Does sedimentary organic delta 13C record variations in quaternary ocean [CO2(aq)]?

Ocean surface water [CO2(aq)] variations based on glacial/interglacial changes in sediment delta 13Corg are shown to compare favorably with reconstructions based on ice core [CO2]. In particular, an approximate 80 microatmospheres increase in atmospheric pCO2 during the last glacial-interglacial transition is calculated to correspond to a 3-4 micromolar increase in ocean surface water [CO2(aq)] at atmospheric equilibrium. A widespread marine delta 13Corg decrease of 1-2% accompanied this event and was not preceded by an equivalent isotopic change in surface water total dissolved inorganic carbon. These observations support the hypothesis that [CO2(aq)] influences photosynthetic isotope fractionation between marine inorganic and organic carbon pools, and therefore that plankton/sediment delta 13Corg may serve as a proxy for surface water [CO2(aq)].     

Netplankton Chlorophyll Biomass along 175°E in the Pacific Ocean

An analysis is presented of data on chlorophyll a concentrations of the total and the netplankton (>10 μm), determined either in April to June or in August to September from 48°N to 15°S along 175°E in the Pacific Ocean during 6 years by the NOPACCS (Northwest Pacific Carbon Cycle Study). Particular attention was given to the variability of absolute concentrations of the netplankton chlorophyll a and their percentage shares of the total chlorophyll a concentration. Below 0.2 μg l⁻¹ of surface total chlorophyll a, the netplankton chlorophyll a showed low percentage shares (such as 12.7% on average) with a large variation, but above 0.2 μg l⁻¹ it was 35.9% on average with less variation, showing an accelerated increase at high total chlorophyll a concentrations. High netplankton chlorophyll a concentrations in surface waters were observed at high latitudes, in waters having high chlorophyll a concentrations at sub-surface depth, and in equatorial upwelling. The percentage shares of netplankton in the total chlorophyll a in the euphotic zone were 8.5% and 25.9% above and below 0.2 μg l⁻¹, respectively, although the data points scattered over a wide range (from 7.2% to 53.8%) depending on differences in water masses, depths and seasons. High chlorophyll a concentrations and high percentage shares of netplankton corresponded to high ambient nitrate plus nitrite concentrations. Integrated netplankton chlorophyll a concentrations in the euphotic zone varied from 0.7 to 19.5 mg m⁻² in waters below 0.2 μg l⁻¹ of surface total chlorophyll a, and from 2.0 to 29.5 mg m⁻² above 0.2 μg l⁻¹, and the percentage shares of netplankton for the former were 7.4% on average and 23.7% for the latter. This revised version was published online in July 2006 with corrections to the Cover Date.     

Toronto’s Little Portugal: gentrification and social relations among local entrepreneurs

This article clarifies neighborhood politics in Toronto’s Little Portugal Business Improvement Area (BIA), an ethnic neighborhood facing gentrification, by focusing on local entrepreneurs and the social relations among them. In the BIA, non-Portuguese businesses have replaced Portuguese businesses in the past decade; Portuguese and non-Portuguese entrepreneurs are now found in almost the same numbers. I visualized their social relations by using a diagram called a sociogram. Portuguese and non-Portuguese entrepreneurs are spatially inseparable but socially divided in the neighborhood. The BIA board, an organization for community development spearheaded by local entrepreneurs and property owners, has become predominantly non-Portuguese. The social relations among non-Portuguese entrepreneurs affect and are affected by the activities of this organization. While the Portuguese community could potentially mount resistance by mobilizing the collective power of the provincial ethnic alliance, the BIA is a form of quasi-government in Little Portugal; hence, the Portuguese community may have limited options for such resistance.     

Simplified technique for the rapid determination of phytoplankton pigments by reverse-phase high-performance liquid chromatography

A simplified technique for the rapid analysis of photosynthetic pigments in marine phytoplankton is described. The pigments extracted in N,N-dimethylformamide (DMF) are injected directly into the reverse-phase high-performance liquid chromatograph fitted with a photodiode array detector. We developed a new stepwise program; that is methanol-water (7525 v/v), methanol, methanol-acetone (8020) and methanol-acetone (6535). This program gives a good separation of at least 13 carotenoids, and 10 chlorophylls and their derivatives, completed within 20 min. The quantitative precision is high; the maximum standard error was less than 6%. The stability of pigments in DMF were also considered for application of this technique to the lab work on board the ship.     

Chlorophyll distribution and photosynthetic activity in the north and equatorial Pacific Ocean along 155°W

The distribution of chlorophylla and photosynthetic characterestics of phytoplankters were investigated along 155°W between 50°N and 15°S during the KH-69-4 cruise of the R. V. Hakuh Maru (Aug. 12–Nov. 13, 1969). High concentrations of chlorophylla (more than 0.2 mg Chla/m³) were observed above the depths of 150 m at all stations except in 17°N, 5°S and 15°S. North of 20°N, the depths of chlorophyll accumulation shifted from near the surface to 50–100 m with southwards. In the equatorial region, chlorophyll accumulation centered at a depth of about 70 m and ranged vertically between 10 and 150 m. In all cases in the present study area, chlorophyll accumulation occurred within the euphotic zone (above the depth corresponding to 1% of the surface illumination), and except in the subarctic and some equatorial waters, this was usually prevalent in the lower half of the euphotic zone.The photosynthetic activities (initial slope of P vs I curve) of samples from the depths of chlorophyll accumulation were similar to, or lower than, those of shallow samples from the depths of upper half of the euphotic zone. At the depths of chlorophyll accumulation, calculatedin situ photosynthesis was high in the central Pacific and equatorial waters but low in the subarctic waters.     

Suzaku observations of iron lines and reflection in AGN

Initial results on the iron K‐shell line and reflection component in several AGN observed as part of the Suzaku Guaranteed Time program are reviewed. This paper discusses a small sample of Compton‐thin Seyferts observed to date with Suzaku; namely MCG‐5‐23‐16, MCG‐6‐30‐15, NGC4051, NGC3516, NGC2110, 3C 120 and NGC2992. The broad iron Kα emission line appears to be present in all but one of these Seyfert galaxies, while the narrow core of the line from distant matter is ubiquitous in all the observations. The iron line in MCG‐6‐30‐15 shows the most extreme relativistic blurring of all the objects, the red‐wing of the line requires the inner accretion disk to extend inwards to within 2.2R _g of the black hole, in agreement with the XMM‐Newton observations. Strong excess emission in the Hard X‐ray Detector (HXD) above 10 keV is observed in many of these Seyfert galaxies, consistent with the presence of a reflection component from reprocessing in Compton‐thick matter (e.g. the accretion disk). Only one Seyfert galaxy (NGC 2110) shows neither a broad iron line nor a reflection component. The spectral variability of MCG‐6‐30‐15, MCG‐5‐23‐16 and NGC 4051 is also discussed. In all 3 cases, the spectra appear harder when the source is fainter, while there is little variability of the iron line or reflection component with source flux. This agrees with a simple two component spectral model, whereby the variable emission is the primary power‐law, while the iron line and reflection component remain relatively constant. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Biogenic opal production changes during the Mid-Pleistocene Transition in the Bering Sea (IODP Expedition 323 Site U1343)

Biogenic opal content and mass accumulation rate (MAR) at IODP Expedition 323 Site U1343 were found to fluctuate consistently, generally being high under warm conditions and low under cold conditions during the last 2.4 Ma. Continuous wavelet transform analysis of the normalized biogenic opal content indicates that export production in the Bering Sea varied predominantly at 41-ka periodicity before 1.25 Ma, and shifted to 100-ka periodicity at the onset of the Mid-Pleistocene Transition (MPT; 1.25–0.7 Ma). The 100-ka cycles dominated until the Holocene. Export production in the Bering Sea decreased markedly in the Bering Sea two times during the MPT: the first occurred at the beginning of the MPT (1.25 Ma) and the second in the middle of the MPT (0.9 Ma). These decreases coincided with both increases in the relative abundance of sea-ice diatoms and decreases in the warm-water diatom species Neodenticula seminae, indicating that reductions in export production in the Bering Sea during the MPT were associated with climate cooling. Decreases in export production in the Bering Sea during the MPT were most likely associated with the increased influence of polar/Arctic domains on the high-latitude North Pacific.