岩藻黄素纳米复合物的制备及抗氧化、抗肿瘤活性研究

岩藻黄素是一种脂溶性类胡萝卜素,由于其水溶性差、环境敏感性强,使其应用受到限制。本研究采用有机溶剂浸提、大孔树脂纯化法,从裙带菜中提取高纯度岩藻黄素。通过复凝聚反应制备乳清分离蛋白-岩藻黄素-阿拉伯胶纳米复合物。通过透射电镜观察,纳米复合物呈光滑的球形,粒径约为44nm。红外光谱则表明,岩藻黄素与乳清分离蛋白、阿拉伯树胶发生相互作用,导致联烯键、乙酰基等特征吸收峰被遮蔽。与单一岩藻黄素相比,纳米包封的岩藻黄素具有较好的抗氧化活性稳定性。抗肿瘤实验表明,纳米复合物保留了岩藻黄素抑制HT29细胞增殖的生物活性。     

Rock Mass Characteristics in Beishan, A Preselected Area for China’s High-Level Radioactive Waste Disposal

Geological and hydrological characteristics, joint geometric features, rock physical and mechanical properties and rock mass quality are studied in the Beishan area, preselected for China’s high-level radioactive waste (HLW) disposal engineering. A comprehensive survey method is developed to study joint geometric features in the outcrop and samples from borehole BS06 into the Xinchang rock mass were tested. The optimal joint sets are determined by rose diagrams and equal-area lower hemisphere plots of joint poles. Results show that: 1) the distribution of joint occurrence obeys a normal distribution, while the distribution of joint spacing obeys a negative exponential distribution; 2) concentric circular and tangent circular sampling windows are applied to study the trace length and the trace midpoint density. Results indicate that tangent circular sampling window is more stable and reasonable; 3) Beishan granite shows high density, low porosity and high strength based on many laboratory tests and the physical properties and mechanical properties are closely related; and 4) a synthesis index, Joint Structure Rating (JSR), is applied to evaluate the quality of rock mass. Through the research results of rock mass characteristics, the Xinchang rock mass in the Beishan preselected area has the favorable conditions for China’s HLW disposal repository site.     

SHRIMP U-Pb zircon age,geochemistry and Nd isotope of the Guandaoshan pluton in SW Sichuan: Petrogenesis and tectonic significance

SHRIMP U-Pb zircon age, geochemical and Nd isotopic data are reported for the Neo-proterozoic Guandaoshan pluton in the Yanbian region, SW Sichuan. This pluton is of typical I-type granite and emplaced at (857 ± 13) Ma. Geochemical and Nd isotopic characters suggest that the pluton was generated by partial melting of pre-existing, young (late Mesoproterozoic to early Neo-proterozoic) low-K tholeiitic protolith within an intraplate anorogenic setting. The Guandaoshan pluton probably records the earliest magmatism induced by the proposed ca. 860–750 Ma mantle superplume beneath the supercontinent Rodinia.     

MAPGIS投影变换子系统的应用

介绍了利用MAPGIS投影变换子系统对地质勘查成果图件进行投影转换的方法步骤,同时用实例说明了不同坐标系之间投影转换过程中的参数选择,对计算机制图具有一定的借鉴作用。     

长白山圆池泥炭氮元素分布特征及其影响因素分析

通过对长白山圆池4个泥炭剖面样品的分析,揭示了其氮元素分布规律。在圆池选取4个具有代表性的采样点,利用泥炭采样器采取新鲜泥炭样品。分析结果表明,4个泥炭剖面氮元素含量在0.014%~3.353%之间;剖面间相比较,其中贫营养泥炭整体含氮量较低;4个泥炭剖面的氮元素分布呈现明显规律,受泥炭上层不同植物、泥炭水分和有机质含量等因素的影响,泥炭剖面中氮元素累积峰可能出现在剖面的表层(0~5cm)或中间层(10~20cm);泥炭剖面氮元素与有机质呈极显著的正相关;泥炭剖面C/N比值变化在9.51~66.98之间,部分剖面层位C/N比值异常高,表明该层位碳的累积速度显著高于氮元素。     

湖北省夏季不同阶段强降水及其大气低频特征

利用1961-2014年湖北省68站逐日降水资料和美国国家海洋和大气管理局环流资料,对比分析了湖北省夏季梅雨期和盛夏期低频强降水事件的基本特征、大气环流形势和低频信号传播特征。结果表明:(1)湖北省夏季降水存在显著的准双周低频周期。(2)相较于盛夏期,梅雨期低频强降水事件次数多,强度强。(3)梅雨期和盛夏期低频强降水事件发生期间的环流形势有着显著的差异。梅雨期,对流层中层东亚沿岸为南北向的波列分布,低层受强索马里越赤道气流和副热带高压外围西南气流共同影响,水汽条件好,东亚存在鞍型场,流场变形,利于形成中尺度气旋系统;盛夏期,对流层中层为欧亚波列分布,低层索马里越赤道气流弱,主要受副热带高压外围水汽输送的影响,日本海以西地区有一异常气旋,其西侧的偏北气流与暖湿气流在30°N附近交汇维持。(4)在强降水事件发生前后,对流层低层的低频正涡度传播特征有较大差异,在梅雨期表现为驻波特征,盛夏期传播更为明显,表现为向西、向南向北传播。     

2015—2019年辽宁省暴雨红色预警信号分布及其特征

利用2015—2019年辽宁省发布的暴雨红色预警信号和1605个自动站的分钟级降水资料,统计暴雨红色预警信号和短时大暴雨年际变化和时空分布,分析暴雨红色预警信号的高分布区、易发时段。结果表明：2015—2017年辽宁省暴雨红色预警信号发布站数逐年递增,最大值出现在2017年,发布站数为147个;2015—2018年预警信号准确率提升,提前时间略减少,最低值为2018年,提前时间为19 min;2019年比2018年暴雨红色预警信号发布站数减少59个,提前时间增加29 min;暴雨红色预警信号的空间分布为东南部地区多、中部地区少;暴雨红色预警信号多在夜间发布;在辽宁省发布的50%以上的暴雨红色预警信号中,降水量达到预警发布标准的时间滞后于最大雨强出现时间90 min,最大雨强出现时间为暴雨红色预警信号发布的重要指标。为了达到防灾减灾的服务效果,发布暴雨红色预警信号时,应充分考虑最大雨强出现时间、发布时机、短时大暴雨高发区及地形的影响。     

Characterization of shale matrix pore structure via experiment and model

Shale gas reservoirs develop multi-scale pores ranging in size from nanometer to micrometer, the characteristics of gas transport involve the multi-scale pore space which divided into organic and inorganic matrix pores. This paper reveals the shale pore structure with large amounts of organic mesoporous based on the techniques of focused ion beam scanning electron microscopes (FIB-SEM), high-pressure mercury intrusion (MICP), and low-pressure adsorption (LPA), which also shows the size and distribution of these pores. Then the research characterizes effective pore scale via circular tube bundle model with due regard for gas adsorption layer thickness on the walls of organic pores and water film thickness on the walls of inorganic pores, and the investigation of shale pore geometry is significant for designing and developing shale gas reservoirs. This work shows that the widely existing shale mesoporous volume with diameter of 2~50 nm accounts for 81% based on experimental testing, then it reduces to about 76% via effective diameter model calculation.     

2007年度华东区地震应急协作联动演练现场通信环境的组建

2007年度华东区进行了地震应急协作联动演练,针对演练途中、前沿指挥部、演练指挥部以及后方指挥中心之间的通信提出了相应的解决方案．并分别介绍了解决方案的系统组成、运用方式和使用结果。提出了现场通信组在演练中暴露的问题及相应的解决思路。     

Phase Equilibria Constraints on Relations of Ore-bearing Intrusionswith Flood Basalts in the Panxi Region, Southwestern China

There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province (LIP); namely, small uitramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element (PGE)-bearing sulfide deposits and large mafic layered intrusions that host giant Ti-V magnetite deposits in the Panxi region. However, except for their coeval ages, the genetic relations between the ore-bearing intrusions and extrusive rocks are poorly understood. Phase equilibria analysis (Q-PI-OI-Opx-Cpx system) has been carried out to elucidate whether ore-bearing Panzhihua, Xinjie and Limahe intrusions are co-magmatic with the picrites and flood basalts (including high-Ti, low-Ti and alkali basalts), respectively. In this system, the parental magma can be classified as silica-undersaturated olivine basalt and silica-saturated tholeiite. The equivalents of the parental magma of the Xinjie and Limahe peridotites and picrites and iow-Ti basalts are silica-undersaturated, whereas the Limahe gabbro-diorites and high-Ti basalts are silica-saturated. In contrast, the Panzhihua intrusion appears to be alkali character. Phase equilibria relations clearly show that the magmas that formed the Panzhihua intrusion and high-Ti basalts cannot be co-magmatic as there is no way to derive one liquid from another by fractional crystallization. On the other hand, the Panzhihua intrusion appears to be related to Permian alkali intrusions in the region, but does not appear to be related to the alkali basalts recognized in the Longzhoushan lava stratigraphy. Comparably, the Limabe intrusion appears to be a genetic relation to the picrites, whereas the Xinjie intrusion may be genetically related to be low-Ti basaits. Additionally, the gabbro-diorites and peridotites of the Limahe intrusion are not co-magmatic, and the former appears to be derived liquid from high-Ti basalts.