Behavior of polycyclic aromatic hydrocarbons at impact shock: Its implication for survival of organic materials delivered to the early Earth

Polycyclic aromatic hydrocarbons (PAHs) with a hydrous or an unhydrous mineral matrix were impacted and analyzed, to study the behavior of PAHs against shock. Results of the shock experiments suggested that volatiles discharged from the hydrous mineral did not influence the behavior of PAHs against shock. The shocked samples contained unreacted starting PAHs, soot-like materials insoluble in dichloromethane, and secondarily formed PAHs with molecular weights ranging from 128 to 404. Approximately 95% of starting PAHs decomposed at ∼30 GPa and the dominant product was the soot-like materials. Formation mechanisms of the shock products were explained by reaction processes under static high pressure-temperature conditions (e.g., carbonization, radical addition reaction, ring cross linking, and methylation).We applied these results to estimate the survival degree of organic matter delivered by carbonaceous asteroids against their impact pressures at the accretion stage of early Earth. If we use a simplified homogeneous accretion model without atmosphere to represent the stage, the radius of Earth causing 30 GPa, the pressure at which PAHs almost decompose, was calculated as 2270 km (4.0 km s⁻¹ of impact velocity) for the impact of carbonaceous asteroids. In the case of impactors striking not land but oceans on the early Earth, the impact velocity for the decomposition of PAHs was estimated to be 6.0 km s⁻¹. These impact velocities should have been commonly realized on the early Earth, due to the airburst and the aerobreak of impactors in the dense atmosphere. The early Earth should have been a favorable environment for obtaining and maintaining a large quantity of prebiotic organic materials leading to life.     

Size distributions of aerosol number concentrations and water-soluble constituents in Toyama, Japan: A comparison of the measurements during Asian dust period with non-dust period

Size-separated aerosol number concentrations and water-soluble constituents were measured in Toyama, the Hokuriku district, near the coast of the Japan Sea, during the spring and summer in 2003. The number concentrations of coarse particles were significantly high in April, which was due to Asian dust events called Kosa in Japanese. Particulate nssCa²⁺, which is mostly present in the coarse-mode particles, was significantly high in April. On the other hand, the concentrations of NH₄⁺ and nssSO₄²⁻, which mainly exist as the accumulation-mode particles were not high in April. The mass-size distributions of water-soluble constituents were compared with the size-separated number concentrations of particles. Backward trajectory analysis was also employed to examine the transport process of the air mass in Toyama.     

ULF waves: 1997 IAGA division 3 reporter review

Highlights of studies of ULF waves from 1995 to early 1997 are presented. The subjects covered include (1) Pc 3–5 waves excited by sources in the solar wind, with emphasis on the role of the magnetospheric cavity in modifying the external source and establishing its own resonances, and the role of the plasmapause in magnetohydrodynamic wave propagation; (2) Pi 2 waves, with emphasis on the plasmaspheric resonances and possible alternative excitation by plasmasheet source waves; (3) the spatial structure of internally excited long-period waves, including a kinetic theory for radially confined ring current instability and groundbased multipoint observation of giant pulsations; (4) amplitude-modulated Pc 1–2 waves in the outer magnetosphere (Pc 1–2 bursts) and in the inner magnetosphere (structured Pc 1 waves or pearls); and (5) the source region of the quasi-periodic emissions. Theory and observations are compared, and controversial issues are highlighted. In addition, some future directions are suggested.     

K-Ar dating studies of Ashigawa and Tokuwa granodiorite bodies and plutonic geochronology in the South Fossa Magna, central Japan

Abstract K-Ar age studies in the Ashigawa and the southern part of the Tokuwa granodioritic bodies, which consist of the southern part of the Kofu plutonic complex, revealed that they formed between 12 and 9 Ma. Quite a narrow range of ages obtained from the Ashigawa southernmost part of the Tokuwa pluton implies that they cooled rapidly. The southern part of the Tokuwa pluton, as a whole, shows a systematic age distribution with a decrease in age to the north. Compilation of currently available plutonic ages in the South Fossa Magna suggests that the plutonic activities occurred three times in this region. Episodic activity like this could be argued in relation to the tectonic development of this region.     

Miocene intra-arc bending at an arc-arc collision zone, central Japan

Abstract Recent paleomagnetic studies are reviewed in an effort to clarify the relationship between the intra-arc deformation of central Japan and the collision tectonics of the Izu-Bonin Arc. The cusp structure of the pre-Neogene terranes of central Japan, called the Kanto Syntaxis, suggests a collisional origin with the Izu-Bonin Arc. The paleomagnetic results and newly obtained radiometric ages of the Kanto Mountains revealed the Miocene rotational history of the east wing of the Kanto Syntaxis. More than 90° clockwise rotation of the Kanto Mountains took place after deposition of the Miocene Chichibu Basin (planktonic foraminiferal zone of N.8: 16.6–15.2 Ma). After synthesizing the paleomagnetic data of the Japanese Islands and collision tectonics of central Japan, it appears that approximately a half rotation (40–50°) probably occurred at ca 15 Ma in association with the rapid rotation of Southwest Japan. The remainder (50-40°) continued until 6 Ma, resulting in the sharp bent structure of the pre-Neogene accretionary complexes (Kanto Syntaxis). The latter rotation seems to have been caused by the collision of the Izu-Bonin Arc on the northwestward migrating Philippine Sea Plate.     

Attenuation of peak ground acceleration,velocity and displacement based on multiple regression analysis of japanese strong motion records

This paper presents the result of multiple regression analysis of 197 sets of two orthogonal horizontal strong motion acceleration records. They were obtained at 67 free field sites in Japan from 90 earthquakes with focal depth less than 60 km. Because sensitivity of the Japanese SMAC accelerograph is appreciably low at the high frequency range, instrument correction was performed on the original data. Each pair of two orthogonal horizontal components was combined in the time domain to get the maximum peak ground motions in the horizontal plane. The records were classified into three groups due to subsoil condition. With the use of multiple regression analysis, empirical formulae of attenuation of the maximum peak ground acceleration, velocity and displacement were proposed for three subsoil conditions.     

A liquid helium cooled mid-infrared imaging Fabry-Perot spectrometer

A liquid helium cooled mid-infrared imaging Fabry-Perot spectrometer has been under development. A Si:P 5×5 detector array is used for this instrument. Although the array system has small format, but combination with JFET array will provide noise equivalent line flux of 1.0×10^-21 W/cm ² (1000sec, 10). This sensitivity is comparable with the SWS of the ISO.     

Correlations between OH,NaD and OI 5577 Å emissions in the airglow

Simultaneous measurements of the night airglow OI 5577 Å and OH (8,3) band have been carried out at Cachoeira Paulista (23°S, 45°W), Brazil since 1976. Cross correlation analyses between the nocturnal variations of these emissions and also with the OH rotational temperature (ROT) for various time shifts are presented. It is found that OH (8,3) is well correlated with ROT but with a time lag of about 1 h. The variations of OI 5577 Å lead OH (8,3) by about 2–3 h and ROT covaries with 5577 Å with a time lag less than 1 h. For the sake of comparison, OI 5577 Å, OH and NaD data from a number of IQSY stations have been analysed. It is noted that (1) OI 5577 Å leads OH by about 2 h at mid-latitude stations and (2) OH is well correlated with Na 5893 Å with a time lag of less than 1 h. The presence of the phase lagged correlation patterns between OH/5577 Å, OH/ROT and OH/NaD indicates vertical propagation of a wavelike perturbation of the upper atmosphere.     

Heterogeneous structure of western Nankai seismogenic zone deduced by multichannel reflection data and wide-angle seismic data

The 1946 Nankai earthquake (Ms=8.2) at the forearc region of the western Nankai Trough showed slow slip deformation off Cape Muroto, which did not propagate until the western end of the Nankai seismogenic zone. New seismic investigations show a low-velocity layer (LVL) on the subducting oceanic crust in the coseismic area. Two prestack depth-migrated sections show reflectivity events in the clay-rich boundary layer on the oceanic crust. Narrowly spaced imbricated slices develop in the nonrupture area. The reflective boundary layer indicates probably that underplating develops in the nonrupture area rather than the coseismic area. It is suggested that the friction is larger in the nonrupture area than the coseismic area because of the lack of LVL on the oceanic crust, the well developed underplating and the narrowly spaced imbricated thrusts in the nonrupture area. The topographic high of the oceanic crust with about 50 km width and maximum 3 km height is also revealed and is related to bending and thickening of the oceanic crust, the well developed underplating and the narn spaced imbricated thrusts in the nonrupture area. These structural characters may be the reason why the slow slip deformation did not propagate until the western end of the Nankai seismogenic zone and toward the trough side.     

Magnetic and electric field observations during the 2000 activity of Miyake-jima volcano, Central Japan

Magnetic and electric field variations associated with the 2000 eruption of Miyake-jima volcano are summarized. For about 1 week prior to the July 8 phreatic explosion, significant changes in the total intensity were observed at a few stations, which indicated uprising of a demagnetized area from a depth of 2 km towards the summit: this non-magnetic source can be regarded as a vacant space itself. Electric and magnetic field variations were observed simultaneously associated with the tilt-step event, which was the abrupt (∼50 s) inflation at a few km depth within the volcano followed by gradual recovery (∼several hours). The electric field is ascribed to the electrokinetic effect most probably due to forced injection of fluids from the source, while the magnetic field to the piezomagnetic effect due to increased pressure. Large magnetic variations amounting to a few tens of nT were observed at several stations since July 8, and they turned almost flat after the August 18 largest eruption. Magnetic changes are explained mostly by the vanishing of magnetic mass in the summit and additionally by the thermal demagnetization at a rather shallow depth. A large increase in the self-potential by 130 mV was also observed near the summit caldera associated with the August 18 eruption, which suggests that the hydrothermal circulation system sustained within the volcano for the past more than 10 years was destroyed by this eruption.