Initial responses of carbonate-rich shelf sediments to rising atmospheric pCO2 and “ocean acidification”: Role of high Mg-calcites

Carbonate-rich sediments at shoal to shelf depths (<200 m) represent a major CaCO₃ reservoir that can rapidly react to the decreasing saturation state of seawater with respect to carbonate minerals, produced by the increasing partial pressure of atmospheric carbon dioxide (pCO₂) and “acidification” of ocean waters. Aragonite is usually the most abundant carbonate mineral in these sediments. However, the second most abundant (typically ∼24 wt%) carbonate mineral is high Mg-calcite (Mg-calcite) whose solubility can exceed that of aragonite making it the “first responder” to the decreasing saturation state of seawater. For the naturally occurring biogenic Mg-calcites, dissolution experiments have been used to predict their “stoichiometric solubilities” as a function of mol% MgCO₃. The only valid relationship that one can provisionally use for the metastable stabilities for Mg-calcite based on composition is that for the synthetically produced phases where metastable equilibrium has been achieved from both under- and over-saturation. Biogenic Mg-calcites exhibit a large offset in solubility from that of abiotic Mg-calcite and can also exhibit a wide range of solubilities for biogenic Mg-calcites of similar Mg content. This indicates that factors other than the Mg content can influence the solubility of these mineral phases. Thus, it is necessary to turn to observations of natural sediments where changes in the saturation state of surrounding waters occur in order to determine their likely responses to the changing saturation state in upper oceanic waters brought on by increasing pCO₂. In the present study, we investigate the responses of Mg-calcites to rising pCO₂ and “ocean acidification” by means of a simple numerical model based on the experimental range of biogenic Mg-calcite solubilities as a function of Mg content in order to bracket the behavior of the most abundant Mg-calcite phases in the natural environment. In addition, observational data from Bermuda and the Great Bahama Bank are also presented in order to project future responses of these minerals. The numerical simulations suggest that Mg-calcite minerals will respond to rising pCO₂ by sequential dissolution according to mineral stability, progressively leading to removal of the more soluble phases until the least soluble phases remain. These results are confirmed by laboratory experiments and observations from Bermuda. As a consequence of continuous increases in atmospheric CO₂ from burning of fossil fuels, the average composition of contemporary carbonate sediments could change, i.e., the average Mg content in the sediments may slowly decrease. Furthermore, evidence from the Great Bahama Bank indicates that the amount of abiotic carbonate production is likely to decline as pCO₂ continues to rise.     

Electron oscillations in the induced martian magnetosphere

The Analyzer of Space Plasmas and Energetic Atoms (ASPERA-3) experiment flown on the Mars Express (MEX) spacecraft includes the Electron Spectrometer (ELS) as part of its complement. The ELS instrument measures the differential electron flux spectrum in a 128-level logarithmic energy sweep within a time period of 4 s. The orbital path of MEX traverses the martian sheath, cusps, and tail where ELS recorded periodic electron intensity oscillations. These oscillations comprised periodic variations of up to an order of magnitude (peak to valley) in energy flux, with the largest amplitudes in the tens to hundreds of eV range. The observed oscillations displayed periods ranging from minutes down to the instrument sweep resolution of 4 s. In the cases analyzed here, the frequency of the integrated electron energy flux typically peaked between 0.01 and 0.02 Hz. This frequency range is nearly the same as the typical O⁺ gyrofrequency in the magnetosheath, calculated using magnetometer data from Mars Global Surveyor. Due to the motion of the spacecraft, it is unclear if the wave structures observed were permanent standing waves or rather constituted waves propagating past the spacecraft.     

Snow density variations: consequences for ground‐penetrating radar

Reliable hydrological forecasts of snowmelt runoff are of major importance for many areas. Ground‐penetrating radar (GPR) measurements are used to assess snowpack water equivalent for planning of hydropower production in northern Sweden. The travel time of the radar pulse through the snow cover is recorded and converted to snow water equivalent (SWE) using a constant snowpack mean density from the drainage basin studied. In this paper we improve the method to estimate SWE by introducing a depth‐dependent snowpack density. We used 6 years measurements of peak snow depth and snowpack mean density at 11 locations in the Swedish mountains. The original method systematically overestimates the SWE at shallow depths (+25% for 0·5 m) and underestimates the SWE at large depths (?35% for 2·0 m). A large improvement was obtained by introducing a depth–density relation based on average conditions for several years, whereas refining this by using separate relations for individual years yielded a smaller improvement. The SWE estimates were substantially improved for thick snow covers, reducing the average error from 162 ± 23 mm to 53 ± 10 mm for depth range 1·2–2·0 m. Consequently, the introduction of a depth‐dependent snow density yields substantial improvements of the accuracy in SWE values calculated from GPR data. Copyright © 2005 John Wiley & Sons, Ltd.     

Segregation and Urban Unrest in Sweden

In 2009, Sweden experienced a wave of urban unrest concentrated in areas with large foreign-born populations. This episode was seen by many as reflecting a trend towards increased ethnically based residential segregation, in line with scholarly literatures that correlate inequality and rising segregation with increases in unrest or rebellion. In this paper, we analyze the empirical connection between ethnic residential segregation and episodes of urban unrest in Sweden. Unrest is measured by the number of car burnings reported to police between 2002 and 2009. We find a positive and statistically significant link between residential segregation and car burnings at the scale of municipalities and metropolitan districts. Unrest/rebellion is also correlated with high proportion of young adults and social welfare assistance.     

Spatial and seasonal variations of fish assemblages in mangrove creek systems in Zanzibar (Tanzania)

Spatial and seasonal variations of fish assemblage composition were studied in three non-estuarine mangrove creeks of Zanzibar (Tanzania). Fish were collected monthly for one year at three sites (lower, intermediate and upper reaches) in each creek using a seine net (each haul covering 170 m²). Density, species number and diversity of fish were all higher at sites with dense cover of macrophytes (seagrass and macroalgae) than over unvegetated sandy sites. In general, fish assemblages mainly comprised juveniles of a few abundant taxa, e.g. Mugil cephalus, Mugilidae spp. and Leiognathus equulus at sites with mud substratum and Gerres oyena, Lethrinus harak and Sillago sihama at sites dominated by macrophytes. Multivariate analyses revealed significant separations in fish assemblage composition within the two creeks where the bottom substratum differed among sites. Overall, season seemed to have little effect on density, species number, diversity index (H′) and assemblage structure of fish. Water condition variables were also relatively stable across the season, although a short-term fluctuation primarily induced by decreased salinity, occurred during the heavy rains in April and May. Fish assemblage structure was not significantly affected by any of the abiotic factors tested. However, significant regressions were found between the other fish variables and environmental variables, but since these associations were mostly species-specific and generally inconsistent, we suggest that the overall distribution patterns of fish were mainly an effect of particular substrate preferences of fish species rather than contemporary water conditions.