.p.m., in good agreement with the gradient obtained from the balloon samples.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Changes in current regime and turbidity in response to a freshwater pulse in the eastmain estuary

In September 1984, the freshwater input to the Eastmain River (James Bay, Canada) was increased by a factor of 50 over a 6-d period during a controlled reservoir discharge. Changes to the current, salinity and turbidity regimes were monitored during the peak runoff. Estuarine salinity values fell rapidly with increasing mean flow, as did the amplitude of the semi-diurnal tidal currents. A large increase in bottom shear stress dispersed the settled suspension layer into the water column, raising concentrations of suspended matter in the estuary by a factor of 4 in 3 d. The peak values exceeded 150 mg I^?1. This led to erosion of the river silt deposits, with the export of an estimated 6 × 10⁴ metric tons of sediments. After the reduction of discharge, current values returned to their normal range within a day, whereas upstream salinity intrusion occurred at a slower rate. Horizontal diffusivities of about 100 m² s^?1 were required to match the observed lag.     

Understanding the Spatial Variability of Chlorophyll a and Total Suspended Matter Distribution Along the Southwest Bay of Bengal Using In-Situ and OCM-2 & MODIS-Aqua Measurements

Spatial and temporal distribution of chlorophyll a (chl a) and Total Suspended Matter (TSM) and inter comparison of Ocean Color Monitor-2 (OCM-2) and Moderate Resolution Imaging Spectro-radiometer (MODIS-Aqua) derived chlorophyll a and TSM was made along the southwest Bay of Bengal (BoB). The in-situ chl a and TSM concentration measured during different seasons were ranged from 0.09 to 10.63 μgl^?1 and 11.04–43.75 mgl^?1 respectively. OCM-2 and MODIS derived chl a showed the maximum (6–8 μgl^?1) at nearshore waters and the minimum (0–1 μgl^?1) along the offshore waters. OCM-2 derived TSM imageries showed the maximum (50–60 mgl^?1) along the nearshore waters of Palk Strait and the moderate concentration (2–5 mgl^?1) was observed in the offshore waters. MODIS derived minimum TSM concentration (13.244 mgl^?1) was recorded along the offshore waters, while the maximum concentration of 15.78 mgl^?1 was found along the Kodiakarai region. The inter-comparison of OCM-2 and MODIS chl a data (R ² ?=?0.549, n?=?49, p?<?0.001, SEE?=?±0.117) indicate that MODIS data overestimates chl a concentration in the nearshore waters of the southern BoB compared to the OCM-2. The correlation between OCM-2 and MODIS-Aqua TSM data (R ² ?=?0.508, N?=?53, P?<?0.001 and SEE?=?±0.024) confirms that variation in the range of values measured by OCM-2 (2–60 mgl^?1) and the MODIS (13–16 mgl^?1) derived TSM values. Despite problems in range of measurements, persistent cloud cover etc., the launch of satellites like OCM-2 with relatively high spatial resolutions makes job easier and possible to monitor chl a distribution and sediment discharges on day to day basis in the southwest BoB.     

Major and trace element geochemistry of neutral and acidic thermal springs at El Chichón volcano,Mexico: Implications for monitoring of the volcanic activity

Four groups of thermal springs with temperatures from 50 to 80 °C are located on the S–SW–W slopes of El Chichón volcano, a composite dome-tephra edifice, which exploded in 1982 with a 1 km wide, 160 m deep crater left. Very dynamic thermal activity inside the crater (variations in chemistry and migration of pools and fumaroles, drastic changes in the crater lake volume and chemistry) contrasts with the stable behavior of the flank hot springs during the time of observations (1974–2005). All known groups of hot springs are located on the contact of the basement and volcanic edifice, and only on the W–SW–S slopes of the volcano at almost same elevations 600–650 m asl and less than 3 km of direct distance from the crater. Three groups of near-neutral (pH ≈ 6) springs at SW–S slopes have the total thermal water outflow rate higher than 300 l/s and are similar in composition. The fourth and farthest group on the western slope discharges acidic (pH ≈ 2) saline (10 g/kg of Cl) water with a much lower outflow rate (< 10 l/s).     

Timing effects on the fragmentation of small scale blocks of granodiorite

A series of small scale tests, simulating multi-hole blasts have been performed to establish the effect of delays on blast fragmentation. The blasts were performed in high quality granodiorite blocks, which were cut from stone prepared by dimensional stone quarry operations. The pattern used was equilateral triangular, with a distance of 10.2 cm between boreholes, which had a diameter of 11 mm, were loaded with detonating cord and the coupling medium was water. The delays used were achieved using different lengths of detonating cord for the cases of delays between 0 and 100 μs between holes and a sequential blasting machine firing seismic detonators for larger delays up to 4 ms. All fragments were collected and screened. The experiments showed that the worst fragmentation was achieved with simultaneous initiation of all charges. Fragmentation improved with the delay time between holes up to 1 ms between holes. If the experiments are scaled up, the results show that in granodiorite, fragmentation optimization requires delays of few milliseconds per metre of burden. The findings, agree with previously published work, involving larger scale experiments and other rock types.     

Geology of the volcanic-hosted Brockman rare-metals deposit,Halls Creek Mobile Zone,northwest Australia. l. Volcanic environment,geochronology and petrography of the Brockman volcanics

Summary Rare-metals mineralization of the Brockman deposit (Halls Creek Mobile Zone, NW Australia) is hosted in a fluorite-bearing, rhyolitic volcaniclastic unit informally termed the Niobium Tuff. The Tuff, more correctly described as a tuffaceous volcaniclastic deposit, is the lowermost unit of a sequence of trachyte-to-rhyolite lavas, trachyandesite subvolcanic rocks, and volcaniclastic units of the Brockman volcanics located within the Halls Creek Group, a thick, early Proterozoic volcano-sedimentary sequence. High precision SHRIMP ion-microprobe zircon dating of the Niobium Tuff gives an eruption age of 1870 ± 4 Ma. Regional geochronological constraints indicate the Niobium Tuff was deposited about 15 Ma before major orogenic activity affected the area. Despite folding, faulting and low-grade metamorphism, the Brockman volcanics show excellent preservation of primary volcanological features, including pillow-lavas and pillow-breccias, that suggest a dominantly subaqueous, below-wave-base emplacement environment. The style of eruption products and magma volume constraints suggest the trachyte-dominated volcanics were erupted from a small shield volcanic complex probably in a rift-related basin in a shallow-marine setting. The tectonic setting was intraplate but differs from most Tertiary to recent trachyte volcanic complexes which are largely subaerial, are built on relatively thick continental crust, and show no post-eruptive orogenic history. Brockman-style rare-metal deposits are characterized by preservation of subaqueous volcanics beneath a thick sedimentary sequence, eruption of early incompatible-element enriched products followed by less differentiated magmas, and fine-grained mineralogy influenced by alteration processes. Prospects exist for discovery of analogous deposits, particularly in early Proterozoic mobile belts and Tertiary intraplate shield volcanic provinces.

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Geologie der an Vulkanite gebundenen Seltene-Metalle-Lagerstätte Brockman, Halls Creek Mobile Zone, Nordwest-Australien. I. Vulkanologie, Geochronologie und Petrographie der Brockman-Vulkanite

Zusammenfassung Selten-Metall-Vererzung der Brockman-Lagerstätten (Halls Creek Mobile Zone, NW Australien) sitzt in einer Fluorit-führenden, rhyolitischen vulkanoklastischen Einheit auf, die informell als der Niob-Tuff bezeichnet wird. Es handelt sich hier um ein vulkanoklastisches Tuff-Sediment; dieses ist die unterste Einheit einer Abfolge vor Trachyt bis Rhyolit-Laven, trachyandesitischen Subvulkaniten and vulkanoklastischen Einheiten der Brockman Vulkanite innerhalb der Halls Creek Gruppe, einer mächtigen frühproterozoischen vulkanosedimentdren Abfolge. Prüzisionsdatierungen des Niob Tuffs mit der SHRIMP Ionen-Mikrosonde ergeben ein Eruptionsalter von 1870 +-4 Millionen Jahren. Regionale geochronologische Zusammenhänge zeigen, daß der Niob Tuff etwa 15 Millionen Jahre vor einer größeren Orogenese, die das Gebiet betroffen hat, abgelagert wurde. Trotz Faltung, Bruchtektonik and niedriggradiger Metamorphose zeigen die Brockman-Vulkanite einen hervorragenden Erhaltungszustand primärer vulkanologischer Erscheinungen. Diese urnfassen auch Kissenlaven und KissenBreckzien, die eine vorwiegend subaquatische Ablagerung in ruhigem Wasser erkennen lassen. Die Art der Eruptionsprodukte and das Magmavolumen zeigen, daß die Trachytdominierten Vulkanite von einem kleinen Schildvulkan stammer, wahrscheinlich in einem Becken in einer Rift-Situation im seichten marinen Milieu. Die tektonische Situation war intraplate, aber unterscheidet sich von den meisten tertiären bis rezenten trachytischen Vulkan-Komplexen, die hauptsächlich subaerisch sind, auf einer relativ mächtigen kontinentalen Kruste aufsitzen, and keine post-eruptive orogene Entwicklung zeigen. Seltene-Metalle-Lagerstatten des Brockman-Typs rind durch die Erhaltung subaquatischer-Vulkanite unterhalb einer machtigen sedimentdren Abfolge gekennzeichnet; welters durch frühe Eruptionsprodukte, die an inkompatiblen Elementen angereichert sind, auf die dann weniger differenzierte Magmen folgten, und schließlich durch einen feinkörnigen Mineralbestand, der vor Umwandlungsprozessen betroffen war. Es besteht die Möglichkeit der Entdeckung analoger Lagerstätten, besonders in frühproterozoischen mobilen Gürteln und in tertidren intraplate Schildvulkan Provinzen.

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