Microtopographic evolution of mineral surfaces as a tool to identify and date young fault scarps in bedrock

Faulting that results in surface ruptures through bedrock can be particularly difficult to date. For example, stratigraphic control on the age of faulting, based on the age of the bedrock, often leaves unacceptably large uncertainty on the age of the faulting. From a paleoseismological perspective, there is a clear need to determine if a bedrock fault scarp is actually a young feature. For young fault ruptures that create fresh mineral surfaces, analysis of microtopography developed by weathering of the mineral surface may provide a quantifiable method for determining the fault age. The direct quantitative measurement of mineral surface microtopography using Atomic Force Microscopy affords a novel method to study the rupture ages of active faults. The method for using microtopographic evolution of mineral surfaces depends on three conditions. The first condition is that freshly exposed mineral cleavage surfaces, which can be described geometrically as planes, are formed during a rupture event. The formation of these fresh surfaces is analogous to the initiation of a weathering ‘clock’ that defines time t=0. Following cleavage formation dissolution of the planar mineral surface occurs. The rate of dissolution for a mineral species under given climatic conditions, governs the rate of mineral surface alteration. Thus as dissolution proceeds, the roughness of the mineral surface increases. We suggest that the progression of microtopographic roughness over time, which can be estimated by computing quantitative statistics derived from digital mineral surface topography, will systematically vary until a steady state surface topography is reached. The fractal dimension, D_f, is one such measure of surface roughness where, D_f at time t=0 is 2. The dissolution of the mineral surface increases the fractal dimension as the removal of material proceeds. We posit that somewhere between D_f=2 and D_f=3, the microtopography reaches a steady state. Therefore, in the pre-steady state stage of surface roughness, the quantitative measure of roughness of the mineral may serve as a measure of time elapsed since faulting. The period of time this initial stage of surface roughening represents is dependent on the mineral and as a consequence, its dissolution rate, in a specific set of environmental conditions. The time elapsed since fault rupture and grain cleavage can also be estimated from the measurement of the volume of material removed through dissolution. If part of the original cleavage surface remains and can be identified then AFM measurements of the surface microtopography can be used to calculate the dissolved volume per unit area.     

Development and application of a spatially‐distributed Arctic hydrological and thermal process model (ARHYTHM)

A process‐based, spatially distributed hydrological model was developed to quantitatively simulate the energy and mass transfer processes and their interactions within arctic regions (arctic hydrological and thermal model, ARHYTHM). The model first determines the flow direction in each element, the channel drainage network and the drainage area based upon the digital elevation data. Then it simulates various physical processes: including snow ablation, subsurface flow, overland flow and channel flow routing, soil thawing and evapotranspiration. The kinematic wave method is used for conducting overland flow and channel flow routing. The subsurface flow is simulated using the Darcian approach. The energy balance scheme was the primary approach used in energy‐related process simulations (snowmelt and evapotranspiration), although there are options to model snowmelt by the degree‐day method and evapotranspiration by the Priestley–Taylor equation. This hydrological model simulates the dynamic interactions of each of these processes and can predict spatially distributed snowmelt, soil moisture and evapotranspiration over a watershed at each time step as well as discharge in any specified channel(s). The model was applied to Imnavait watershed (about 2·2 km²) and the Upper Kuparuk River basin (about 146 km²) in northern Alaska. Simulated results of spatially distributed soil moisture content, discharge at gauging stations, snowpack ablations curves and other results yield reasonable agreement, both spatially and temporally, with available data sets such as SAR imagery‐generated soil moisture data and field measurements of snowpack ablation, and discharge data at selected points. The initial timing of simulated discharge does not compare well with the measured data during snowmelt periods mainly because the effect of snow damming on runoff was not considered in the model. Results from the application of this model demonstrate that spatially distributed models have the potential for improving our understanding of hydrology for certain settings. Finally, a critical component that led to the performance of this modelling is the coupling of the mass and energy processes. Copyright © 2000 John Wiley & Sons, Ltd.     

Pelagic tar off Georgia and Florida in relation to physical processes

Following the Ixtoc I oil rig blowout in Campeche Bay we hypothesized that resulting tarballs should eventually appear in the Gulf Stream off Gerogia and that because of dynamic barriers in the innershelf little would reach nearshore areas. To test these hypotheses, surface tows to collect floating tar were taken off the coasts of Georgia and Florida in October and December, 1979.No tar was found within 40 km of the shore. All samples more than 40 km offshore contained some tar. The mean concentration was 0.82 mg m^?2 with a range of 0.01–5.6 mg m^?2. Closely spaced sampling showed extreme variation but trends were consistent. Perylene was the most abundant compound in the tarballs.     

Seismicity and the subduction process

There is considerable variation between subduction zones in the largest characteristic earthquake within each zone. Assuming that coupling between downgoing and upper plates is directly related to characteristic earthquake size, we have tested for correlations between variation in coupling and other physical features of subduction zones: the lateral extent and penetration depth of Benioff zones, age of subducting lithosphere, convergence rate, and back-arc spreading. Using linear multivariate regression, coupling is correlated with two variables: convergence rate and lithosphere age. Secondary correlations within the data set are penetration depth versus lithosphere age, and lateral extent versus convergence rate. An important additional correlation is that back-arc spreading is found to be associated with subduction zones where coupling is low (those characterised by small earthquakes). Taken together, the observed correlations suggest a simple qualitative model where convergence rate and lithosphere age determine the horizontal and sinking rates, respectively, of slabs: these parameters influence the seismic coupling in the subduction zone. In the limit of a fast sinking rate and slow convergence rate, back-arc spreading occurs and thereby appears to be a passive process.     

Altitude variation of the plasmapause signature in the main ionospheric trough

The projection of the plasmapause magnetic-field lines to low altitudes, where the light-ion chemistry is dominated by O⁺, tends to occur near the minimum electron density in the main (midlatitude) electron density trough at night. With increasing altitude in the trough, where H⁺ emerges as the dominant ion on the low-latitude boundary, we have found cases where the plasmapause field lines are located on the sharp low-latitude side of the trough as expected if this topside ionosphere H⁺ distribution varies in step with the plasmapause gradient in the distant plasmasphere. These conclusions are based on near-equatorial crossings of the plasmapause (corresponding to the steep gradient in the dominant species H⁺) by the Explorer-45 satellite as determined from electric-field measurements by Maynard and Cauffman in the early 1970s and ISIS-2 ionospheric topside-sounder measurements. The former data have now been converted to digital form and made available at http://nssdcftp.gsfc.nasa.gov. The latter provide samples of nearly coincident observations of ionospheric main trough crossings near the same magnetic-field lines of the Explorer 45-determined equatorial plasmapause. The ISIS-2 vertical electron density profiles are used to infer where the F-region transitions from an O⁺ to a H⁺ dominated plasma through the main trough boundaries.     

Geochemical fractionation and ecological risks assessment of benthic sediment-bound heavy metals from coastal ecosystems off the Equatorial Atlantic Ocean

This study determines the pollution, fractionation, and ecological risks of sediment-bound heavy metals from coastal ecosystems off the Equatorial Atlantic Ocean. Contamination Factor(CF), pollution load index(PLI), and geoaccumulation index(Igeo) were used to assess the extent of the heavy metal pollution, while the potential ecological risk was evaluated using the risks assessment code(RAC) and Hkanson potential ecological risk. The analysis revealed concentrations(mg/g, dw) of the cadmium(Cd),chromium(Cr), copper(Cu), nickel(Ni), and lead(Pb) in sediments for wet and dry seasons vary from 4.40-5.08, 14.80-21.09. 35.03-44.8, 2.14-2.28, and 172.24-196.39, respectively. The results also showed that the metal fractionation percentages in the residual, oxidizable, and reducible fractions are the most significant, while the exchangeable and carbonate bound trace metals are relatively low. The RAC values indicate no risk for Cd and Ni and low risk for other metals at all the studied sites during both seasons.Potential ecological risk analysis of the heavy metal concentrations indicates that Cd had high individual potential ecological risk, while the other metals have low risk at all investigated sites. The multi-elemental potential ecological risk indices(R_1) indicate high ecological risk in all the ecosystems.     

Boundary frame contribution in coupled and uncoupled steel plate shear walls

The steel plate shear wall (SPSW) system is a robust option for earthquake resistance due to the strength, stiffness, ductility and energy dissipation that it provides. Although thin infill plates are efficient for resisting lateral loads, boundary frames that are proportioned based on capacity design requirements add significant structural weight that appears to be one of the factors limiting the use of the system in practice. An alternate configuration, the SPSW with coupling (SPSW‐WC), was explored recently as an option for increasing architectural flexibility while also improving overall system economy and seismic performance. The SPSW‐WC, which extensively employs flexural boundary frame contribution, has shown promise in analytical, numerical and experimental studies, but recent research on uncoupled SPSWs suggests that boundary frame contribution should not be considered for carrying seismic design shear. As a result, in the present study, boundary frame contribution in SPSWs was explored with detailed three‐dimensional finite element models, which were validated against large‐scale SPSW‐WC tests. Six‐story systems were considered, and the study matrix included single and double uncoupled SPSWs along with coupled SPSWs that had various degrees of coupling. Variations in design methodology were also explored. The modeling framework was employed to conduct static monotonic and cyclic pushover analyses and dynamic response history analysis. These analyses demonstrate the beneficial effect of coupling in SPSWs and illustrate the need to consider boundary frame contribution in design of coupled SPSWs. In addition, sharing design shear between the infill plate and the boundary frame is more generally shown to not be detrimental if this sharing is done in the design stage based on elastic analysis and the resulting boundary frame provides adequate secondary strength and stiffness following infill plate yielding. Copyright © 2017 John Wiley & Sons, Ltd.     

Methane-producing bacteria: natural fractionations of the stable carbon isotopes

The ${}^{13}\text{C}{}^{12}\text{C}$ fractionation factors ($\text{CO}{}_2\text{CH}{}_4$) for the reduction of CO₂ to CH₄ by pure cultures of methane-producing bacteria are, for Methanosarcina barkeri at 40°C, 1.045 ± 0.002; for Methanobacterium strain M.o.H. at 40°C, 1.061 ± 0.002; and, for Methanobacterium thermoautotrophicum at 65°C, 1.025 ± 0.002. These observations suggest that the acetic acid used by acetate dissimilating bacteria, if they play an important role in natural methane production, must have an intramolecular isotopic fractionation ($\text{CO}{}_2\text{H}\text{CH}{}_3$) approximating the observed $\text{CO}{}_2\text{CH}{}_4$ fractionation.     

Environmental tracers as indicators of karst conduits in groundwater in South Dakota,USA

Environmental tracers sampled from the carbonate Madison aquifer on the eastern flank of the Black Hills, South Dakota, USA indicated the approximate locations of four major karst conduits. Contamination issues are a major concern because these conduits are characterized by direct connections to sinking streams, high groundwater velocities, and proximity to public water supplies. Objectives of the study were to estimate approximate conduit locations and assess possible anthropogenic influences associated with conduits. Anomalies of young groundwater based on chlorofluorocarbons (CFCs), tritium, and electrical conductivity (EC) indicated fast moving, focused flow and thus the likely presence of conduits. δ¹⁸O was useful for determining sources of recharge for each conduit, and nitrate was a useful tracer for assessing flow paths for anthropogenic influences. Two of the four conduits terminate at or near a large spring complex. CFC apparent ages ranged from 15 years near conduits to >50 years in other areas. Nitrate-N concentrations >0.4 mg/L in groundwater were associated with each of the four conduits compared with concentrations ranging from <0.1 to 0.4 mg/L in other areas. These higher nitrate-N concentrations probably do not result from sinking streams but rather from other areas of infiltration.     

生态模型在河口管理中的应用研究综述

河口作为河流和海洋的交汇地,具有生态交错带特性,其在自然和人类活动双重压力下发生着演变.生态模型是研究生态系统结构、功能及其时空演变规律以及生物过程对于生态系统的影响及其反馈机制的重要手段.采用不同方法对生态模型进行分类,综述各类生态模型的特性、优缺点及应用领域.讨论建模过程中模型变量与函数、模型整合及时空尺度、模型参数取值及不确定等关键技术问题.分析各类生态模型在河口生态工程设计、生态系统修复、生态系统评价、系统决策支持等管理领域的应用.尽管中国河口生态模型构建及应用已有一些成果,但与国外相比,在理论生态学及数据积累方面仍有一定差距.