Secular variations of the upper crust composition: Implication of geochemical data on the Upper Precambrian shales from the Southern Urals western flank and Uchur-Maya region

In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean.     

Comparison of methods to model the gravitational gradients from topographic data bases

A number of methods have been developed over the last few decades to model the gravitational gradients using digital elevation data. All methods are based on second-order derivatives of the Newtonian mass integral for the gravitational potential. Foremost are algorithms that divide the topographic masses into prisms or more general polyhedra and sum the corresponding gradient contributions. Other methods are designed for computational speed and make use of the fast Fourier transform (FFT), require a regular rectangular grid of data, and yield gradients on the entire grid, but only at constant altitude. We add to these the ordinary numerical integration (in horizontal coordinates) of the gradient integrals. In total we compare two prism, two FFT and two ordinary numerical integration methods using 1" elevation data in two topographic regimes (rough and moderate terrain). Prism methods depend on the type of finite elements that are generated with the elevation data; in particular, alternative triangulations can yield significant differences in the gradients (up to tens of Eötvös). The FFT methods depend on a series development of the topographic heights, requiring terms up to 14th order in rough terrain; and, one popular method has significant bias errors (e.g. 13 Eötvös in the vertical–vertical gradient) embedded in its practical realization. The straightforward numerical integrations, whether on a rectangular or triangulated grid, yield sub-Eötvös differences in the gradients when compared to the other methods (except near the edges of the integration area) and they are as efficient computationally as the finite element methods.     

On two types of metalliferous carbonaceous rocks

Two types of metalliferous carbonaceous rocks that differ in associated metals are considered. One of them is characterized by gold occurring in finely dispersed arsenopyrite and arsenic-bearing pyrite, and the other, by finely impregnated native metals in carbonaceous matter. Rocks of the first type also contain elements of the platinum group, while those of the second type bear rhenium, silver, iron, molybdenum, and other metals. Graphitic mineralization is usually localized in the shear zone associated with alkaline basalts.