Nitrogen uptake and denitrification in restored and unrestored streams in urban Maryland, USA

There is growing interest in rates of nitrate uptake and denitrification in restored streams to better understand the effects of restoration on nitrogen processing. This study quantified nitrate uptake in two restored and two unrestored streams in Baltimore, Maryland, USA using nitrate additions, denitrification enzyme assays, and a ¹⁵N isotope tracer addition in one of the urban restored streams, Minebank Run. Restoration included either incorporation of stormwater ponds below a storm drain and catch basins to attenuate flow or hydrologic “reconnection” of a stream channel to its floodplain. Stream restoration was conducted for restoring aging sanitary and bridge infrastructure and introducing some stormwater management in watersheds developed prior to current regulations. Denitrification potential in sediments was variable across streams, whereas nitrate uptake length appeared to be significantly correlated to surface water velocity, which was low in the restored streams during summer baseflow conditions. Uptake length of NO₃ ⁻–N in Minebank Run estimated by ¹⁵N tracer addition was 556 m. Whole stream denitrification rates in Minebank Run were 153 mg NO₃ ⁻–N m⁻² day⁻¹, and approximately 40% of the daily load of nitrate was estimated to be removed via denitrification over a distance of 220.5 m in a stream reach designed to be hydrologically “connected” to its floodplain. Increased hydrologic residence time in Minebank Run during baseflow likely influenced rates of whole stream denitrification, suggesting that hydrologic residence time may be a key factor influencing N uptake and denitrification. Restoration approaches that increase hydrologic “connectivity” with hyporheic sediments and increase hydrologic residence time may be useful for stimulating denitrification. More work is necessary, however, to examine changes in denitrification rates in restored streams across different seasons, variable N loads, and in response to the “flashy” hydrologic flow conditions during storms common in urban streams.     

Isotopic and geochemical characterization of salinization in the shallow aquifers of a reclaimed subsiding zone: The southern Venice Lagoon coastland

The coastal plain bordering the southern Venice Lagoon is a reclaimed lowland characterized by high subsidence rate, and ground level and water-table depth below sea level. In this agricultural region, where the surface hydrologic network is entirely artificially controlled by irrigation/drainage canals, salinization problems have long been encountered in soils and groundwaters. Here we use isotopic and geochemical tracers to improve our understanding of the origin of salinization and mineralization of the semi-confined aquifer (0–40 m), and the freshwater inputs to this hydrological system. Water samples have been collected at different seasons in the coastal Adriatic Sea, lagoon, rivers and irrigation canals, as well as in the semi-confined aquifer at depths between 12 and 35 m (14 boreholes), and in the first confined aquifer (three boreholes drilled between 40 and 80 m depth). Stable isotopes (δ¹⁸O and δD) and conductivity profiles show that direct saline intrusion from the sea or the lagoon is observed only in a restricted coastal strip, while brackish groundwaters are found over the entire topographic and piezometric depression in the centre of the study area. Fresh groundwaters are found only in the most western zone. The sharp isotopic contrast between the western and central regions suggests disconnected hydrological circulations between these two parts of the shallow aquifer. The border between these two regions also corresponds to the limits of the most strongly subsiding zone.Our results can be interpreted in terms of a four end-member mixing scheme, involving (1) marine water from the lagoon or the open sea, (2) alpine and pre-alpine regional recharge waters carried either by the main rivers Adige, Bacchiglione and Brenta (irrigation waters) or by the regional groundwater circulation, (3) local precipitation, and (4) evaporated waters infiltrated from the surface. Infiltration from the surface is also revealed by the stratification of the electrical conductivity profiles, showing that the brackish groundwaters are overlain by a shallow layer of less saline water all over the central depression. In the first confined aquifer, the groundwaters have isotopic compositions similar to the deep groundwaters of the Venetian confined aquifers (40–400 m depth). The isotopic data and the Br/Cl ratio show that the origin of the salinization of the phreatic aquifer can be ascribed to seawater intrusion alone, with no indication of the involvement of deep brines (identified at 450 m depth) in the process.The chemical composition of the saline and brackish groundwaters is characterized by an excess of sodium and a deficit of calcium compared to conservative mixing between fresh groundwaters and seawater. This suggests that the phreatic aquifer is progressively freshening, as a consequence of the beneficial influence of the extensive irrigation/drainage network, including raised canals acting as a hydraulic barrier along the coast. This freshening tendency may have been lasting since the reclamation in the mid-twentieth century, and has probably been accelerated by the ban on groundwater abstraction since the 1970s.     

Microtopographic evolution of mineral surfaces as a tool to identify and date young fault scarps in bedrock

Faulting that results in surface ruptures through bedrock can be particularly difficult to date. For example, stratigraphic control on the age of faulting, based on the age of the bedrock, often leaves unacceptably large uncertainty on the age of the faulting. From a paleoseismological perspective, there is a clear need to determine if a bedrock fault scarp is actually a young feature. For young fault ruptures that create fresh mineral surfaces, analysis of microtopography developed by weathering of the mineral surface may provide a quantifiable method for determining the fault age. The direct quantitative measurement of mineral surface microtopography using Atomic Force Microscopy affords a novel method to study the rupture ages of active faults. The method for using microtopographic evolution of mineral surfaces depends on three conditions. The first condition is that freshly exposed mineral cleavage surfaces, which can be described geometrically as planes, are formed during a rupture event. The formation of these fresh surfaces is analogous to the initiation of a weathering ‘clock’ that defines time t=0. Following cleavage formation dissolution of the planar mineral surface occurs. The rate of dissolution for a mineral species under given climatic conditions, governs the rate of mineral surface alteration. Thus as dissolution proceeds, the roughness of the mineral surface increases. We suggest that the progression of microtopographic roughness over time, which can be estimated by computing quantitative statistics derived from digital mineral surface topography, will systematically vary until a steady state surface topography is reached. The fractal dimension, D_f, is one such measure of surface roughness where, D_f at time t=0 is 2. The dissolution of the mineral surface increases the fractal dimension as the removal of material proceeds. We posit that somewhere between D_f=2 and D_f=3, the microtopography reaches a steady state. Therefore, in the pre-steady state stage of surface roughness, the quantitative measure of roughness of the mineral may serve as a measure of time elapsed since faulting. The period of time this initial stage of surface roughening represents is dependent on the mineral and as a consequence, its dissolution rate, in a specific set of environmental conditions. The time elapsed since fault rupture and grain cleavage can also be estimated from the measurement of the volume of material removed through dissolution. If part of the original cleavage surface remains and can be identified then AFM measurements of the surface microtopography can be used to calculate the dissolved volume per unit area.     

Effects of mesoscale sea-surface temperature fronts on the marine atmospheric boundary layer

A numerical modelling study is presented focusing on the effects of mesoscale sea-surface temperature (SST) variability on surface fluxes and the marine atmospheric boundary-layer structure. A basic scenario is examined having two regions of SST anomaly with alternating warm/cold or cold/warm water regions. Conditions upstream from the anomaly region have SST values equal to the ambient atmosphere temperature, creating an upstream neutrally stratified boundary layer. Downstream from the anomaly region the SST is also set to the ambient atmosphere value. When the warm anomaly is upstream from the cold anomaly, the downstream boundary layer exhibits a more complex structure because of convective forcing and mixed layer deepening upstream from the cold anomaly. An internal boundary layer forms over the cold anomaly in this case, generating two distinct layers over the downstream region. When the cold anomaly is upstream from the warm anomaly, mixing over the warm anomaly quickly destroys the shallow cold layer, yielding a more uniform downstream boundary-layer vertical structure compared with the warm-to- cold case. Analysis of the momentum budget indicates that turbulent momentum flux divergence dominates the velocity field tendency, with pressure forcing accounting for only about 20% of the changes in momentum. Parameterization of surface fluxes and boundary-layer structure at these scales would be very difficult because of their dependence on subgrid-scale SST spatial order. Simulations of similar flow over smaller scale fronts (<5 km) suggest that small-scale SST variability might be parameterized in mesoscale models by relating the effective heat flux to the strength of the SST variance.     

Anasazi (Pre-Columbian Native-American) Migrations During The Middle-12Th and Late-13th Centuries – Were they Drought Induced?

Severe droughts in the middle-12th and late-13th centuries appear to have affected Anasazi (pre-Columbian Native American) populations. During the first drought most of the great houses in the central San Juan Basin were vacated; the second drought resulted in the abandonment of the Four Corners region. During the first drought, villages may not have been completely abandoned. The multi-year drought periods probably were characterized by reductions in both winter and summer precipitation. Maize is dependent on winter precipitation for its germination and initial growth and on summer (monsoonal) precipitation for its continued growth. Reductions in precipitation are hypothesized to have resulted in low yields of maize, the dietary staple of the Anasazi. A comparison of historic climate data and tree-ring-based reconstructions of precipitation in the Four Corners region with tree-ring-based reconstructions of the Pacific Decadal Oscillation (PDO) and the Atlantic Multidecadal Oscillation (AMO) indicate that severe and persistent drought in the Four Corners region occurs when the PDO is negative and the AMO is positive. Historic climate data from the greater San Juan Basin indicate that a negative PDO is characterized by reductions in both water-year and summer precipitation, reinforcing the concept that at least some multi-year droughts involved weakening of the summer monsoon with attendant decreases in the yields of maize.     

On the local multiscale determination of the Earth’s disturbing potential from discrete deflections of the vertical

As a first approximation, the Earth is a sphere; as a second approximation, it may be considered an ellipsoid of revolution. The deviations of the actual Earth’s gravity field from the ellipsoidal “normal” field are so small that they can be understood to be linear. The splitting of the Earth’s gravity field into a “normal” and a remaining small “disturbing” field considerably simplifies the problem of its determination. Under the assumption of an ellipsoidal Earth model, high observational accuracy is achievable only if the deviation (deflection of the vertical) of the physical plumb line, to which measurements refer, from the ellipsoidal normal is not ignored. Hence, the determination of the disturbing potential from known deflections of the vertical is a central problem of physical geodesy. In this paper, we propose a new, well-promising method for modelling the disturbing potential locally from the deflections of the vertical. Essential tools are integral formulae on the sphere based on Green’s function with respect to the Beltrami operator. The determination of the disturbing potential from deflections of the vertical is formulated as a multiscale procedure involving scale-dependent regularized versions of the surface gradient of the Green function. The modelling process is based on a multiscale framework by use of locally supported surface curl-free vector wavelets.      

1891–1883 Ma Southern Bastar–Cuddapah mafic igneous events, India: A newly recognized large igneous province

A newly recognized remnant of a Paleoproterozoic Large Igneous Province has been identified in the southern Bastar craton and nearby Cuddapah basin from the adjacent Dharwar craton, India. High precision U–Pb dates of 1891.1 ± 0.9 Ma (baddeleyite) and 1883.0 ± 1.4 Ma (baddeleyite and zircon) for two SE-trending mafic dykes from the BD2 dyke swarm, southern Bastar craton, and 1885.4 ± 3.1 Ma (baddeleyite) for a mafic sill from the Cuddapah basin, indicate the existence of 1891–1883 Ma mafic magmatism that spans an area of at least 90,000 km² in the south Indian shield.This record of 1.9 Ga mafic/ultramafic magmatism associated with concomitant intracontinental rifting and basin development preserved along much of the south-eastern margin of the south Indian shield is a widespread geologic phenomenon on Earth. Similar periods of intraplate mafic/ultramafic magmatism occur along the margin of the Superior craton in North America (1.88 Ga Molson large igneous province) and in southern Africa along the northern margin of the Kaapvaal craton (1.88–1.87 Ga dolerite sills intruding the Waterberg Group). Existing paleomagnetic data for the Molson and Waterberg 1.88 Ga large igneous provinces indicate that the Superior and Kalahari cratons were at similar paleolatitudes at 1.88 Ga but a paleocontinental reconstruction at this time involving these cratons is impeded by the lack of a robust geological pin such as a Limpopo-like 2.0 Ga deformation zone in the Superior Province. The widespread occurrence of 1.88 Ga intraplate and plate margin mafic magmatism and basin development in numerous Archean cratons worldwide likely reflects a period of global-scale mantle upwelling or enhanced mantle plume activity at this time.