Research progress of TiO2 photocathodic protection to metals in marine environment

Corrosion protection has become an important issue as the amount of infrastructure construction in marine environment increased.Photocathodic protection is a promising method to reduce the corrosion of metals,and titanium dioxide(TiO_2) is the most widely used photoanode.This review summarizes the progress in TiO_2 photo gene rated protection in recent years.Different types of semiconductors,including sulfides,metals,metal oxide s,polymers,and other materials,are used to design and modify TiO_2.The strategy to dramatically improve the efficiency of photoactivity is proposed,and the mechanism is investigated in detail.Characterization methods are also introduced,including morphology testing,light absorption,photoelectrochemistry,and protected metal observation.This review aims to provide a comprehensive overview of Ti02 development and guide photocathodic protection.     

中国沿海海洋站GNSS坐标时间序列噪声模型的建立与分析

选取中国沿海海洋站中与验潮室并址的22个GNSS基准站近9 a的观测资料,利用最大似然估计法分析各站时间序列的噪声特性,建立最优噪声模型;然后顾及有色噪声,利用最优噪声模型估计测站速度,并与纯白噪声模型和GLOBK获取的速度及误差进行对比分析。结果表明：1）沿海海洋站的GNSS时间序列均含有有色噪声,各分量的噪声特性不完全一致,E方向和U分量均以白噪声+闪烁噪声为主,N分量以白噪声+闪烁噪声和白噪声+一阶马尔科夫噪声+随机漫步噪声为主。2）全国沿海3个海区N、E分量的白噪声和闪烁噪声基本呈现越往南噪声越大的规律,南海海区U分量的白噪声和闪烁噪声最大。3）顾及有色噪声的速度中误差是仅考虑白噪声和GLOBK估计的速度中误差估计值的5～10倍,这种差异比内陆观测站的要大。4）在对海洋站GNSS时间序列进行速度分析时,为获取正确的速度值,应该先准确判断噪声的类型,再顾及有色噪声的影响估计测站速度。     

滨海含水层胶体絮凝导致地层损害的实验研究

滨海含水层地层损害是指淡水驱替咸水过程中,释放后的黏土胶体发生絮凝沉降,导致地层孔隙被堵塞,引起含水介质的渗透性降低的现象。该文通过絮凝沉降实验和定流速砂柱实验,分析不同离子强度和阳离子价态(一价、二价)对胶体絮凝沉降的影响,结果表明:NaCl作为电解质时,絮凝发生的离子强度范围在0.032~0.034 mol/L之间,絮凝时间从82 min减少至39 min;而电解质为CaCl 2,离子强度为0.006 mol/L时,胶体的絮凝时间仅需6 min;钙钠比越高,黏粒絮凝发生的越快。砂柱实验结果显示,含水介质渗透性会随着电解质溶液的离子强度增加和阳离子价态的升高快速降低。当电解质为NaCl,离子强度分别为0.054 mol/L和0.017 mol/L时,含水介质渗透性降低20%所需时间分别为15 min和50 min;当电解质为CaCl2,离子强度为0.011 mol/L时,含水介质渗透性降低20%仅需5 min。因为高离子强度和高价阳离子可以加速胶体絮凝,多孔介质的孔吼更容易发生堵塞,研究成果对降低滨海含水层的地层损害有一定的实际应用价值。     

山东半岛海域成矿区带划分浅析

山东半岛海域成矿区带划分以往研究程度较低。该文利用海域重磁资料,在研究区梳理了渤海和黄海的重磁异常特征,渤海和北黄海呈负布格重力异常,南黄海北部与之相反;渤海为正磁异常,黄海与之相反。以重磁异常为基础,基于陆域构造单元划分,对海域构造单元划分至Ⅲ级10个构造单元,海域构造单元多为陆域向海域的延伸,仅渤中坳陷和北黄海盆地为独立的海域构造单元。参照陆域成矿区带划分,以构造单元边界为界线,海域成矿区带划分至Ⅳ级6个成矿区,各成矿区特征不同,坳陷构造单元内成矿区富集油气矿产,隆起构造单元内成矿区表现为埕宁隆起富集煤矿,胶北隆起富集金、菱镁矿、煤、灰岩矿,千里隆起富集岩金、蛇纹岩、石棉、花岗石矿。     

日照市海岸带海滩沉积物粒度特征及物源分析

根据日照市海岸带2个重点海滩所采集的样品,通过粒度、磁化率、主微量及稀土元素等方面的调查资料,综合分析了研究区沉积物类型、分布特征、搬运路径及物质来源。结果表明,研究区沉积物类型以砂为主,在平行海岸方向上,沉积物粒径自北至南由细变粗。在垂直海岸方向上,从滩肩到滩面再到低潮线处,沉积物粒径逐渐变细。海滨国家森林公园海滩的分选性要好于万平口海水浴场海滩。沉积物受黄海沿岸流影响,多自北向南运移。海滩中浅部物质的来源与陆内一侧基岩中斜长片麻岩和二长花岗岩的关系较为密切,深部物质的来源与靠海一侧基岩中花岗斑岩和花岗闪长岩的关系较为密切。     

Impacts of Increasing Model Resolutions and Shortening Forecast Lead Times on QPFs in South China During the Rainy Season

This study investigated the impacts of increasing model resolutions and shortening forecast lead times on the quantitative precipitation forecast(QPF) for heavy-rainfall events over south China during the rainy seasons in 2013–2020.The control experiment, where the analysis-forecast cycles run with model resolutions of about 3 km, was compared to a lower-resolution experiment with model resolutions of about 9 km, and a longer-term experiment activated 12 hours earlier. Rainfall forecasting in th...     

一种用于篡改定位及近似恢复的水印算法

针对遥感影像易被非法篡改的问题,提出了一种用于篡改定位及近似恢复的遥感影像半脆弱水印方案。首先将二值伪随机矩阵作为认证水印,通过量化Contourlet变换各方向子带中绝对值最大的系数将其嵌入,然后采用影像4×4分块后的灰度平均值作为恢复水印,将其嵌入到最低有效位。水印检测不需要原始遥感影像参与,实现了盲提取。实验结果表明,算法对于噪声、JPEG压缩等合理性失真具有一定的鲁棒性,而对于恶意篡改等攻击具有脆弱性,能够实现篡改区域的精确定位和近似恢复,使恢复后的遥感影像满足基本的视觉要求,可有效保护遥感影像的安全。     

无旋转倾角的NAV/CNAV型GEO广播星历拟合

目前北斗GEO的星历拟合算法和用户卫星位置算法均引进了人为设置的5°倾角旋转,此外,少数星历参数还有超限现象。取消GEO的旋转倾角和抑制参数超限能够统一北斗混合星座的用户算法。基于第一类无奇点根数,分析了无旋转倾角的GEO两步法星历参数拟合算法。讨论了GEO的参数超限原因,提出采用固定1至2个超限参数取值的缩减参数拟合法。北斗GEO卫星在非地影期和地影期的拟合试验表明,拟合成功率和拟合精度能够保证,拟合用户距离误差(URE)的平均值优于3mm;缩减参数拟合法能够抑制特定时段下的参数超限问题,但是拟合URE放大到2cm。     

云凝结核浓度对雷暴云电过程影响的数值模拟研究

本文将非感应起电机制耦合到WRF中尺度模式中,选取Morrison双参数微物理方案,采用整体放电参数化方案,改变初始云凝结核（CCN）浓度（浓度变化从500 cm-3到4000 cm-3）,共模拟15组试验,讨论了CCN浓度（n_CCN）对雷暴云起电强度的影响。通过研究发现:随n_CCN增加,霰粒子数浓度减少,混合比增加,导致霰粒子平均尺度增加;冰晶粒子数浓度增加,混合比基本不变,导致冰晶粒子平均尺度减小。此外,霰粒子平均尺度增大,下落末速度增大,冰晶粒子平均尺度减小,下落末速度减小,二者末速度差值增加,导致单次碰撞电荷分离量增加。综上所述,气溶胶浓度增加使霰粒子与冰晶粒子碰撞分离过程增强,单次碰撞电荷分离量增加,正负电荷密度平均值增加,从而增强雷暴起电强度。     

Developing the science product algorithm testbed for Chinese next-generation geostationary meteorological satellites: Fengyun-4 series

Fengyun-4A (FY-4A), the first of the Chinese next-generation geostationary meteorological satellites, launched in 2016, offers several advances over the FY-2: more spectral bands, faster imaging, and infrared hyperspectral measurements. To support the major objective of developing the prototypes of FY-4 science algorithms, two science product algorithm testbeds for imagers and sounders have been developed by the scientists in the FY-4 Algorithm Working Group (AWG). Both testbeds, written in FORTRAN and C programming languages for Linux or UNIX systems, have been tested successfully by using Intel/g compilers. Some important FY-4 science products, including cloud mask, cloud properties, and temperature profiles, have been retrieved successfully through using a proxy imager, Himawari-8/Advanced Himawari Imager (AHI), and sounder data, obtained from the Atmospheric InfraRed Sounder, thus demonstrating their robustness. In addition, in early 2016, the FY-4 AWG was developed based on the imager testbed—a near real-time processing system for Himawari-8/AHI data for use by Chinese weather forecasters. Consequently, robust and flexible science product algorithm testbeds have provided essential and productive tools for popularizing FY-4 data and developing substantial improvements in FY-4 products.